重庆大学化学化工学院蔡云飞

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蔡云飞，男，1986年2月出生，重庆璧山人，理学博士。2017年重庆大学“百人计划”引进人才，现为特聘研究员，博士生导师。
联系方式
电话：15928708564
E-mail: yf.cai@cqu.edu.cn；522874321@qq.com
通信地址：重庆市沙坪坝区大学城南路55号 重庆大学虎溪校区理科楼化学化工学院（邮编：401331）
研究方向
主要研究方向：有机合成新方法的开发及其在具有重要生理活性或药用价值分子合成中的应用
主要研究内容：不对称催化与合成，可见光催化，纳米材料催化，酶催化。欢迎有意向读硕、读博的同学报考。
代表性论文、专著和专利
1.      Yunfei Cai, Yurong Tang, Iuliana Atodiresei, and Magnus Rueping*, Catalytic Asymmetric Piancatelli Rearrangement:  Br➢nsted Acid Catalyzed 4p Electrocyclization for the Synthesis of Multisubstituted Cyclopentenones, Angew. Chem. Int. Ed. 2016,55, 14126 –14130.
2.      Yunfei Cai, Xiaohua Liu, Yonghai Hui, Jun Jiang, Wentao Wang, Weiliang Chen, Lili Lin, and Xiaoming Feng*,Catalytic Asymmetric Bromoamination of Chalcones: Highly Efficient Synthesis of Chiral α-Bromo-β-Amino Ketone Derivatives, Angew. Chem. Int. Ed. 2010, 49, 6160–6164. (VIP paper; Highlighted by Angew. Chem. Int. Ed. 2011, 50, 7734 andSynfacts2010, 6, 1261.)
3.      Yunfei Cai, Xiaohua Liu, Jun Jiang, Weiliang Chen, Lili Lin, and Xiaoming Feng*, Asymmetric Chloroamination Reaction of α,β-Unsaturated γ-Keto Esters and Chalcones, J. Am. Chem. Soc.2011, 133, 5636–5639. (Invited to write SynstoryJuly, 2011; Highlighted by Synfacts2011, 7,0757.)
4.      Yunfei Cai,Pengfei Zhou, Xiaohua Liu, Jiannan Zhao, Lili Lin and Xiaoming Feng*, Diastereoselectively Switchable Asymmetric Haloaminocyclization for the Synthesis of Cyclic Sulfamates, Chem. Eur. J. 2015, 21, 6386–6389.
5.      Yunfei Cai,Xiaohua Liu, Pengfei Zhou, Yulong Kuang, Lili Lin and Xiaoming Feng*, Iron–Catalyzed Asymmetric Haloamination Reactions, Chem. Commun. 2013, 49, 8054–8056.
6.      Yunfei Cai, Jun Li, Weiliang Chen, Mingsheng Xie, Xiaohua Liu, Lili Lin, and Xiaoming Feng*, Catalytic Asymmetric Sulfenylation of Unprotected 3-Substituted Oxindoles, Org. Lett. 2012, 14, 2726–2729. (Highlighted by Synfacts2012,8,0998.)
7.      Yunfei Cai, Xiaohua Liu, Jun Li, Wentao Wang, Weiliang Chen, Lili Lin and Xiaoming Feng*, Asymmetric Iodoamination of Chalcones and 4-Aryl-4-oxobutenoates Catalyzed by a Complex Based on Scandium(III) and a N,N′-Dioxide Ligand, Chem. Eur. J. 2011, 17, 14916–14921.
8.      Yunfei Cai, Wentao Wang, Ke Shen, Jun Wang, Xiaolei Hu, Lili Lin,Xiaohua Liu and Xiaoming Feng*, Highly enantioselective α-chlorination of cyclic β-ketoesters catalyzed by N,N’-Dioxide using NCS as the chlorine source, Chem. Commun. 2010, 46, 1250–1252. (Highlighted by Synfacts2010, 0477.)
9.      Pengfei Zhou, Yunfei Cai, Xia Zhong, Weiwei Luo, Tengfei Kang, Jun Li, Xiaohua Liu*, Lili Lin, and Xiaoming Feng*, Catalytic Asymmetric Intra- and Intermolecular Haloetherification of Enones: An Efficient Approach to (−)-Centrolobine, ACS Catal., 2016, 6, 7778–7783.
10.  Pengfei Zhou, Yunfei Cai, Lili Lin, Xiangjin Lian, Yong Xia, Xiaohua Liu and Xiaoming Feng*, Asymmetric Synthesis of Spirocyclic Oxindole-Fused Tetrahydrothiophenes via N,N′-Dioxide–Nickel(II) Catalyzed Domino Reaction of 1,4-Dithiane-2,5-diol with 3-Alkenyloxindoles, Adv. Syn. Cat.2015, 357, 695-700.
