华中科技大学化学与化工学院材料与环境化学研究所夏宝玉

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夏宝玉，华中科技大学教授，博士生导师。2010年毕业于上海交通大学大学，获工学博士学位。2011年至2016年在新加坡南洋理工大学能源研究所和化学与生物工程学院工作。主要从事结构功能材料的设计及其在能源、环境等领域应用的教学与研究工作，包括研发新型水电解池、燃料电池、金属空气电池以及二氧化碳转换等能源技术，并在新能源与新材料工程领域取得一系列创新性研究成果。近些年在国际学术期刊发表论文49篇，包括Nat. Energy 1篇，Nat. Commun. 1篇，J. Am. Chem. Soc. 3篇，Angew. Chem. Int. Ed. 6篇，Adv. Mater. 2篇，Energy Environ. Sci. 1篇等。发表论文包括2篇ESI热点论文 (hot paper) 、15篇ESI高被引论文、4篇封面论文、1篇VIP论文和2篇热点论文 (Angew. Chem.)，研究成果被ChemistryViews和MaterialsViews等多个国内外媒体报道。截止目前，论文被国内外同行引用超过2500余次，单篇最高被引用次数达到250次，单篇引用次数超过100次的有12篇，H指数25。2016年获RSC Top 10 Reviewers for J Mater Chem.

姓名： 夏宝玉  Bao Yu, Xia

出生年月：

学历：博士

职称：教授

专业方向：材料、物理、化学

电话：

Email：byxia@hust.edu.cn

个人主页：https://www.researchgate.net/profile/Bao_Yu_Xia

教育与研究经历

2016- , School of Chemistry and ChemicalEngineering, Huazhong University of Science and Technology (HUST), PR China

2012-2016, School of Chemical andBiomedical Engineering, Nanyang Technological University (NTU), Singapore

2011-2012, Energy Research Institute@NTU,Nanyang Technologica University (NTU), Singapore

2006-2010, School of Materials Science andEngineering, Shanghai Jiao Tong University (SJTU), PR China

研究领域与兴趣

Our work and goals are to design andprepare nanostructures for energy harvesting applications. We focused onnanocatalysts with electrochemical technologies for the future clean, green andsustainable energy and environments.

教学情况

2016 《工程化学》

2017 《能源化学》

承担项目与课题

1，中组部计划 2016-2019

2，华中科技大学人才引进基金2016-2019

3，华中科技大学自主创新基金2016-2017

4，深圳市科创委基金 2016-2018

5，青岛储能基金 2016-2017

学术兼职

1, Guest Editor of Journal ofNanomaterials

2, Referee for ACS, Wiley, RSC and Elsevier journals,including JACS, Angew Chem, Adv Mater, Chem Commun, J Mater Chem etc

3, 2016 Top 10 Reviewersfor Journal of Materials Chemistry

代表性成果

For full publication list please referto Google Scholar or Researchgate: https://scholar.google.com/citations?user=AHJbZFEAAAAJ&hl=en

2017

51, H. Wang, W. Wang, Y. Xu, S. Dong, J.Xiao, F. Wang, H. Liu*, Xia BY*, ACS Applied Materials &Interfaces 2017.

50. Cai Y,Xia BY (Co-firstauthor), Franklin J, Li B, Wang X, Wang Z, Chen L, Lin J, Lai L, Shen Z, Journalof Materials Chemistry A. 2017, 5 (6), 2488.

2016

49. Y. Yan, B. Y. Xia, B.Zhao, X. Wang, J. Mater. Chem. A 2016, 4, 17587.

48. Xia BY, Yan Y, Li N, Wu HB,Lou XW, Wang X. A metal–organic framework-derived bifunctional oxygenelectrocatalyst. Nature Energy. 2016; 1: 15006.

47. Xie MS, Xia BY (Co-firstauthor), Li Y, Yan Y, Yang Y, Sun Q, et al. Amino acid modified copperelectrodes for the enhanced selective electroreduction of carbon dioxidetowards hydrocarbons. Energy & Environmental Science.2016;9(5):1687-1695 (Cover Paper).

