苏州大学材料与化学化工学部张茂杰

filament

张茂杰，苏州大学教授。2011年毕业于中国科学院化学研究所获博士学位，导师李永舫院士；2011年至2014年在中国科学院化学研究所高分子物理与化学国家重点实验室工作。2013年获北京市科学技术奖二等奖。2014年获国家基金委优秀青年科学基金资助。2014年9月受聘苏州大学材化部，特聘教授，博士生导师。主要从事聚合物太阳能电池方面的研究工作，迄今为止共发表SCI研究论文60余篇，刊物包括Adv. Mater.、Energy Environ. Sci.、Adv. Energy Mater.、Adv. Funct. Mater.、Chem. Mater.、Macromolecules等。发表论文SCI他人引用1700余次，H因子27。


姓名：张茂杰
职称：教授、博士生导师
部门：材料学院
联系方式：
苏州大学，苏州市仁爱路199号，215213
Tel：+86-512-65883576；Email: mjzhang@suda.edu.cn
国家优秀青年科学基金获得者

研究领域：
聚合物光伏材料的设计与合成；聚合物太阳能电池器件构筑与器件物理。

代表性论文：
1.    Maojie Zhang, Xia Guo, Wei Ma*, Harald Ade, Jianhui Hou*, A Polythiophene Derivative with Superior Properties for the Practical Application in Polymer Solar Cells. Adv. Mater., 2014, 26, 5880-5885.
2.      Maojie Zhang, Xia Guo, Shaoqing Zhang, and Jianhui Hou*, Synergistic Effect of Fluorination on Molecular Energy Level Modulation in Highly Efficient Photovoltaic Polymers, Adv. Mater., 2014, 26, 1118-1123.
3.       Maojie Zhang, Xia Guo, Wei Ma*, Shaoqing Zhang, Lijun Huo, Harald Ade, Jianhui Hou*, An Easy and Effective Method to Modulate Molecular Energy Level of D-A Polymer for the Application in Polymer Solar Cells, Adv. Mater., 2014, 26, 2089-2095.
4.       Maojie Zhang, Yu Gu, Xia Guo, Feng Liu, Shaoqing Zhang, Lijun Huo, Thomas P. Russell* and Jianhui Hou*, Efficient Polymer Solar Cells Based on Benzothiadiazoleand Alkylphenyl Substituted Benzodithiophene with a Power Conversion Efficiency over 8%, Adv. Mater., 2013, 25, 4944-4949.
5.       Xia Guo, Maojie Zhang*, Wei Ma*, Long Ye, Shaoqing Zhang , Shengjian Liu, Harald Ade, Fei Huang*, Jianhui Hou*, Enhanced Photovoltaic Performance by Modulating Surface Composition in Bulk Heterojunction Polymer Solar Cells Based on PBDTTT-C-T/PC71BM. Adv. Mater., 2014, 26, 4043-4049.
6.       Xia Guo, Maojie Zhang*, Jiahui Tan, Shaoqing Zhang, Lijun Huo, Wenping Hu*, Yongfang Li*, and Jianhui Hou*, Influence of D/A Ratio on Photovoltaic Performance of a Highly Efficient Polymer Solar Cell System, Adv. Mater., 2012, 24, 6536-6541.
7.       Maojie Zhang, Xia Guo, Yongfang Li*, Synthesis and characterization of a D-A copolymer based on dithienosilole and thiazolothiazole for polymer solar cells, Adv. Energy Mater., 2011, 1, 557-560.
8.       Maojie Zhang, Xia Guo, Xiaochen Wang, Haiqiao Wang, Yongfang Li*, Synthesis and Photovoltaic Properties of D-A Copolymers Based on Alkyl-Substituted Indacenodithiophene Donor Unit, Chem. Mater., 2011. 23, 4264-4270.
9.       Maojie Zhang, Yeping Sun, Xia Guo, Chaohua Cui, Shanshan Wang, Youjun He, Yongfang Li*, Synthesis and Characterization of Dioctyloxybenzo[1,2-b:4,3-b']-dithiophene- Containing Copolymers for Polymer Solar Cells, Macromolecules, 2011, 44, 7625-7631.
10.     Maojie Zhang, Xia Guo, Yongfang Li*, Photovoltaic Performance Improvement of D-A Copolymers Containing Bithiazole Acceptor Unit by Using Bithiophene Bridges, Macromolecules, 2011, 44, 8798-8804.
11.     Maojie Zhang, Haijun Fan, Xia Guo, Youjun He, Zhi-Guo Zhang, Jie Min, Jing Zhang, Guangjin Zhao, Xiaowei Zhan*, Yongfang Li*, Synthesis and Photovoltaic Properties of Bithiazole-Based Donor-Acceptor Copolymers, Macromolecules, 2010, 43, 5706-5712.
12.     Maojie Zhang, Haijun Fan, Xia Guo, Youjun He, Zhi-Guo Zhang, Jie Min, Jing Zhang, Guangjin Zhao, Xiaowei Zhan, Yongfang Li*, Synthesis and Photovoltaic Properties of a Copolymer of Benzo[1,2-b:4,5-b’]dithiophene and Bithiazole, Macromolecules, 2010, 43, 8714-8717.
13.     Xia Guo, Maojie Zhang*, Lijun Huo, Chaohua Cui, Yue Wu, Jianhui Hou,* and Yongfang Li*, Poly(thieno[3,2-b]thiophene-alt-bithiazole): A D-A Copolymer Donor Showing Improved Photovoltaic Performance with Indene-C60 Bisadduct Acceptor, Macromolecules, 2012, 45, 6930-6937.
14.     Xia Guo, Maojie Zhang*, Chaohua Cui, Jianhui Hou*, and Yongfang Li*， Efficient Polymer Solar Cells Based on Poly(3-hexylthiophene) and Indene-C60 Bisadduct Fabricated with Non-Halogenated Solvents ACS Applied Materials & Interfaces, 2014, 6, 8190-8196.
15.     Maojie Zhang, Xia Guo, Zhi-Guo Zhang, Yongfang Li*, D-A copolymers based on dithienosilole and phthalimide for photovoltaic materials, Polymer, 2011, 52, 5464-5470.
16.     Maojie Zhang, Haijun Fan, Xia Guo, YangYang, Shanshan Wang, Zhi-Guo Zhang, Jing Zhang, Xiaowei Zhan, and Yongfang Li*, Synthesis and photovoltaic properties of copolymers based on bithiophene and bithiazole, J. Polym. Sci. A: Polym. Chem., 2011, 49, 2746-2754.
17.     Maojie Zhang, Xia Guo, Yang Yang, Jing Zhang, Zhi-Guo Zhang, Yongfang Li*, Downwards tuning the HOMO level of polythiophene by carboxylate substitution for high open-circuit-voltage polymer solar cells, Polym. Chem., 2011, 2, 2900-2906.
18.     Weina Yong, Maojie Zhang*, Xiaodong Xin, Zhaojun Li, Yue Wu, Xia Guo, Zhou Yang* and Jianhui Hou*, Solution-processed indacenodithiophene-based small molecule for bulk heterojunction solar cells, J. Mater. Chem. A, 2013, 1, 14214-14220.
19.     Youguang Huang, Maojie Zhang*, Yan Jing, Huili Fan,* Xia Guo, Yongfang Li* Synthesis and Photovoltaic Properties of a Donor-Acceptor Copolymer of Dithienosilole and 5, 6-Bis(octyloxy)benzo[1,2,5]thiadiazole, Macromol. Chem. Phys., 2012, 213, 2529-2535.

