华东师范大学化学与分子工程学院高国华

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高国华，华东师范大学化学系上海市绿色化学与化工过程绿色化重点实验室教授，博士生导师。他具有与日本SONY公司、中国石化发展部以及中国石化催化剂公司等国内外知名企业合作开发经验。受邀担任华东师范大学物理化学学科组组长、中国化工学会离子液体专业委员会委员。主持国家自然科学基金面上项目5项，参与重点、重大项目各一项，参与国家重点研发计划1项。近五年在国际核心期刊Chem. Rev., Chem. Sci., Green Chem., Chem. Commun., ACS Macro. Lett., Eur. J. Org. Chem.等发表科研论文30余篇。


高国华
教授
化学与分子工程学院
上海市绿色化学与化工过程绿色化重点实验室
联系电话： 021-62233323
办公地点： 华东师范大学化学馆B210
电子邮箱： ghgao@chem.ecnu.edu.cn
通讯地址： 上海市中山北路3663号
研究方向
催化化学‚有机无机功能材料‚离子液体化学
社会兼职
中国化工学会离子液体专业委员会委员


学术成果
代表性研究论文

• Yongya Zhang, Bihua Chen, Yifeng Zhang, Li Qin, Bo Liu, Bing Ni and Guohua Gao*. Water-enriched poly(ionic liquid)s: highly-efficient microreactors for the hydrolysis of ethylene carbonate. Green Chem., 2018, 20, 1594–1601.
• Binshen Wang, Li Qin, Tiancheng Mu*, Zhimin Xue, Guohua Gao*. Are Ionic Liquids Chemically Stable? Chem. Rev.，2017, 117, 7113−7131.
• Dawei Zhang, Kelsey Jamieson, Laure Guy, Guohua Gao*. Jean-Pierre Dutasta, Alexandre Martinez*. Tailored oxido-vanadium(V) cage complexes for selective sulfoxidation in confined spaces, Chem. Sci., 2017.01.18, 8: 789~794.
• Li Qin，Binshen Wang，Yongya Zhang，Li Chen，Guohua Gao *. Anion Exchange: A Novel Way for Preparing Hierarchal PorousStructure of Poly(ionic liquid)s. Chem. Commun., 2017, 53, 3785--3788 .
• Shi Wu，Yongya Zhang，Binshen Wang，Elnazeer H. M. Elageed，Liangzheng Ji，Haihong Wu *，Guohua Gao*. Synthesis of Functionalized Cyclic Carbonates by One-Pot Reactions of Carbon Dioxide, Epibromohydrin, and Phenols,Thiophenols, or Carboxylic Acids Catalyzed by Ionic Liquids，Eur. J. Org. Chem., 2017.1.18, 3: 753~759.
• Yifeng Zhang, Yongya Zhang, Bihua Chen, Li Qin, and Guohua Gao*. Swelling Poly (Ionic Liquid)s: Heterogeneous Catalysts That are Superior than Homogeneous Catalyst for Ethylene Carbonate Transformation. ChemistrySelect 2017, 2, 9443– 9449.
• Yongya Zhang, Binshen Wang, Elnazeer H. M. Elageed, Li Qin, Xiuli Liu, Bing Ni, Guohua Gao*. Swelling poly(ionic liquid)s: synthesis and application as quasi-homogeneous catalysts in the reaction of ethylene carbonate with aniline. ACS Macro Lett., 2016, 5: 435-438.
• Elnazeer H. M. Elageed, Bihua Chen, Binshen Wang, Yongya Zhang, ShiWu, Xiuli Liu, Guohua Gao*. Selective Synthesis of 5-Substituted N-Aryloxazolidinones by Cycloaddition Reaction of Epoxides with Arylcarbamates Catalyzed by the Ionic Liquid BmimOAc. Eur. J. Org. Chem., 2016, 21: 3650-3656.
• Shi Wu, Binshen Wang, Yongya Zhang, Elnazeer H.M. Elageed, Haihong Wu*, Guohua Gao*. Phenolichydroxyl-functionalized imidazolium ionic liquids: Highly efficient catalysts for the fixation of CO2 to cyclic carbonates. J. Mol. Catal. A:Chem., 2016, 418: 1-8.
• Binshen Wang, Zhoujie Luo, Elnazeer H. M. Elageed, Shi Wu, Yongya Zhang, Xiaopei Wu, Fei Xia*, Guirong Zhang, Guohua Gao*. DBU and DBU-Derived Ionic Liquid Synergistic Catalysts for the Conversion of Carbon Dioxide/Carbon Disulfide to 3-Aryl-2-oxazolidinones/[1,3]Dithiolan-2-ylidenephenylamine. ChemCatChem, 2016, 8: 830-838.
• Xiaopei Wu, Liangzheng Ji, Yayan Ji, Elnazeer H.M. Elageed, Guohua Gao*. Hydrogenation of ethylene carbonate catalyzed by lutidine-bridged N-heterocyclic carbene ligands and ruthenium precursors. Catal. Commun., 2016, 85: 57-60.
• Zhoujie Luo, Binsen Wang, Yuan Liu, Guohua Gao*, Fei Xia*. Reaction mechanisms of carbon dioxide, ethylene oxide and amines catalyzed by ionic liquids BmimBr and BmimOAc: a DFT study. Phys. Chem. Chem. Phys., 2016, 18(40), 27951-27957.
• Dawei Zhang, Guohua Gao*, Laure Guy, Vincent Robert, Jean-Pierre Dutasta*, Alexandre Martinez*. A fluorescent heteroditopic hemicryptophane cage for the selective recognition of choline phosphate. Chem. Commun., 2015, 51 (13): 2679-2682.
• Elnazeer H. M.Elageed, Binshen Wang, Yongya Zhang, Shi Wu, Guohua Gao*. BmimOAc ionic liquid: A highly efficient catalyst for synthesis of 3-aryl-2-oxazolidinones by direct condensation of 2-(arylamino) alcohols with diethyl carbonate. J. Mol. Catal. A: Chem., 2015, 408: 271-277.
• Binshen Wang, Sijuan Yang, Lijun Min, Yanlong Gu*, Yongya Zhang, Xiaopei Wu, Lifeng Zhang, Elnazeer H. M. Elageed, Shi Wu, Guohua Gao*. Eco-Efficient Synthesis of Cyclic Carbamates/Dithiocarbonimidates from Cyclic Carbonates/ Trithiocarbonate and Aromatic Amines Catalyzed by Ionic Liquid BmimOAc. Adv. Synth. Catal., 2014, 356(14-15): 3125-3134.
• Binshen Wang, Elnazeer H. M. Elageed, Dawei Zhang, Sijuan Yang, Shi Wu, Guirong Zhang, Guohua Gao*. One-Pot Conversion of Carbon Dioxide, Ethylene Oxide, and Amines to 3-Aryl-2-oxazolidinones Catalyzed with Binary Ionic Liquids. ChemCatChem, 2014, 6(1): 278-283.
• Dawei Zhang, Haiqiang Yang, Alexandre Martinez*, Kelsey Jamieson, Jean-Pierre Dutasta, Guohua Gao*. N-Heterocyclic Carbene Formation Induced Fluorescent and Colorimetric Sensing of Fluoride Using Perimidinium Derivatives. Chem. Eur. J., 2014, 20: 17161-17167.
• Dawei Zhang, James Robert Cochrane, Alexandre Martinez*, Guohua Gao*. Recent advances in H2PO4- fluorescent sensors. RSC Adv., 2014, 4(56): 9735-29749.
• Dawei Zhang, Xiaozhi Jiang, Haiqiang Yang, Zhao Su, Enqing Gao, Alexandre Martinez*, Guohua Gao*, Novel benzimidazolium-urea-based macrocyclic fluorescent sensors: synthesis, ratiometric sensing of H2PO4-and improvement of the anion binding performance via a synergistic binding strategy. Chem. Commun., 2013, 49(55): 6149-6151.
• Binshen Wang, Xin Feng, Lifeng Zhang, Sijuan Yang, Xiaozhi Jiang, Jing Zhou, Guohua Gao*, One-pot reaction of CO2, epichlorohydrin and amine to synthesize 4-(phenylamino)methyl-ethylene carbonate catalyzed by ionic liquids. J. CO2 Util., 2013, 1(1): 88-91.
• Dawei Zhang, Xiaozhi Jiang, Haiqiang Yang, Alexandre Martinez*, Meiyuan Feng, Zhiyun Dong, Guohua Gao*. Acridine-based macrocyclic fluorescent sensors: self-assembly behavior characterized by crystal structures and a tunable bathochromic-shift in emission induced by H2PO4- via adjusting the ring size and rigidity. Org. Biomol. Chem., 2013, 11(20): 3375-3381.  
  