46. Yu L, Xia BY, Wang X, LouXW. General formation of M–MoS3 (M= Co, Ni) hollow structures with enhancedelectrocatalytic activity for hydrogen evolution. Advanced Materials.2016;28(1):92-97

45. Ma R, Xia BY, Zhou Y, Li P,Chen Y, Liu Q, et al. Ionic liquid-assisted synthesis of dual-doped graphene asefficient electrocatalysts for oxygen reduction. Carbon. 2016; 102:58-65.

44. Ma R, Ren X, Xia BY, ZhouY, Sun C, Liu Q, et al. Novel synthesis of N-doped graphene as an efficientelectrocatalyst towards oxygen reduction. Nano Research. 2016:1-12.

43. Lü X, Xia BY, Liu C, YangY, Tang H. TiO2-Based Nanomaterials for Advanced Environmental andEnergy-Related Applications. Journal of Nanomaterials. 2016.

42. Li FM, Kang YQ, Peng RL, Li SN, XiaBY*, Liu ZH, et al. Sandwich-structured Au@polyallylamine@Pdnanostructures: tuning the electronic properties of the Pd shell forelectrocatalysis. Journal of Materials Chemistry A. 2016;4(31):12020-12024(ESI highly cited paper).

2015

41. Yan Y, Xia BY, Ge X, Liu Z,Fisher A, Wang X. A flexible electrode based on iron phosphide nanotubes foroverall water splitting. Chemistry–A European Journal.2015;21(50):18062-18067.

40. Yan Y, Thia L, Xia BY, GeX, Liu Z, Fisher A, et al. Construction of Efficient 3D Gas EvolutionElectrocatalyst for Hydrogen Evolution: Porous FeP Nanowire Arrays on GrapheneSheets. Advanced Science. 2015;2(8) (MaterialsViews reported).

39. Xia BY, Wu HB, Li N, Yan Y,Lou XW, Wang X. One‐Pot Synthesis of Pt–Co Alloy Nanowire Assemblies withTunable Composition and Enhanced Electrocatalytic Properties. AngewandteChemie International Edition. 2015;127(12):3868-3872 (ESI highly citedpaper).

38. Wu HB, Xia BY (Co-firstauthor), Yu L, Yu X-Y, Lou XW. Porous molybdenum carbide nano-octahedronssynthesized via confined carburization in metal-organic frameworks forefficient hydrogen production. Nature Communications. 2015; 6:6512(ESI hot paper, ESI highly cited paper).

37. Ma L, Wang C, Xia BY (Co-firstauthor), Mao K, He J, Wu X, et al. Platinum Multicubes Prepared byNi2+‐Mediated Shape Evolution Exhibit High Electrocatalytic Activity for OxygenReduction. Angewandte Chemie International Edition.2015;127(19):5758-5763.

36. Ma FX, Wu HB, Xia BY, XuCY, Lou XW. Hierarchical β‐Mo2C Nanotubes Organized by Ultrathin Nanosheets asa Highly Efficient Electrocatalyst for Hydrogen Production. AngewandteChemie International Edition. 2015;54(51):15395-15399.

35. Hu H, Guan B, Xia BY, LouXW. Designed formation of Co3O4/NiCo2O4 double-shelled nanocages with enhancedpseudocapacitive and electrocatalytic properties. Journal of theAmerican Chemical Society. 2015;137(16):5590-5595 (ESI hotpaper, ESI highly cited paper).

34. Fu GT, Xia BY (Co-firstauthor), Ma RG, Chen Y, Tang YW, Lee JM. Trimetallic PtAgCu@PtCu core@shellconcave nanooctahedrons with enhanced activity for formic acid oxidationreaction. Nano Energy. 2015; 12:824-832 (ESI highly cited paper).

2014

33. Yan Y, Xia BY, Xu Z, WangX. Recent development of molybdenum sulfides as advanced electrocatalysts forhydrogen evolution reaction. ACS Catalysis. 2014;4(6):1693-1705 (Invited Reviewarticle, ESI highly cited paper).

