汕头大学化学系李明德

danjuan

李明德 [ 教授 ]        化学系       
性别：男
出生日期：
职务：
学术兼职：
社会兼职：
电话：0754-86503787
手机：
传真：
E-mail：mdli@stu.edu.cn                 
学历简介：
博士        2008-9 至 2012-2        香港大学
硕士        2004-9 至 2007-11        厦门大学
本科        1997-9 至 2001-6        兰州大学
工作经历：
2016年8月 至 现在        汕头大学 教授
2016年4月 至 2017年4月        香港大学 助理教授（研究）
2013年8月 至 2016年4月        香港大学 博士后（postdoctoral fellow）
2012年3月 至 2013年5月        美国加州大学伯克利分校 博士后
2008年4月 至 2008年8月        香港大学 研究助理
担任课程：
本科课程：
基础化学实验III
高等分析化学
学科前沿讲座
研究生课程：化学进展
主要研究兴趣：
     分子光谱：超快激光光谱（飞秒，亚纳秒瞬态吸收光谱/时间分辨共振拉曼光谱/飞秒时间分辨荧光光谱）的开发和应用；光致变色材料和分子光控开关；太阳能电池光电转化机理和动力学过程；光敏小分子和生物药物分子光化学反应过程与机理；纳米材料的光催化和光降解。
详细信息请查看个人主页 http://sci.stu.edu.cn/mdli/Default.aspx
承担项目：
[ 1 ] 香港研究资助局资助项目 Time-Resolved Spectroscopic Studies of the Photophysics and Photochemistry of Selected Statins；
[ 2 ] 香港大学研究项目资助项目 Ultrafast laser Spectroscopic Investigations of the phototoxicity mechamism of Blebbistatin；
[ 3 ] 香港研究资助局资助项目 芳香羰基化合物的光氧化还原和光去保护反应机理的超快激光光谱研究；
研究成果：
[ 1 ] Su, T., Li, M. D.*, Ma, J., Phillips, D. L.,* (通讯作者)；Time-Resolved Spectroscopic Study of the Defluorination and Cyclization Reactions of Lomefloxacin in Water；The Journal of Physical Chemistry B, ·2017, Accepted；
[ 2 ] Zhu, R., Li, M. D.*, Du, L., Phillips, D. L.,* (通讯作者)；Singlet Versus Triplet Excited State Mediated Photoin-duced Dehalogenation Reactions of Itraconazole in Acetonitrile and Aqueous Solutions；The Journal of Physical Chemistry B, ·2017, DOI: 10.1021/acs.jpcb.6b11934；
[ 3 ] Liu, M., Tang, W., Li, M. D.*, Phillips, D. L.,* (通讯作者)；pH Dependent Photodeprotection of Formaldehyde: Homolytic C-C Scission in Acidic Aqueous Solution Versus Heterolytic C-C Scission in Basic Aqueous Solution；The Journal of Organic Chemistry, 2017, DOI: 10.1021/acs.joc.6b02756；
[ 4 ] Li, M. D., Zhu, R., Phillips, D. L.,*；Direct time-resolved spectroscopic investigation of intramolecular hydrogen atom transfer of deoxyblebbistatin；Chemical Physics Letters, 2017, DOI: 10.1016/j.cplett.2017.02.068；
[ 5 ] Huang J., Muliawan, A. P., Ma, J.,* Li, M. D., Chiu, H. K., Lan, X., Deodato, D., Phillips, D. L.,* Dore, T. M.*；Meta Versus Para Substitution: How Does C-H Activation in a Methyl Group Occur in 3-Methylbenzophenone But Does Not Take Place in 4-Methylbenzophenone.；Photochemical & Photobiological Sciences, 2017, DOI: 10.1039/c6pp00377j；
[ 6 ] Liu, M., Li, M. D.,* Su, T., Huang, J. Phillips, D. L.* (*通讯作者)；Substituent Effect on the Photodeprotection Reaction of Selected Ketoprofen Derivatives in Phosphate Buffered Aqueous Solution；Scientific Report. 2016, DOI: 10.1038/srep21606；
[ 7 ] Zhang, X., Ma, J.,* Li, S., Li, M. D., Zhu, R., Guan, X., Phillips, D. L.*；Ketyl Radical Formation via Proton-Coupled Electron Transfer in an Aqueous Solution versus Hydrogen Atom Transfer in Isopropanol after Photoexcitation of Aromatic Carbonyl Compounds；J. Org. Chem. 2016, 81, 5330-5336；
