南京工业大学化学与分子工程学院何广科

xiaoshoubuyi

E-mail: hegk@njtech.edu.cn

学习及工作经历

    *2010/07–至今，南京工业大学工作

* 2005/12 – 2009/12，浙江大学，理学博士

* 2002/09 – 2005/06，浙江大学，工学硕士

* 1998/09 – 2002/07，江苏石油化工学院，学士

<span]研究方向

]主持的科研项目

*  江苏省高校自然科学基金面上项目(12KJB150011)

*  江苏省青年自然科学基金(BK20140937)

近3年科研论文

*  Zhu, G.; Qiu, S.; Xi, Y.; Ding, Y.; Zhang D.; Zhang R.;He, G.*; Zhu, H*. (IPr)CuF-catalyzed α-site regiocontrolled trans-hydrofluorination of ynamides Org. Biomol. Chem., 2016, 14, 7746–7753.

*  He, G.; Qiu, S.; Zhu, G.; Zhang D.; Zhang R.; Zhu, H*. Cu(I)- or Ag(I)-Catalyzed Regio- and Stereocontrolled trans-Hydrofluorination of Ynamides, Org. Lett., 2016, 18, 1856–1859.

*  Huang, H.; Tang, L.; Yang, Z.; Liu, Q.; Xi, Y.; He, G.*, Zhu, H*. Formation of α-chalcogenyl acrylamides through unprecedented chalcogen-mediated metal-free oxyfunctionalization of ynamides with DMSO as an oxidant, Chem. Commun., 2016, 52, 5605–5608.

*  Huang, H.; Fan, J.; He, G.*; Yang, Z.; Jin, X.; Liu, Q.; Zhu, H*. Generation of Oxazolidine-2,4-diones Bearing Sulfur-Substituted Quaternary Carbon Atoms by Oxothiolation/Cyclization of Ynamides, Chem. Eur. J. 2016, 22, 2532–2538.

*  Huang, H.; Zhu, X.; He, G.*; Liu, Q.; Fan, J.; Zhu, H*. Controlled Synthesis of 1,3,5-Oxadiazin-2-ones and Oxazolones through Regioselective Iodocyclization of Ynamides, Org. Lett. 2015, 17, 2510–2513.

*  He, G.; Chen, S.; Wang, Q.; Huang, H.; Zhang, Q.; Zhang, D.; Zhang, R.; Zhu, H*. Studies on copper(I)-catalyzed highly regio- and stereo-selective hydroboration of alkynamides,Org. Biomol. Chem. 2014, 12, 5945–5953.

*  He, G.; Zhang, Q.; Huang, H.; Chen, S.; Wang, Q.; Zhang, D.; Zhang, R.; Zhu, H*. Copper(I)-Catalyzed Highly Regio- and Stereoselective Boron Addition–Protonolysis of Alkynamides to give Alkenamides, Eur. J. Org. Chem. 2013, 2013, 6979–6989.

*  何广科，陈山，马鸿飞，王强，朱红军*。 克莱森酯缩合反应中碱性试剂作用的探讨， 化学教育，2014, 35, 57–59.