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和庆钢，浙江大学特聘研究员。长期从事电化学能源系统、燃料电池应用技术及正电子发射计算机断层扫描（PET）核示踪试剂基础及应用研究。作为主要研究人员，完成了多项由美国能源部，美国陆军研究办公室，美国国防部等资助的重大基础科学问题项目。在电化学催化及电极反应动力学研究上取得多项创新成果。2015年入选第十一批国家“##计划”青年人才。 个人简介 和庆钢
特聘研究员，博士生导师 浙江大学/化学工程与生物工程学院 玉泉校区教学十楼6107室 教育工作经历：
2015.9 – 至今, 浙江大学，化学工程与生物工程学院，特聘研究员
2012.7 – 2015.8, UCLA, Dept. of Molecular & Medical Pharmacology, 博士后研究员
2010.7 – 2012.6, Lawrence Berkeley National Lab, Environmental EnergyTechnologies Division, 博士后研究员
2005.9 – 2010.6, Northeastern University (Boston), Dept. of Chemistry andChemical Biology, 物理化学博士学位
2002.9 – 2005.3, 上海交通大学，化学化工学院，化学工程硕士学位
1998.9 – 2002.6, 上海交通大学，化学化工学院，化学工程与工艺学士学位 工作研究领域 1. 中、低温燃料电池（质子交换膜、磷酸和碱性燃料电池等）中的电催化剂和膜电极材料，以及电极反应动力学等的研究 2. 利用原位X射线光谱和原位扫描探针显微技术，对电化学能源转化和存储装置中的关键界面现象和性质等的研究 3. 正电子发射计算机断层扫描（PET）核示踪试剂的开发，以及后续生命医学影像分析和研究 联系方式 科研方向 1. 利用电化学原位X射线吸收和衍射光谱技术，指导开发新型燃料电池电催化材料 原位X射线光谱技术（insitu XAS, XRD）是在高等同步加速器的某一阶段能量光路中置入特殊设计的电化学反应池，在改变入射光的能量（或角度）的情况下，既可获取电极材料在工作状态下的X射线吸收或衍射光谱。通过相应的图谱分析和模型计算便可获得诸如材料的电子结构，短距离和长距离原子次序，配为数，晶体结构，离子表面吸附状态等多种信息。我们主要通过in situ XAS, XRD技术，深入了解中、低温燃料电池电催化剂在真实工作状态（电压、电流等）和工作环境（酸碱度、通氧等）下的微观电子和几何结构变化。并为开发性能更高、稳定性更强、价格更低廉的新型催化材料做出指导。 2. 利用电化学原位扫描探针显微技术，研究电化学能源转化和存储装置中界面现象 原位扫描探针显微技术（insitu SPM）能够利用扫描探针作为工作电极，在与扫描底物之间形成电势差时，便可以在真实电化学反应状态下获取电极材料的微观形貌和结构。另外还可以测量多种离子导电材料（如导电聚合物）的离子导电通道的分布，并且对固体/固体，固体/液体界面现象进行观测。除了材料本身的性质，电化学能源转化和存储系统的综合性能与界面性质是直接相关的。基于in situ SPM技术，我们重点研究燃料电池膜电极的电子传输情况和锂离子电池中电极/电解质界面膜的生长。 3. 正电子发射计算机断层扫描（PET）核示踪试剂电化学合成过程研究 正电子发射计算机断层扫描 (PET) 是一项分子核医学成像技术，被成功地用于肿瘤、神经系统和心血管疾病的临床诊断和治疗评价当中。由放射性同位素（如碳[11]、氟[18]等）标定的核示踪试剂的开发是这项技术在临床医学中应用的关键。目前氟[18]代脱氧葡萄糖([18F]FDG)已经取得商业化并且广泛地应用于临床（特别是肿瘤的诊断和治疗）。然而基于分子生物学及病理学的机理，不同类型的病症往往需要特殊的PET示踪剂，才能形成准确的诊断与评价。在核示踪试剂的合成过程中，人们更倾向于选择无载体的亲核取代反应（相对于亲电取代反应），以在最大程度上提高取代产物的单位核活性（specific activity）。我们使用电化学氧化手段，利用在电极上产生的碳正离子和直接来自于回旋加速器产生的氟[18]阴离子，能够进行无载体的亲核取代反应。目前我们重点进行根据目标示踪剂的前驱体设计、电化学反应条件设置、微流体反应平台的优化、产物的分离与表征等的研究。 2018年 1） Xin Deng, MeilingXiao, Ruoou Yang, Fan Guo, Hengquan Chen ， Ye Hu , Yan Li,Cuicui Zhu, Yaping Deng, Zheng Jiang, Zhen Xu, Chao Gao, Qinggang He*, JunjieGe, Yang Hou, Xingwang Zhang, Zhongwei Chen*, "The effect of CNTs onPerformance Improvement of rGO Supported Fe-Nx/C Electrocatalysts for theOxygen Reduction Reaction"，Journal of The Electrochemical Society, 2018, 165（5）,F401-F407 2）Xiao, Meiling; Zhu,Jianbing; Ma, Liang; Jin, Zhao; Ge, Junjie*; Deng, Xin; Hou, Yang; He,Qinggang*; Li, Jingkun; Jia, Qingying; Mukerjee, Sanjeev; Yang, Ruoou; Jiang,Zheng; Su, Dang Sheng; Liu, Changpeng; Xing, Wei*，“MicroporousFramework-Induced Synthesis of Single-Atom Dispersed Fe-N-C Acidic ORR Catalystand Its in-Situ Reduced Fe-N4 Active Site Identification Revealed by X-RayAbsorption Spectroscopy”， ACS Catalysis，2018, 8, 