[ 8 ] Li, M. D.,Albright, T. R., Hanway, P. J., Liu, M.,Lan, X., Li, S., Peterson, J., Winter, A. H.,* Phillips, D. L.*；Direct Spectroscopic Detection and EPR Investigation of a Ground State Triplet Phenyl Oxenium Ion.；J. Am. Chem. Soc. 2015,137, 10391–10398.；
[ 9 ] Du, L.,§Li, M. D.,§ Zhang, X., Zhu, R., Cheng, S. C., Li, X., Philllips, D. L. *([§]共同一作).；Photoconversion of β-Lapachone to α-LapachoneVia a Protonation Assisted Singlet Excited State Pathway in Aqueous Solution: A Time-Resolved Spectroscopic Study.；J. Org. Chem. 2015, 80, 7340-7350.；
[ 10 ] Li, M. D., Huang, J., Liu, M., Li, S., Ma, J., Phillips, D. L.*；Investigation of the Role of Protonation of Benzophenoneand Its Derivatives in Acidic Aqueous Solutions Using TimeResolved Resonance Raman Spectroscopy: How Are KetylRadicals Formed in Aqueous Solutions? (Invited Special Issues: Photoinduced Proton Transfer in Chemistry and Biology Symponium).；J. Phys. Chem. B 2015, 119, 2241-2252.；
[ 11 ] Li, M. D.,Dang, L.,* Liu, M., Du, L., Zheng, X., Phillips, D. L.*；Ultrafast Time Resolved Spectroscopic Studies on the Generation of the Ketyl-Sugar Biradical by Intra-molecular Hydrogen Abstraction Among Ketoprofen and Purine Nucleoside Dyads；J. Org. Chem. 2015, 80, 3462-3470.；
[ 12 ] Li, M. D.,Hanway, P. J., Albright, T. R., Winter, A. H.,* Phillips, D. L.*；Direct Spectroscopic Observation of Closed-Shell Singlet, Open-ShellSinglet, and Triplet p-Biphenylyloxenium Ion.；J. Am. Chem. Soc.2014, 136, 12364–12370.；
[ 13 ] Leverenz, R. L.,a,bJallet, D.,bLi, M. D.,aMathies, R. A.,a,*Kiriloysky, D.,bKerfeld, C. A.b,*；Structural and functional modularity of the orange carotenoid protein: distinct roles for the N- and C-terminal domains in cyanobacterialphotoprotection.；Plant Cell 2014, 26, 426-437.；
[ 14 ] Liu, M., Li, M. D.,* Xue, J., Phillips, D. L.*( *通讯作者)；Time-Resolved Spectroscopic and Density Functional TheoryStudy of the Photochemistry of Irgacure-2959 in anAqueous Solution；J. Phys. Chem. A 2014, 118, 8701–8707.；
[ 15 ] Phillips, D. L.,* Li, M. D., Su, T.；Time-resolved resonance Raman spectroscopy combination with femtosecond and nanosecond transient absorption study on the biomolecules: Ketoprofen and Tiaprofenic acid. (invited letter)；EPA newsletter.2013, 85, 55-60.；
[ 16 ] Li, M. D., Ma, J., Li, W., Su. T., Liu, M., Phillips, D. L.*；A solvent dependent photochemistry of Fenofibric acid study by femtosecond transient absorption and nanosecond time-resolved resonance Raman and density functional theory.；Phys. Chem. Chem. Phys. 2013, 15,1557-1568.；
[ 17 ] Li, M. D., Su, T., Ma, J., Liu, M., Liu, H., Li, X., Phillips, D. L.*；Phototriggered release of a leaving group in Ketoprofen derivatives via a benzyliccarbanion pathway, but not via a biradical pathway.；Chem. Eur. J. 2013, 19, 11241-11250.；
