湖南师范大学化学化工学院周明波

qingsuanzhi

周明波，男，硕士生导师。2015年6月毕业于湖南大学获理学博士学位，师从李金恒教授（国家杰出青年项目获得者）。曾连续两次获得博士研究生国家奖学金、湖南大学优秀博士研究生、湖南省优秀博士毕业生，湖南大学优秀博士学位论文等荣誉。2015年7月加入湖南师范大学化学化工学院，从事有机化学领域的教学与研究工作。
已获得的研究成果主要集中在：（1）以廉价的氮杂环丙烷为起始原料，通过底物的巧妙设计，实现其与炔烃的[3+2]、[4+2]、[3+2+2]、[5+2]等环加成反应，构建一系列具有生物活性以及医药价值的氮杂环化合物；（2）通过自由基策略，快速、高效地构建出多种吲哚酮类药物骨架。上述成果先后在Angew. Chem. Int. Ed.（4篇），Chem. Sci., Chem. Comm.，Chem. Eur. J.以及J. Org. Chem等国际知名杂志上发表，累积影响因子超过70。文章发表后获得同行的热点报道和广泛引用，截止2016年12月，他引次数累计已超过450。
联系方式：zhoumingbo2004@163.com, zhoumingbo@hunnu.edu.cn。
研究领域：
（1）过渡金属催化有机反应及其机理的研究，主要指过渡金属催化的环加成反应，合成具有生物活性或医药价值的七元、八元等中等杂环以及螺杂环化合物；
（2）以卟啉为研究中心，通过现代高效的合成方法，对其外围官能团化，构建结构新颖、性能独特的有机光电功能分子材料并尝试开发其应用价值；
（3）设计与合成以卟啉为母体的催化剂，实现高效率、高选择性地催化有机反应。
主持课题：
（1）基于卟啉β位官能团化合成芳环稠合卟啉及性能的研究（湖南师范大学特聘教授基金2015年-2022年，80万）；
（2）新颖芳环稠合卟啉合成方法及性能的研究（国家自然科学基金2017年-2019年，20万）；
（3）含卟啉单元的多环芳烃的合成及其性能的研究（湖南省教育厅优秀青年项目2017年-2019年，5万）。
代表性论文：
1 Zhou, M.-B. (周明波); Li, J.-H.* etc. Rhodium(III)-Catalyzed [3+2] Annulation of 5-Aryl-2,3-dihydro-1H Pyrroles with Internal Alkynes through C(sp2)-H/Alkene Functionalization, Angew. Chem. Int. Ed., 2014, 53, 11338-11341 (SCI, 一区, IF=13.6).
2 Zhou, M.-B. (周明波); Li, J.-H.* etc. Hexafluoroantimonic Acid Catalysis: Formal [3+2+2] Cycloaddition of Aziridines with Two Alkynes, Angew. Chem. Int. Ed., 2014, 53, 4196–4199 (SCI, 一区, IF=13.6).
3 Zhou, M.-B. (周明波); Li, J.-H.* etc. Synthesis of Azepine Derivatives by Silver-Catalyzed [5+2] Cycloaddition of γ-Amino Ketones with Alkynes, Angew. Chem. Int. Ed., 2013, 52, 10805-10858 (SCI, 一区, IF=13.6).
4 Wei, W.-T.;# Zhou, M.-B. (周明波);# Li, J.-H.* etc. Synthesis of Oxindoles by Iron-Catalyzed Oxidative 1,2-Alkylarylation of Activated Alkenes with an Aryl C(sp2)–H Bond and a C(sp3)–H Bond Adjacent to a Heteroatom, Angew. Chem. Int. Ed., 2013, 52, 3638–3641 (#并列第一作者，SCI, 一区, IF=13.6).
5 Zhou, M.-B. (周明波); Li, J.-H.* etc. Metal-Free Oxidative Tandem Coupling of Activated Alkenes with Carbonyl C(sp2)–H Bonds and Aryl C(sp2)–H Bonds Using TBHP, Chem. Sci., 2013, 4, 2690-2694 (SCI 一区 IF=9.2).
6 Zhou, M.-B. (周明波); Li, J.-H.* etc. Alkylation of Terminal Alkynes with Transient σ-Alkylpalladium(II) Complexes: A Carboalkynylation Route to Alkyl-Substituted Alkynes, Chem. Eur. J., 2014, 20, 1843– 846 (SCI 二区 IF=5.7).