32. Xia BY, Wu HB, Yan Y, WangHB, Wang X. One‐Pot Synthesis of Platinum Nanocubes on Reduced Graphene Oxidewith Enhanced Electrocatalytic Activity. Small. 2014;10(12):2336-2339 (MaterialsViewsreported).

31. Xia BY, Yan Y, Wang X, LouX-W. Recent Progress on Graphene-based Hybrid Electrocatalysts. MaterialsHorizons. 2014; 1:379-399 (Invited Reviewarticle, ESI highly cited paper).

30. Wu T, Zhou HM,Xia BY, Xiao P,Yan Y, Xie MS, et al. Facile Synthesis of 3 D Platinum Dendrites with a CleanSurface as Highly Stable Electrocatalysts. ChemCatChem. 2014;6(6):1538-1542.

29. Song SS, Xia BY (Co-firstauthor), Chen J, Yang J, Shen X, Fan SJ, et al. Two dimensional TiO2nanosheets: in vivo toxicity investigation. RSC Advances. 2014;4(80):42598-42603.

28. Li N, Yan Y, Xia BY, WangJ-Y, Wang X. Novel tungsten carbide nanorods: an intrinsic peroxidase mimeticwith high activity and stability in aqueous and organic solvents. Biosensorsand Bioelectronics. 2014; 54:521-527.

27. Li CC, Zhang W, Ang H, Yu H, XiaBY, Wang X, et al. Compressed hydrogen gas-induced synthesis of Au–Ptcore–shell nanoparticle chains towards high-performance catalysts for Li–O2batteries. Journal of Materials Chemistry.2014;2(27):10676-10681.

2013

26. Zhang G, Xia BY, Xiao C, YuL, Wang X, Xie Y, et al. General Formation of Complex Tubular Nanostructures ofMetal Oxides for the Oxygen Reduction Reaction and Lithium‐Ion Batteries. AngewandteChemie International Edition. 2013;125(33):8805-8809 (ESI highlycited paper, Cover paper).

25. Zhang G, Xia BY, Wang X,Lou XW. Strongly Coupled NiCo2O4‐rGO Hybrid Nanosheets as a Methanol‐TolerantElectrocatalyst for the Oxygen Reduction Reaction. Advanced Materials.2014. 26(15):2408-2412 (ESI highly cited paper).

24. Yan Y, Xia BY, Qi X, Wan H,Zhang H, Wang X. Nano-Tungsten Carbide Decorated Graphene as Co-catalysts forEnhanced Hydrogen Evolution on Molybdenum Disulfide. ChemicalCommunications. 2013,49(43):4884-4886 (Cover paper).

23. Yan Y, Xia BY, Ge X, Liu Z,Wang J-Y, Wang X. Ultrathin MoS2 nanoplates with rich active sites as highlyefficient catalyst for hydrogen evolution. ACS applied materials &interfaces. 2013;5(24):12794-12798 (ESI highly cited paper).

22. Xia BY, Wu HB, Yan Y, LouXW, Wang X. Ultrathin and ultralong single-crystal platinum nanowire assemblieswith highly stable electrocatalytic activity. Journal of the AmericanChemical Society. 2013;135(25):9480-9485 (ESI highly cited paper).

21. Xia BY, Wu HB, Wang X, LouXW. Highly Concave Platinum Nanoframes with High‐Index Facets and EnhancedElectrocatalytic Properties. Angewandte Chemie International Edition.2013;52(47):12337-12340 (VIP paper, Hot paper, ESI highly cited paper).

20. Wang H, Xia BY, Yan Y, LiN, Wang J-Y, Wang X. Water-soluble polymer exfoliated graphene: as catalystsupport and sensor. The Journal of Physical Chemistry B.2013;117(18):5606-5613.

2012

19. Zhu T, Xia BY, Zhou L, LouXW. Arrays of Ultrafine CuS Nanoneedles Supported on CNT Backbone forApplication in Supercapacitors. Journal of Materials Chemistry. 2012;22:7851-7855 (ESI highly cited paper).

