教育经历
2002-2006年,汕头大学,本科,导师:黄晓春教授
2006-2009年,University of San Francisco,硕士,导师:Prof. J. C. Curtis
2009-2013年,University of Rochester,博士,导师:Prof. Richard Eisenberg 和 Prof. Patrick L. Holland
工作经历
2014-2017年,Caltech,导师:Prof. Theodor Agapie
2017-2018年,Newcastle University,导师:Dr. Elizabelt Gibson
2018年3月-至今,中山大学化学学院,教授,博士生导师
获奖情况
● 中山大学化学学院青年教师授课大赛一等奖(2022)
● Anges M. and George Messersmith Fellowships (2013)
● Elon Huntington Hooker Fellowships (2012)
● Sherman-Clarke Fellowships (2010, 2011)
● American Institute of Chemists (AIC) Student Award (2009)
18. Yuan, H.; Du, J.; Ming, M.; Chen, Y.; Jiang, L.; Han, Z.* “Combination of Organic Dye and Iron for CO2 Reduction with Pentanuclear Fe2Na3 Purpurin Photocatalysts” J. Am. Chem. Soc. 2022, 144, 4305-4309
17. Chen, Y.;† Yuan, H.;† Lei, Q.; Ming, M.; Du, J.; Tao, Y.; Cheng, B.; Han, Z.* “Improving Photocatalytic Hydrogen Production through Incorporating Copper to Organic Photosensitizers” Inorg. Chem. 2022, Accepted
16. Cheng, B.; Du, J.; Yuan, H.; Tao, Y.; Chen, Y.; Lei, J.; Han, Z.* “Selective CO2 Reduction to Ethylene Using Imidazolium-Functionalized Copper” ACS Appl. Mater. Interfaces 2022, 14, 27823-27832
15. Yuan, H.; Cheng, B.; Lei, J.; Jiang, L.; Han, Z.* “Promoting Photocatalytic CO2 Reduction with a Molecular Copper Purpurin Chromophore” Nat. Commun. 2021, 12, 1835
14. Wang, J-W.; Jiang, L.; Huang, H-H.; Han, Z., Ouyang, G.* “Rapid electron transfer via dynamic coordinative interaction boosts quantum efficiency for photocatalytic CO2 reduction” Nat. Commun. 2021, 12, 4276
13. Li. F.; Thevenon, A.; Rosas-Hernández, A.; Wang, Z.; Li, Y.; Gabardo, C. M.; Ozden, A.; Dinh, C. T.; Li, J.; Wang, Y.; Edwards, J. P.; Xu, Y.; McCallum, C.; Tao, L.; Liang, Z-Q.; Luo, M.; Wang, X.; Li, H.; Brien, C.; Tan, C-S.; Nam, D-H.; Quintero-Bermudez, R.; Zhuang, T-T.; Li, Y. C.; Han, Z.; Britt, R. D.; Sinton, D.; Agapie, T.;* Peters, J. C.;* Sargent,E. H.;*“Molecular Tuning of CO2-to-Ethylene Conversion” Nature 2020, 577, 509-51
12. Han, Z.;† Kortlever, R.;† Chen, H-Y; Peters, J. C.;* Agapie, T.* “CO2 Reduction Selective for C≥2 Products on Polycrystalline Copper with N-substituted Pyridinium Additives” ACS Cent. Sci. 2017, 3, 853-959
11. Han, Z.; Horak, K.; Lee, H. B.; Agapie, T.* “Tetrametallic Manganese Models of the OEC Displaying Hydrogen Bonding Interactions: Application to Electrocatalytic Water Oxidation to Hydrogen Peroxide” J. Am. Chem. Soc. 2017, 139, 9108-9111
10. Das, A.;† Han, Z.;† Brennessel, W. W.; Holland, P. L.* and Eisenberg R.* “Nickel Complexes for Robust Light-Driven and Electrocatalytic Hydrogen Production from Water” ACS Catal. 2015, 5, 1397-1406.
9. Han, Z. and Eisenberg R.* “Fuel from Water: the Photochemical Generation of Hydrogen from Water” Acc. Chem. Res. 2014, 47, 1397-1406.
8. Han, Z.; Shen, L.; Brennessel, W. W.; Holland, P. L.* and Eisenberg R.* “Nickel Pyridinethiolate Complexes for as Catalysts for the Light-Driven Production of Hydrogen from Aqueous Solutions in Noble-Metal-Free Systems” J. Am. Chem. Soc. 2013, 135, 14659-14669.