7 Zhou, M.-B. (周明波); Li, J.-H.* etc. Oxidative 1,2-Difunctionalization of Activated Alkenes with Benzylic C(sp3)-H Bonds and Aryl C(sp2)-H Bonds, Chem. Comm., 2013, 49, 10817-10819 (SCI 二区 IF=6.7).
8 Zhou, M.-B. (周明波); Li, J.-H.* etc. Palladium-Catalyzed Cross-Coupling of Electron-Poor Terminal Alkyneswith Arylboronic Acids under Ligand-Free and Aerobic Conditions, J. Org. Chem,. 2010, 75, 5635–5642 (SCI 二区 IF=4.6).
合作论文：
9 Rao, Y.; Zhou, M.; Osuka, A.*; Kim, D.*; Song, J.* etc. β-to-β 2,5-Pyrrolylene-Linked Cyclic Porphyrin Oligomers, Chem. Eur. J,. 2016, 22, 8801-8804.
10 Rao, Y.; Zhou, M.; Kim, D.*; Song, J.* etc. π-Extended “Earring” Porphyrins with Multiple Cavities and Near-Infrared Absorption, Angew. Chem. Int. Ed., 2016, 55, 6438-6442.
11 Yang, Y.; Zhou, M.-B.; Li, J.-H.* etc. Rhodium(III)-Catalyzed [3+2]/[5+2] Annulation of 4-Aryl 1,2,3- Triazoles with Internal Alkynes through Dual C(sp2)-H Functionalization, Angew. Chem. Int. Ed., 2015, 54, 6595-6599.
12 Pi, R.; Zhou, M.-B.; Li, J.-H.* etc. Rhodium(III)-catalyzed oxidative bicyclization of 4-arylbut-3-yn-1-amines with internal alkynes through C–H functionalization, Chem. Commun., 2015, 51, 13550-13553.
13 Liu, Y.; Zhou, M.-B.; Li, J.-H.* etc. Copper-catalyzed cascade cyclization of 1,7-enynes with aromatic sulfonyl chlorides toward selective assembly of benzo[j]phenanthridin-6(5H)-ones, Chem. Commun., 2014, 50, 14412-14414.
14 Fan, J.-H.; Zhou, M.-B.; Li, J.-H.* etc. Palladium-Catalyzed Oxidative Difunctionalization of Alkenes with α-Carbonyl Alkyl Bromides Initiated through a Heck-type Insertion: A Route to Indolin-2-ones, Angew. Chem. Int. Ed., 2014, 53, 6650-6654.
15 Fan, J.-H.; Zhou, M.-B.; Li, J.-H.* etc. letter Iron-Catalyzed Oxidative Arylmethylation of Activated Alkenes Using a Peroxide as the Methyl Source, SYNLETT, 2014, 25, 0657-0660.
16 Xia, J.-D.; Zhou, M.-B.; Li, J.-H.* etc. Reusable Visible Light Photoredox Catalysts; Catalyzed Benzylic C(sp3)–H Functionalization/Carbocyclization Reactions, SYNLETT, 2012, 23, 2707-2713.
17 Deng, G.-B.; Zhou, M.-B.; Li, J.-H.* etc. Synthesis of 3-(aminomethylene)-2-oxoindolines by palladium-catalyzed annulation of 3-chloro-2-iodo-N-arylacrylamides with amides or amines, Chem. Commun., 2011, 47, 8151-8153.
18 Wang, Z.-Q.; Zhou, M.-B.; Li, J.-H.* etc. Iron-catalyzed annulations of 2-(2-alkynyl)phenoxy)-1-arylethanones leading to substituted naphthalen-1-ols, Chem. Commun., 2009, 5242-5244.
19 Wang, Z.-Q.; Zhou, M.-B.; Li, J.-H.* etc. Iron-Mediated [3+2] or [3+3] Annulation of 2-(2-(Ethynyl)phenoxy)-1-arylethanones: Selective Synthesis of Indeno[1,2-c]chromenes and 5H-Naphtho[1,2-c]chromenes, ORG. LETT., 2011, 13, 14-17.
20 Tang, B.-X.; Zhou, M.-B.; Li, J.-H.* etc. Copper-Catalyzed Intramolecular C-H Oxidation/Acylation of Formyl-N-arylformamides Leading to Indoline-2,3-diones, J. AM. CHEM. SOC., 2010, 132, 8900-8902.