2824–2832 3) Chen, Qing; Du, Yang; Zhang, Kai; Liang,Zeyu; Li, Jinquan; Yu, Hao; Ren, Rong; Feng, Jin; Jin, Zhiming; Li, Fangyuan;Sun, Jihong; Zhou, Min; He, Qinggang; Sun, Xiaolian; Zhang, Hong; Tian, Mei;Ling, Daishun, "Tau-Targeted Multifunctional Nanocomposite forCombinational Therapy of Alzheimer's Disease", ACS Nano, 2018, 12(2),1321-1338 2017年 1) Hengquan Chen, Masahiko Nishijima,Guangjin Wang, Samson Khene, Mingqiao Zhu, Xin Deng, Xingmin Zhang, Wen Wen, YuLuo, Qinggang He*, "The Ordered and Disordered Nano-Intermetallic AuCu/CCatalysts for the Oxygen Reduction Reaction: the Differences of the ElectrochemicalPerformance", Journal of The Electrochemical Society, 164 (2017)F1654-F1661 2) 古望军朱明乔李征 任荣 和庆钢*张宏*, 18F标记芳环类PET显像剂方法的研究进展,中华核医学与分子影像，InPress 3) 邓昕，陈亨权，和庆钢*，Fe-N-C类催化剂在碱性燃料电池中的研究进展，电化学，In Press 4）"Hydrogen andChemicals from renewable alcohols by Organometallic Electro-Reforming(OMER)" by Marco Bellini, PhD; Jonathan Filippi, PhD; Hamish AndrewMiller, PhD; Werner Oberhauser; Francesco Vizza; He Qinggang; Hansjorg Grützmacher， ChemCatChem，9 (2017)746–750 2016年 1）Hamish A. Miller,*Marco Bellini, Werner Oberhauser, Xin Deng, Hengquan Chen, Qinggang He,*Maurizio Passaponti, Massimo Innocenti, Ruoou Yang, Fanfei Sun, Zheng Jiang,and Francesco Vizza*，“Heat treated carbon supported iron(II) phthalocyanineoxygenreduction catalysts: elucidation of the structure-activity relationship usingX-ray absorption spectroscopy”，Physical Chemistry Chemical Physics，18 (2016)33142-33151 2015年 1) "Recent progress inelectrocatalysts for oxygen reduction suitable for alkaline anion exchangemembrane fuel cells" Q. He, E. Cairns Journal of Electrochemical Society, 162(2015) F1504-F1539 2) “No-carrier-added electrochemicalnucleophilic radiofluorination of aromatics” Q. He, I. Alfeazi, S. Sadeghi Journal of Radioanalytical and NuclearChemistry, 303 (2015) 1037-1040 2014年 1) “Effects of Redox Mediators on theCatalytic Activity of Iron Porphyrins towards Oxygen Reduction in Acidic Media” Q. He, G. Wu, K. Liu, S. Khene, Q. Li, T.Mugadza, E. Deunf, T. Nyokong, and S. Chen ChemElectroChem, 1 (2014) 1508-1515 2) “Electrochemical Nucleophilic Synthesisof Di-tert-butyl-(4-[18F]fluoro-1,2-phenylene)-dicarbonate” Q. He, Y. Wang, I. Alfeazi, S. Sadeghi Applied Radiation and Isotopes, 92 (2014)52-57 2013年 1) “Electrochemical and SpectroscopicCharacterization of a Dicobalt Macrocyclic Pacman Complex in the Catalysis ofthe Oxygen Reduction Reaction in Acid Media”, Q. He, X. Cheng, Y. Wang, R. Qiao, W. Yang,J. Guo Journal of Porphyrins andPhthalocyanines,17 (2013) 252-258 2) “High-Loading Cobalt Oxide Coupled withNitrogen-Doped Graphene for Oxygen Reduction in Anion-Exchange-MembraneAlkaline Fuel