7. Han, Z.;† Qiu, F.;† Eisenberg, R.;* Holland, P. L.;* Krauss, T. D.;* “Robust Photogeneration of H2 in Water Using Semiconductor Nanocrystals and a Nickel Catalyst” Science 2012, 338, 1321-1324.
6. Han, Z.; McNamara W. R.; Eum, Min-Sik, Holland, P. L.* and Eisenberg R.* “A Nickel Thiolate Catalyst for the Long-Lived Photocatalytic Production of Hydrogen in a Noble-Metal-Free System”Angew. Chem. Int. Ed. 2012, 51, 1667-1670. ("Hot Paper")
5. Qiu, F.; Han, Z.; Peterson, J. J.; Oda, M. Y.; Sowers, K. L.; Krauss, T. D.* “Photocatalytic Hydrogen Generation by CdSe/CdS Nanoparticles”Nano Lett. 2016, 16, 5347-5352.
4. Das, A.; Han, Z.; Haghighi, M. G.; Eisenberg, R.* “Photogeneration of Hydrogen from Water Using CdSe Nanocrystals Demonstrating the Importance of Surface Exchange” Proc. Natl. Acad. Sci. USA 2013, 110, 16716-16723.
3. McNamara, W. R.; Han, Z.; Yin, Chih-Juo; Brennessel, W. W.; Holland, P. L.;* Eisenberg, R.* “Cobalt-Dithiolene Complexes for Photocatalytic and Electrocatalytic Reduction of Protons in Aqueous Solutions” Proc. Natl. Acad. Sci. USA 2012, 109, 15594-15599.
2. McNamara, W. R.; Han, Z.; Alperin, P. J.; Brennessel, W. W.; Holland, P. L.;* Eisenberg, R.* “A Cobalt-Dithiolene Complex for the Photocatalytic and Electrocatalytic Reduction of Protons" J. Am. Chem. Soc. 2011, 133, 15368-15371.
1. McCormick, T. M.; Han, Z.; Weinberg, D. J.; Holland, P. L* and Eisenberg, R.* “Impact of Ligand Exchange in Hydrogen Production from Cobaloxime-Fluorescein Photocatalytic Systems”Inorg. Chem. 2011, 50, 10660-10666.
相关成果
2. Han, Z.; Kortlever, R.; Chen, H-Y; Jonas, P. C.; Agapie, T.; Hernandez, J. A. R.; Thevenon, A. A.“Product Selectivity for CO2 Reduction” Patent number: US 11,371,152 B2
1. Krauss, T. D.; Eisenberg, R.; Holland, P. L.; Qiu, F.; Han, Z. “Methods for producing hydrogen using nanoparticle-catalyst mixtures” Patent number: WO2014071366 A1 and US20150290615
自然界的 [Ni-Fe]-氢化酶和一氧化碳脱氢酶能够进行高选择性的质子或二氧化碳还原,这两类酶的催化中心均涉及镍-硫配位结构。鉴于此,中山大学化学学院韩治际教授课题报道了一系列同时具备此两类酶催化活性特性的镍巯基配合物(图1),首次实现分子催化剂上实现了二氧化碳还原为C3(丙烯和丙烷)等多碳产物,碳水化合物的总法拉第效率高达41.1%。
作者通过对比不同配原子的镍巯基配合物,筛选出系列中活性最高的配合物5。在可逆氢电极−1.0 V的条件下,配合物5的C1、C2、C3碳氢化合物的法拉第效率(FEs)分别为10.6%、7.2%和8.2%。结果表明,Ni−CO为反应中的重要中间体,系统在一氧化碳的条件下可以显著促进配合物的催化活性,其中C1、C2、C3烃的FEs分别提高至18.8%、12.1%和8.7%。研究通过各类光谱,如:NMR、CV、UV-vis、ESI-MS、XPS、DLS、SEM和HR-TEM等,对催化过程中催化剂的变化进行了详细的研究,充分证明了此类配合物的结构在CO2还原过程中保持完整。该工作为仿生催化剂的合成和CO2还原的机理研究均提供了新的研究思路。
相关成果以 “Molecular Nickel Thiolate Complexes for Electrochemical Reduction of CO2 to C1−3 Hydrocarbons” 为题发表于Angewandte Chemie International Edition (DOI: 10.1002/anie.202211804),并被评为VIP文章。韩治际教授为通讯作者,化学学院2018级博士生杜杰毫为第一作者。中山大学化学学院为本成果的唯一通讯单位。