18. Xia BY, Wu HB, Wang X, LouXW. One-pot synthesis of cubic PtCu3 nanocages with enhanced electrocatalyticactivity for the methanol oxidation reaction. Journal of the AmericanChemical Society. 2012;134(34):13934-13937 (ESI highly cited paper).

17.Xia BY, Wu HB, Chen JS, Wang Z,Wang X, Lou XW. Formation of Pt–TiO2–rGO 3-phase junctions with significantlyenhanced electro-activity for methanol oxidation. Physical Chemistry ChemicalPhysics. 2012;14(2):473-476.

16. Xia BY, Wang B, Wu HB, LiuZ, Wang X, Lou XW. Sandwich-structured TiO2–Pt–graphene ternary hybridelectrocatalysts with high efficiency and stability. Journal of MaterialsChemistry. 2012;22(32):16499-16505.

15. Xia BY, Ng WT, Wu HB, WangX, Lou XW. Self‐Supported Interconnected Pt Nanoassemblies as Highly StableElectrocatalysts for Low‐Temperature Fuel Cells. Angewandte ChemieInternational Edition. 2012;124(29):7325-7328 (ESI highly citedpaper, hot paper, ChemistryViews reported).

14. Xia BY, Ding S, Wu HB,Wang X, Wen X. Hierarchically structured Pt/CNT@ TiO2 nanocatalysts withultrahigh stability for low-temperature fuel cells. RSC Advances.2012;2(3):792-796.

13. Liu WW,Xia BY, Wang X-X, WangJN. Exfoliation and dispersion of graphene in ethanol-water mixtures. Frontiersof Materials Science. 2012;6(2):176-182.

2011

12. Zhang X, Xia BY, Song J,Chen B, Tian X, Hao Y, et al. Effects of equal channel angular extrusion andaging treatment on R phase transformation behaviors and Ti3Ni4 precipitates ofNi-rich TiNi alloys. Journal of Alloys and Compounds.2011;509(21):6296-6301.

2010

11. Zhang X, Song J, Huang C, XiaBY, Chen B, Sun X, et al. Microstructures evolution and phasetransformation behaviors of Ni-rich TiNi shape memory alloys after equalchannel angular extrusion. Journal of Alloys and Compounds.2010;509(21):3006-3012.

10. Xia BY, Wang JN, Teng SJ,Wang XX. Durability Improvement of a Pt Catalyst with the Use of a GraphiticCarbon Support.Chemistry-A European Journal. 2010;16(28):8268-8274.

9. Wu ZP,Xia BY, Wang XX, Wang JN.Preparation of dispersible double-walled carbon nanotubes and application ascatalyst support in fuel cells. Journal of Power Sources.2010;195(8):2143-2148.

8. Teng SJ, Wang XX, Xia BY,Wang JN. Preparation of hollow carbon nanocages by iodine-assisted heattreatment. Journal of Power Sources. 2010;195(4):1065-1070.

7. Teng SJ, Wang JN, Xia BY,Wang XX. A General Strategy for the Preparation of Hollow Carbon Nanocages byNH4Cl‐Assisted Low‐Temperature Heat Treatment. Chemistry–A EuropeanJournal. 2010;16(46):13603-13608.

Before 2010

6. Xia BY, Wang JN, Wang XX.Synthesis and Application of Pt Nanocrystals with Controlled CrystallographicPlanes. The Journal of Physical Chemistry C. 2009;113(42):18115-18120.

5. Xia BY, Wang JN, Wang XX,Niu JJ, Sheng ZM, Hu MR, et al. Synthesis and application of graphitic carbonwith high surface area.Advanced Functional Materials. 2008;18(12):1790-1798.

4. Zhang X-Y, Wu X-L, Zuo R-L, XiaBY, Zhou M-Z. Microstructure evolution of nanocrystalline nickel aftercold-rolled deformation. Chinese Journal of Nonferrous Metals. 2005;15(10):1607-1611.