diergutu

聚合物太阳能电池( PSCs )作为一种新兴的清洁能源技术，由于其具有半透明性、柔性以及可大面积制备等优点，近年来受到了广泛关注。近三年来，n型有机半导体(n-OSs)作为非富勒烯(NF)受体在高性能PSCs中得到了蓬勃发展，这是因为与传统富勒烯衍生物相比，n型有机半导体具有前体来源广泛、制备成本低、吸收和能级可调、能量损失小、形貌稳定性高等优点。迄今为止，单结NF-PSCs的功率转换效率(PCEs)已达到11–13%。在与宽带隙聚合物共混时，IT-4F基PSCs显示出高达13.1 %的PCE。由于良好匹配的聚合物给体和n - OS受体在获得高效PSCs中起着至关重要的作用，因此广泛的合成变化(如原子取代、侧链修饰和引入芳族稠环)被用于优化高性能聚合物给体。其中原子取代，特别是氟(F)原子取代氢原子引起了人们的广泛关注，并在分子设计中得到了广泛的应用

近日，来自苏州大学的张茂杰教授团队在Nano Energy发文，题为：“Chlorine substituted 2D-conjugated polymer for high-performance polymer solar cells with 13.1% efficiency via toluene processing”。研究人员设计并合成了一种新的D-A型两维共轭聚合物PM7，它含有氯化噻吩基苯并二噻吩( BDT - 2Cl )给体单元和苯并二噻吩-4，8-二酮受体单元。与无氯取代的对照聚合物PBDB-T相比，PM7具有较低的HOMO能级、较高的吸收系数、较强的结晶性和较高的载流子迁移率。此外，以PM7为给体、IT-4F为受体的光伏器件在使用非卤溶剂甲苯做溶剂时，在获得0.88 V的高开路电压、20.9 mA·cm-2的短路电流密度的同时，填充因子( FF )为71.1 %的，从而取得了13.1 %的能量转化效率( PCE )。而相同条件下， PBDB - T : IT - 4F体系的PSC在低Voc为0.67 V的条件下仅表现出5.8 %的低PCE。13.1%的PCE是迄今为止报告的非卤溶剂制备的光伏器件能量转化效率最高值之一。这些结果表明，氯取代是设计高性能共轭聚合物光伏材料的一种简单有效的策略。

dieluo

高效全聚合物太阳能电池中受体材料的合成及器件性能优化
批准号        51973146       
学科分类        光电磁信息功能材料 ( E030901 )
项目负责人        张茂杰       
依托单位        苏州大学
资助金额        61.00万元       
项目类别        面上项目       
研究期限        2020 年 01 月 01 日 至2023 年 12 月 31 日