heligui

双离子液体基多孔炭的制备与电化学性能

Preparation and Electrochemical Performance of Porous Carbons Prepared from Binary Ionic Liquids

高国华等以质子型离子液体1-氢-3-乙烯基咪唑硫酸氢盐(HVImHSO4)为主炭源, 以1-丁基-3-甲基咪唑六氟磷酸盐(BMImPF6)为助剂, 在氮气气氛、 1000 ℃下一步炭化得到氮、 磷、 硫共掺杂多孔炭. 通过N2吸附-脱附、 扫描电子显微镜(SEM)、 透射电子显微镜(TEM)、 X射线衍射(XRD)、 拉曼光谱(Raman)、 热重分析(TGA)和X射线光电子能谱(XPS)等技术对多孔炭进行了分析表征. 结果表明, 多孔炭的孔结构以微孔为主, 最高比表面积可达1111 m2/g, 其微晶结构中无定形碳和石墨化碳并存; 多孔炭中的氮主要以季氮(N-Q)、 吡咯氮(N-5)和吡啶氮(N-6)的形式存在, 磷以磷-氧(N—O—P)键合形式为主, 硫主要以噻吩硫(C—S—C)为主. 在6 mol/L KOH溶液、 三电极体系中, 多孔炭在0.5 A/g电流密度下的比电容为138 F/g; 在10 A/g电流密度下的比电容为100 F/g; 在2 A/g电流密度下循环充放电10000次, 其比电容保持率为95.8%, 显示出良好的电化学性能.

链接本文:
http://www.cjcu.jlu.edu.cn/CN/10.7503/cjcu20190703
http://www.cjcu.jlu.edu.cn/CN/Y2020/V41/I5/1048