3. Zhang X, Hu Z, Zhou S, Jia C, ZhouM, Xia BY. Study on the deformation of nanocrystallinecobalt. Philosophical Magazine Letters. 2005;85(11):595-601.

2. Zhang X, Hu Z, Wu X, Xia BY,Zhou M, Zhou S, et al. A Study on the Microstructure Characteristic of theCold-Rolled Deformed Nanocrystalline Nickel. Reviews on Advanced MaterialsScience. 2005;10(2):181-184.

1. Xi-Yan Z, Xiao-Lei W, Xia BY,Ming-Zhe Z, Shi-Jie Z, Chong J. Step structure in cold-rolled deformednanocrystalline Nickel. Chinese Physics Letters. 2005; 22:2335.

获奖与荣誉

2016，Excellence inReviewing for Chemsphere

2016，OutstandingReviewer for Journal of MaterialsChemistry A

2016，Top 10 Reviewers for Journal of Materials Chemistry

2016，中组部计划

2010，中科院严东生奖学金

2009，光华一等奖学金

2008，国家优秀奖学金

更多信息请浏览个人（或课题组）主页：https://www.researchgate.net/profile/Bao_Yu_Xia

youjiang

便携式电子产品和电动汽车对能源的需求成为了促使高效储能技术快速发展的动力。超级电容器是介于电容器和电池之间的储能器件，它既具有电容器可以快速充放电的特点，又具有电池的储能特性，具有高能量密度、快速充电速率和优异的长循环稳定性等优点。金属有机框架材料（MOFs）是由金属离子或金属簇与有机配体通过自组装配位形成的化合物。由于其高比表面积、可控的多孔结构、和丰富的拓扑结构而被广泛应用于储能领域。考虑到MOFs材料中的金属组分对电化学性能的影响和贡献，通过活化金属离子来提升电极材料的性能是目前常见的方法，然而这种活化却往往伴随着结构的严重破坏而不能最大限度地增强材料的电化学性能。

    华中科技大学夏宝玉课题组通过氧化还原策略来调控双金属Co-Ni MOF纳米薄片的结晶性和电子结构来增强材料法拉第电容。依次通过硼化和硫化处理后，得到稳定低价的混合价态的Co-Ni MOF衍生物（Co-Ni-B-S）。该衍生物不仅保存了原始Co-Ni MOF的结构完整性，活化后表现为部分晶态和非晶态共存的结构，有利于实现优异的电化学性能。测试结果表明：（1）活化后的Co-Ni-B-S样品在1 A g-1的电流密度下，可达到1281 F g-1的高比电容；（2）在20 A g-1的电流密度下，可达到802.9 F g-1的高比电容，具有出色的倍率性能；（3）经过10,000次循环后容量保留率可达到92.1％，表现出优良的循环性能稳定性。基于Co-Ni-B-S电极制造的储能装置在功率密度为857.7 W kg-1时表现出50.0 Wh kg-1的高能量密度，在12 A g-1下经过5000次循环，容量保持率可达到87.7％。同时，在以活性炭为负极组装的超级电容器器件的测试中，发现器件在水系电解液中可以得到1.7 V的高电压，给此材料的应用提供了更多的可能性。
    该工作所制备的材料不仅具有优异的电化学性能，还可以拓展到其他相关的能量转换技术，为调控MOFs的电子结构及构建高效的电极材料提供了新思路。相关成果在线发表于Adv. Mater.（DOI: 10.1002/adma.201905744）。
    原文链接：
https://www.materialsviewschina.com/2019/11/41402/
https://onlinelibrary.wiley.com/doi/10.1002/adma.201905744

huatai

随着能源短缺和环境污染问题的日益严峻，太阳能/风能等可再生清洁能源占据越来越重要的位置。开发新型高效的能源存储与转换技术（如燃料电池、金属-空气电池和电解水产氢）已然成为新能源产业发展的关键环节。其中，氧催化反应，即氧还原反应和氧析出反应，是众多能源存储与转换器件的核心反应，其性能直接决定着新能源器件的工作效率。因此，设计开发高性能氧电催化剂是促进新能源存储与转换器件发展应用的关键。基于多年的研究努力，已有多种类型的高效氧催化剂被开发，包括贵金属基材料，过渡金属基材料以及碳基材料等。同时，针对不同类型的氧催化剂，科研人员进一步开发出多种技术策略在不同层面（形貌结构，化学组成以及电子结构）对其性能进行优化。