[ 18 ] Li, M. D., Ma, J., Su, T., Phillips, D. L.*；Direct observation of triplet state mediated decarboxylation of the neutral and anion forms of Ketoprofen in water-rich, acidic and PBS solutions.；J. Phys. Chem. B 2012,116, 5882-5887.；
[ 19 ] Li, M. D., Yeung, C. S., Guan, X., Li, W., Ma, J. Ma, C., Phillips, D. L.*；Water and acid mediated excited-state intramolecular proton transfer and decarboxylation reactions of Ketoprofen in water-rich and acidic aqueous solutions.；Chem. Eur. J. 2011, 17, 10935-10950.；
[ 20 ] Li, M. D., Li, W., Ma, J., Su. T., Liu, M., Du, Y., Phillips, D. L.*；Femtosecond transient absorption, nanosecond time-resolved resonance Raman and density functional theory study of Fenofibric acid in acetonitrile and isopropanol.；J. Phys. Chem. A 2011,115, 14168-14174.；
[ 21 ] Li, M. D., Du, Y., Chuang, Y. P., Xue, J., Phillips, D. L.*；Water concentration dependent photochemistry of Ketoprofen in aqueous solutions.；Phys. Chem. Chem. Phys.2010, 12, 4800-4808.；
[ 22 ] Li, M. D., Du, Y., Yeung, C. S., Phillips, D. L.*；Time-resolved resonance Raman study of the effect of pH on the photoreactions of 3-benzoylpyridine in aqueous solution.；J. Phys. Chem. A 2009, 113, 12215-12224.；
[ 23 ] Li, M. D., Cui, Y., Gao, M. X., Luo, J., Ren, B.,*Tian, Z. Q.*；Clean substrates prepared by chemical adsorption of iodide followed by electrochemical oxidation for surface-enhanced Raman spectroscopic study of cell membrane.；Anal. Chem. 2008, 80, 5118-5125.；
[ 24 ] Huang, J., Ma, J.,* Li, M. D., Liu, M., Phillips, D. L.*；How does the C-Halogen Bond Break in the Photosubstitution Reaction of 3-Fluorobenzophenone in Acidic Aqueous Solutions？；J. Org. Chem.2015,80, 9425–9436.；
[ 25 ] Su, T., Li, M. D.,* Ma, J., Wong, N., Phillips, D. L.* (* 通讯作者)；Femtosecond Transient Absorption Spectroscopy Study of the Early Events of Norfloxacin in Aqueous Solutions with Varying pH Values.；J. Phys. Chem. B, 2014,118, 13458-13467；
[ 26 ] Ma, J., Su, T., Li, M. D., Zhang, X., Huang, J., Phillips, D. L.*；Meta Versus Para Substitution: How Does C-H Activation in a Methyl Group Occur in 3-Methylbenzophenone But Does Not Take Place in 4-Methylbenzophenone.；J. Org. Chem., 2013, 78,4867–4878.；
[ 27 ] Su, T., Ma, J., Li, M. D., Guan, X., Yu, L., Phillips, D. L.*；Time-resolved spectroscopic study of the photochemistry of Tiaprofenicacid in a neutral phosphate buffered aqueous solution from femtoseconds to final products.；J. Phys. Chem. B 2013, 117, 811-824.；
[ 28 ] Ma, J., Su, T., Li, M. D., Du, W., Huang, J., Guan, X., Phillips, D. L.*；How and when does an unusual and efficient photoredoxreaction of 2-(1-hydroxyethyl) 9,10-anthraquinone occur? acombined time-resolved spectroscopic and DFT study.；J. Am. Chem. Soc. 2012, 134, 14858-14868.；