Cells”, Q. He, Q. Li, S. Khene, X. Ren, F.López-Suárez, D. Lozano-Castelló, A. Bueno-López, and G. Wu Journal of Physical Chemistry C, 117 (2013)8697–8707 3) “Highly Stable Pt−Au@Ru/CCatalyst Nanoparticles for Methanol Electro-oxidation”, Q. He, B. Shyam, M. Nishijima, X. Yang, B.Koel, F. Ernst, D. Ramaker, S. Mukerjee Journal of Physical Chemistry C, 117 (2013)1457-1467 4) “Preparation of ceria-supported rhodiumoxide sub-nanoparticles with improved catalytic activity for CO oxidation”, V. Pérez, M. Beltrán, Q. He, Q. Wang, C.Martínez de Lecea, A. Bueno-López Catalysis Communications, 33 (2013) 47-50 5) “Mitigating Phosphate Anion Poisoning ofCathodic Pt/C Catalysts in Phosphoric Acid Fuel Cells”, Q. He, B. Shyam, M. Nishijima, D. Ramaker,and S. Mukerjee Journal of Physical Chemistry C, 117 (2013)4877–4887 2012年 1) “Scanning Probe Imaging of Surface IonConductance in an Anion Exchange Membrane”, Q. He, X. Ren Journal of Power Sources, 220 (2012)373-376 2) “Mechanisms of Electrocatalysis ofOxygen Reduction by Metal Porphyrins in Trifluoromethane Sulfonic AcidSolution”, Q. He, T. Mugadza, G. Hwang, T. Nyokong International Journal of ElectrochemicalScience, 7 (2012) 7045-7064 3) “Dramatically Enhanced Cleavage of theC-C Bond Using an Electrocatalytically Coupled Reaction”, Q. He, B. Shyam, K. Macounova, Petr. Krtil,D. Ramaker, S. Mukerjee Journal of the American Chemical Society,134 (2012) 8655-8661 4) “Molecular catalysis of the oxygenreduction reaction by iron porphyrin catalysts tethered into Nafion layers: anelectrochemical study in solution and a membrane-electrode-assembly study infuel cells”, Q. He, T. Mugadza, X. Kang, X. Zhu, S.Chen, J. Kerr, T. Nyokong Journal of Power Sources, 216 (2012) 67-75 5) “Electrochemical and Spectroscopic Studyof Novel Cu and Fe-based Catalysts for Oxygen Reduction in Alkaline Media”, Q. He, X. Yang, R. He, A. Bueno-López, H.Miller, X. Ren, W. Yang, and B. E. Koel Journal of Power Sources, 213 (2012)169-179 6) “Bridge to Fuel Cell MolecularCatalysis: 3D Non-Platinum Group Metal Catalyst in MEAs”, X. Zhu, J. Kerr, Q. He, G. Hwang, Z.Martin, K. Clark, A. Weber, and N. Zhao ECS Transactions, 45 (2012) 143-152 2011年 1) “Correlating Humidity-DependentIonically Conductive Surface Area with Transport Phenomena in Proton-ExchangeMembranes”, Q. He, A. Kusoglu, I. T. Lucas, K. Clark,A. Z. Weber, and R. Kostecki Journal of Physical Chemistry B, 115 (2011)11650–11657 2) “A novel CuFe-based catalyst for theoxygen reduction reaction in alkaline media”, Q. He, X. Yang, X. Ren, B. E. Koel, N.Ramaswamy, S. Mukerjee, and R. Kostecki Journal of Power Sources, 196 (2011)7404-7410 3) “Effect of praseodymium oxide andcerium–praseodymium mixed oxide in the Pt