       最近，华中科技大学夏宝玉教授团队联合韩国成均馆大学Ho Seok Park(朴皓錫)教授团队，应邀在Advanced Functional Materials上发表题为“Advanced Oxygen Electrocatalysis in Energy Conversion and Storage”的综述文章，全面地概述了近年来已开发的高效氧催化剂以及其在新能源存储与转换器件应用中取得的进展。该综述围绕电催化氧还原与氧析出反应，分别将电催化剂分为贵金属基、过渡金属基和碳基材料，探讨了不同类型催化剂的电催化机理，并重点分析了其结构与催化活性和性能关系。作者进一步总结了氧电催化剂在新能源存储与转换器件领域的最新进展，阐述了催化材料工作机制，并详细讨论了相关影响因素。最后，作者展望了未来高效氧催化剂开发的机遇与挑战，并对其在合成技术、催化机理以及表征手段等方面的发展提出了建设性的见解。
       本文旨在为未来高效稳定的氧电催化剂设计开发提供思路与借鉴。相关工作发表于Advanced Functional Materials（DOI: 10.1002/adfm.202007602）上，华中科技大学杨欢博士和韩国成均馆大学韩晓彤博士为本文共同第一作者，华中科技大学夏宝玉教授和韩国成均馆大学Ho Seok Park(朴皓錫)教授为共同通讯作者。

chandler

电化学全解水、CO2还原以及可充电金属-空气电池等可持续新能源体系已经在学术界以及工业界引起了广泛的研究兴趣。但是，由于水氧化过程的缓慢动力学，这些技术还难以获得令人满意的转换效率。因此，设计高性能的电催化剂以克服反应能垒从而加速电化学反应动力学是十分重要的。Ni-Fe氧化物/氢氧化物已经展现出类似于贵金属（Ru/Ir基）的电催化性能，成为了极具潜力的电催化剂。已经开发了很多自下而上的制备方法，比如水热法、电沉积法等，用于合成Ni-Fe氧化物/氢氧化物，但是这些方法通常需要苛刻的条件以及复杂的工艺才能实现纳米结构的可控制备，因此难以大规模生产。因此，开发自上而下的方法制备Ni-Fe氧化物/氢氧化物是十分有必要的，但是仍然具有挑战性。

         鉴于此，华中科技大学的夏宝玉教授课题组受到自然界腐蚀现象的启发，设计了一种新型的自上而下的方法制备NiFe氢氧化物，以及相转变为NiFe羟基氧化物用于高效的水氧化电催化，将传统的腐蚀工程与纳米技术有机地结合，为设计新型的电催化剂提供了思路。
       本文要点：
       1) 通过模拟自然界的腐蚀条件，将泡沫镍可以直接腐蚀成NiFe氢氧化物，所获得的产物呈现出纳米片阵列的形貌。随后通过电化学活化，可以将NiFe氢氧化物相转变为NiFe羟基氧化物纳米片阵列。
       2) 经过活化相转变以后，所制备的催化剂在10 mA·cm−2的电流密度下具有275 mV的低过电位，同时表现出出色的稳定性。
       3) 通过实验与理论计算相结合，通过腐蚀工程诱导氢氧化物的形成以及其向羟基氧化物的转变可以降低对反应中间体的吸附和脱附，从而有利于电催化性能的提升。
       Lanqing Gong, et al. Corrosion formation and phase transformation of nickel-iron hydroxide nanosheets array for efficient water oxidation. Nano Res., https://doi.org/10.1007/s12274-021-3366-3.