[ 29 ] Yu, L a., Xi, J b., Li, M. D a.,Chan, H a., Su, T a., Phillips, D. L.,a,* Chan, W. K.a,*；The degradation mechanism of methyl orange under photo-catalysis of TiO2.；Phys. Chem. Chem. Phys.2012, 14, 3589-3595.；
[ 30 ] Wang, H. Ga., Wang, La., Shen, Sa., Zhang, Wa., Li, M. Db., Du, Lb., Pei, K. Ma., Zheng, X.,a,* Phillips, D. L.b,*；Effects of hydrogen bond and solvent polarity on the C=O stretching and photophysicalproperties of bis(2-thienyl)ketone in solution.；J. Chem. Phys.2012,136, 124509-12511；
[ 31 ] Ma, Ja., An, Ha., Ma, Ca., Guan, Xa., Li, M. Da., Su, Ta., Yeung, C. Sa., Zhu, Yb., Nganga, J. Lb., Dore,, T. M.,b,* Phillips, D. L.a,*；Unraveling the mechanism of the photodeprotectionreaction of 8-bromo-7-hydroxyquinoline caged acetate in neutral aqueous solutions；Chem. Eur. J. 2011, 18, 6854-6865.；
[ 32 ] Ma, Ja., Cheng, S. Ca., An, Ha., Li, M. Da., Phillips, D. L.,a,* Dore, T. M.b,*；Comparison of the absorption, emission and resonance Raman spectra of 7-hydroxyquinoline and 8-bromo-7-hydroxyquinoline caged acetate.；J. Phys. Chem. A 2011, 115, 11632–11640.；
[ 33 ] Zheng, Xa., Du, Ra., Liu, Ca., Zhao, Ya., Pei, Ma., Wang, H. G.,a,*Li, M. Db., Xue, Jb., Phillips, D. L.b,*；Resonance Raman spectroscopic and theoretical investigation of the excited state proton transfer reaction dynamics of 2-thiopyridone.；J. Phys. Chem.B 2011, 115, 8266-8277.；
[ 34 ] Ma, J., Li, M. D., Phillips, D. L.,* Wan, P.*；Reaction mechanisms and structural characterization of the reactive intermediates observed after the photolysis of 3-(hydroxymethyl)benzophenone in acetonitrile, 2-propanol and neutral and acidic aqueous solutions.；J. Org. Chem. 2011, 76, 3710-3719.；
[ 35 ] Du, Y., Xue, J., Li, M. D., Guan, X., McCamant, D. W., Phillips, D. L.*；Unraveling the reaction mechanism for the fast photocyclisation of 2-benzoylpyridine in aqueous solvent by time-resolved spectroscopy and density functional theory calculations.；Chem. Eur. J. 2010, 16, 6961-6972.；
[ 36 ] Cao, Q.,a Guan, X.,b George, M. W.,a,* Phillips, D. L.,b,* Ma, C.,b Kwok, W. M.,bLi, M. D.,b Du, Y.,b Sun, X. Z.,aXue, J.b；Ultrafast time-resolved transient infrared and resonance Raman spectroscopic study of the photo-deprotection and rearrangement reactions of p-hydroxyphenacyl caged phosphates.；Faraday Discuss.2010, 145, 171-183.；
[ 37 ] Du, Y., Xue, J., Li, M. D., Phillips, D. L.*；Time-resolved resonance Raman and density functional theory investigation of the photoreactions of benzophenone in aqueous solution.；J. Phys. Chem. A 2009, 113, 3344-3352.；
[ 38 ] Chuang, Y. P., Xue, J., Du, Y., Li, M. D., An, H. Y., Phillips, D. L.*；Time-resolved resonance Raman and density functional theory investigation of the photochemistry of (S)-ketoprofen.；J. Phys. Chem. B 2009, 113, 10530-10539.；