electrocatalyst performance for theoxygen reduction reaction in PAFCs”, Q. He, S. Mukerjee, S. Parres-Esclapez, andA. Bueno-Lopez Journal of Applied Electrochemistry,41(2011) 891-899 2010年 1) “Influence of phosphate anion adsorptionon the kinetics of oxygen electroreduction on low index Pt(hkl) singlecrystals”, Q. He, X. Yang, W. Chen, S. Mukerjee, B.Koel and S. Chen Physical Chemistry Chemical Physics, 12(2010) 12544-12555 2) “Enhanced Pt stability in MO2 (M = Ce,Zr or Ce0.9Zr0.1)-promoted Pt/C electrocatalysts for oxygen reduction reactionin PAFCs”, Q. He, S. Mukerjee, R. Zeis, S.Parres-Exclapez, M.J. Illán-Gómez, and A. Bueno-López Applied Catalysis A: General., 381 (2010)54-65 3) “Electrocatalysis of Oxygen Reduction onCarbon Supported PtCo Catalysts Prepared by Water-in-Oil Microemulsions”, Q. He, and S. Mukerjee Electrochimica Acta, 55 (2010) 1709-1719 2009年 1) “Carbon-supported PdM (M = Au and Sn)nanocatalysts for the electrooxidation of ethanol in high pH media”, Q. He, W. Chen, S. Mukerjee, S. Chen, andF. Laufek Journal of Power Sources, 187 (2009)298–304 2) “Promoting effect of CeO2 in theelectrocatalytic activity of Rhodium for ethanol electro-oxidation”, Q. He, S. Mukerjee, B. Shyam, D. Ramaker,S. Parres-Exclapez, M.J. Illán-Gómez, and A. Bueno-López Journal of Power Sources, 193 (2009)408-415 专利 1) "一种用于半制备高效液相色谱的压力调节阀" 和庆钢、古望军、朱明桥 中国发明专利（2018）2017204496039 2) "一种可以进行电化学光谱实验的原位池" 和庆钢、陈亨权、赵建江 中国发明专利（2017） 201621170358X 3) “Membrane-Electrode Structures forMolecular Catalysts for use in Fuel Cells and other Electrochemical Devices” J. Kerr, X. Zhu, G. Hwang, Z. Martin, Q.He, P. Driscoll, A.Weber, K. Clark U.S. Pat. Appl. Publ. (2014), US20140106255 4) “Synthesis of FluorinatedRadiopharmaceuticals via Electrochemical Fluorination” S. Sadeghi, Q. He US Patent, PCT/US14/37731 5) “Electrochemical process for conversionof biodiesel to aviation fuels” S. Mukerjee, Q. He PCT Int. Appl. (2012), WO 2012012799 6) “Highly Stable Platinum Alloy Catalystfor Methanol Electrooxidation” S. Mukerjee, Q. He, N. Ramaswamy PCT Int. Appl. (2011), WO 2011160022 7) “Metal Co-catalyst enhancer ofelectro-oxidation of ethanol” S. Mukerjee, Q. He, P. Krtil, and K.Mancounova PCT Int. Appl. (2011), WO 2011159314 8) “Catalyst for electrochemicalapplications” E. Schwab, S. Brauninger, A. Panchenko, C.Querner, O. Unsal, M. Vogt, Q. He, N. Ramaswamy, and S. Mukerjee PCT Int. Appl. (2010), WO 2010139596 9) “Novel electrolyte blends for enhancedmass transport in elevated temperature electrolytes” S. Mukerjee, V. Gregoriou, Q. He US Patent, Application No. 61/386,770, 2010
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发表于 2018-5-21 17:22:59
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