11.  Jun Li, Yunfei Cai, Weiliang Chen, Xiaohua Liu, Lili Lin, and Xiaoming Feng*, Highly Enantioselective Fluorination of Unprotected 3 Substituted Oxindoles: One-Step Synthesis of BMS 204352 (MaxiPost), J. Org. Chem.2012, 77,9148–9155.
12.  Jun Jiang, Yunfei Cai, Weiliang Chen, Lili Lin, Xiaohua Liu and Xiaoming Feng*, Enantioselective aza-Michael reaction of hydrazide to chalcones through the nonactivated amine moiety conjugated addition, Chem. Commun.2011, 47, 4016–4018.
13.  Weiliang Chen, Yunfei Cai, Xuan Fu, Xiaohua Liu, Lili Lin, and Xiaoming Feng*, Enantioselective One-Pot Synthesis of 2-Amino-4-(indol-3-yl)-4H-Chromenes, Org. Lett. 2011, 13, 4910–4913.
14.  Ke Shen, Xiaohua Liu, Yunfei Cai, Lili Lin, Xiaoming Feng*, Facile and Efficient Enantioselective Strecker Reaction of Ketimines by Chiral Sodium Phosphate, Chem. Eur. J. 2009,15, 6008–6014.
15.  Weiliang Chen, Lili Lin, Yunfei Cai, Yong Xia, Weidi Cao, Xiaohua Liu and Xiaoming Feng *, Catalytic asymmetric [3+2] cycloaddition of aromatic aldehydes with oxiranes by C–C bond cleavage of epoxides: highly efficient synthesis of chiral 1,3-dioxolanes, Chem. Commun.2014, 50, 2161–2163.
16.  Huifeng Yue, Lin Guo, Hsuan-Hung Liao, Yunfei Cai, Chen Zhu and Magnus Rueping*, Catalytic Ester and Amide to Amine Interconversion: Nickel-Catalyzed Decarbonylative Amination of Esters and Amides by C−O and C−C Bond Activation, Angew. Chem. Int. Ed. 2017, 56, 4282–4285.
17.  Wei Li, Xiaohua Liu, Xiaoyu Hao, Yunfei Cai, Lili Lin, and Xiaoming Feng*, A Catalytic Asymmetric Ring-Expansion Reaction of Isatins and a-Alkyl-a-Diazoesters: Highly Efficient Synthesis of Functionalized 2-Quinolone Derivatives, Angew. Chem. Int. Ed. 2012, 51, 8644–8647.
18.  Xiao Xiao, Xiaohua Liu, Shunxi Dong, Yunfei Cai, Lili Lin, Xiaoming Feng*, Asymmetric Synthesis of 2,3-Dihydroquinolin-4-one Derivatives Catalyzed by a Chiral Bisguanidium Salt, Chem. Eur. J. 2012, 18, 15922–15926.
19.  Mingsheng Xie, Xiaohua Liu, Xiaoxia Wu, Yunfei Cai, Lili Lin, Xiaoming Feng*, Catalytic Asymmetric [8+2] Cycloaddition: Synthesis of Cycloheptatriene-Fused Pyrrole Derivatives, Angew. Chem. Int. Ed. 2013, 52, 5604-5607.
20.  Yonghai Hui, Jun Jiang, Wentao Wang, Weiliang Chen, Yunfei Cai, Lili Lin, Xiaohua Liu, Xiaoming Feng*, Highly Enantioselective Conjugate Addition of Thioglycolate to Chalcones Catalyzed by Lanthanum: Low Catalyst Loading and Remarkable Chiral Amplification, Angew. Chem. Int. Ed. 2010, 49, 4290-4293.
21.  Weiliang Chen, Yonghai Hui, Xin Zhou, Jun Jiang, Yunfei Cai, Xiaohua Liu, Lili Lin, Xiaoming Feng*, Chiral N,N'-Dioxide-Yb(III) Complexes Catalyzed Enantioselective Hydrophosphony- lation of Aldehydes, Tetrahedron Lett. 2010, 51, 4175–4178.
22.  Yonghai Hui, Weiliang Chen, Wentao Wang, Jun Jiang, Yunfei Cai, Lili Lin, Xiaohua Liu, Xiaoming Feng*, Highly Enantioselective Zinc-Catalyzed Friedel–Crafts Alkylation of Indoles with Ethyl Trifluoropyruvate, Adv. Syn. Cat.2011, 18, 3174-3178.
23.  Zhen Wang, Zuliang Zhang, Qian Yao, Xiaohua Liu, Yunfei Cai, Lili Lin, Xiaoming Feng*, Highly Stereoselective Conjugate Addition and α-Alkynylation Reaction with Electron-Deficient Alkynes Catalyzed by Chiral Scandium(III) Complexes, Chem. Eur. J. 2013, 19, 8591–8596.