王新平，南京大学化学化工学院和配位化学国家重点实验室教授，教育部长江学者特聘教授，国家杰出青年科学基金获得者。1997年本科毕业于四川大学化学系，2000年于兰州大学化学化工学院获得硕士学位，2007年于加拿大新不伦瑞克大学化学系获得博士学位，2007-2010年于加州大学戴维斯分校从事博士后研究，2010加入南京大学化学化工学院和配位化学国家重点实验室。王新平教授从事主族元素化学和自由基化学研究，已发表学术论文60多篇，其中在J.Am.Chem.Soc.，Angew.Chem.Int.Ed.，Nature Communications和Acc.Chem.Res.四种刊物上发表论文30多篇。2013年被美国化学会三大期刊联合选为Young Investigator。目前担任南京大学无机化学学科主任，Chinese Journal of Chemistry副主编和Science China: Chemsitry编委。
王新平（青年##，杰青，长江学者）
E-mail：xpwang@nju.edu.cn
Phone：025-83621650
Funding
国家杰出青年基金
国家青年##计划
新世纪优秀人才支持计划
国家自然科学基金面上项目
江苏省自然科学基金面上项目
国家自然科学基金重大研究计划/培育项目
江苏省双创计划
江苏省杰出青年基金
教育部长江学者计划特聘教授(2015)
国家杰出青年基金(2015)
中组部首批国家青年##计划(2011)
教育部新世纪优秀人才支持计划(2011)
南京大学优秀青年骨干教师计划(2011)
教育部国家优秀自费留学生奖学金(2006)
江苏省双创计划(2013)
江苏省杰出青年基金(2014)
研究方向
功能自由基化学
自由基物质是含不成对电子的原子、分子或离子，跟有机反应机理、结构化学和功能材料化学密切相关，并且渗透到物理学和生物医学领域，如空气中的氧气、首例有机超导材料四硫富瓦烯(TTF)阳离子、以及调节血管功能的一氧化氮(相关工作获1998年诺贝尔生理医学奖) 等都是自由基分子。由于含有不成对电子的自由基很活跃，大多数自由基的寿命都非常短。如何稳定活跃的自由基是该领域的重大关键问题，也是国际上的研究热点。
我们课题组根据空间位阻效应和电子性质，设计配体，合成自由基化合物，结合光(波)谱表征技术和量子化学计算, 对生成的自由基化合物的结构、化学健本质和反应机理进行深层次的研究，并挖掘自由基化合物可能具有的功能特性如催化、发光、导电和磁性等，来发现和解决基础化学领域中的重要问题。
我们主要从事以下几方面的研究：
■ 新型自由基化合物的合成
■ 基于自由基的活化与催化
■ 自由基光电功能
■ 自由基分子磁体
■ 自由基超导材料
近期论文 - Y. Su, X. Wang, Y. Li, Y. Song, Y. Sui, X. Wang,* Nitrogen Analogues of Thiele’s Hydrocarbon:Closed-Shell vs Open-Shell in the Ground State. Angew. Chem. Int. Ed. 2014,DOI: 10.1002/ange.201410256.
- S. Zhang, X. Wang, Y. Sui,* X. Wang,* Odd-Electron Bonded Sulfur Radical Cations: X-ray Structural Evidence of a Sulfur-Sulfur Three-Electron σ–Bond. J. Am. Chem. Soc. 2014, 136, 14666–14669.
- X.Pan, X. Wang, Y. Zhao, Y. Sui, and X. Wang,* A Crystalline Phosphaalkene Radical Anion. J. Am. Chem. Soc. 2014, 136, 9834-9837.
- S. Zhang, X. Wang, Y. Su, Y. Qiu, Z. Zhang, and X. Wang,* Isolation and Reversible Dimerization of a Selenium–Selenium Three–Electron σ–Bond, Nature Communications, 2014, 5, 4127. Doi: 10.1038/ncomms5127.
- Y. Su, X. Zheng, X. Wang, X. Zhang, Y. Sui, and X. Wang,* Two Stable Phosphorus-Containing Four-Membered Ring Radical Cations with Inverse Spin Density Distributions, J. Am. Chem. Soc. 2014, 136, 6251-6254.
- Y. Su, X. Wang, X. Zheng, Z. Zhang, Y. Song, Y. Sui, Y. Li, and X. Wang,* Tuning Ground States of Bis(triphenylamine)benzidine Dications by Substituent Effect: From a Closed-Shell Singlet to a Diradicaloid with an Excited Triplet State, Angew. Chem. Int. Ed. 2014, 53, 2857- 2861. (29)F. Gao, F. Zhu, X. Wang, Y. Xu, X. Wang,* and J. Zuo,* Stabilizing Radical Cation and Dication of a Tetrathiafulvalene Derivative by a Weakly Coordinating Anion, Inorg. Chem. 2014, 53, 5321 – 5327.
- X. Zheng, X. Wang, Y. Qiu, Y. Li, C. Zhou, Y. Sui, Y. Li, J. Ma, and X. Wang*, One-Electron Oxidation of an Organic Molecule by B(C6F5)3; Isolation and Structures of Stable Non-para-substituted Triarylamine Cation Radical and Bis(triarylamine) Dication Diradicaloid, J. Am. Chem. Soc. 2013, 135, 14912 - 14915 .
- X. Pan, Y. Su, X. Chen, Y. Zhao, Y. Li, J. Zuo, and X. Wang,*Stable Tetraaryldiphosphine Radical Cation and Dication, J. Am. Chem. Soc. 2013, 135, 5561 - 5564 .
- X. Pan, X. Chen, T. Li, Y. Li, and X. Wang,* Isolation and X-ray Crystal Structures of Triarylphosphine Radical Cations, J. Am. Chem. Soc. 2013, 135,3414 - 3417
- X. Chen, X. Wang, Z. Zhou, Y. Li, Y. Sui, J. Ma, X. Wang,* P. P. Power,*Reversible σ-Dimerizations of Persistent Organic Radical Cations, Angew. Chem. Int. Ed. 2013, 52, 589-592.
- X. Chen, B. Ma, S. Chen, Y. Li, W. Huang, J. Ma, X. Wang,*Synthesis, Crystal Structure, and Physical Property of Sterically Unprotected Thiophene/Phenylene Co-Oligomer Radical Cations: A Conductive π-π Bonded Supermolecular meso-Helix, Chem. -Asian J. 2013, 8, 238-243.
- T. S. Cameron, A. Decken, I. Krossing, J. Passmore,* J. M. Rautiainen,* X. Wang, X. Zeng, Reactions of a Cyclodimethylsiloxane (Me2SiO)6 with Silver Salts of Weakly Coordinating Anions; Crystal Structures of [Ag(Me2SiO)6][Al] ([Al] = [FAl{OC(CF3)3}3], [Al{OC(CF3)3}4]) and their comparison with [Ag(18-Crown-6)]2[SbF6]2,Inorg. Chem. 2013, 52, 3113 - 3126 .
- X. Chen, X. Wang, Y. Sui,Y. Li, J. Ma,* J. Zuo and X. Wang,* Synthesis,Characterization and Structures of a Persistent Aniline Radical Cation, Angew. Chem. Int. Ed. 2012, 51,11878-11881.
- X. Chen, B. Ma, X. Wang, S. Yao, L. Ni, Z. Zhou, Y. Li, W. Huang, J. Ma, J. Zuo* and X. Wang*, From Monomersto π-Stacks,from Nonconductive to Conductive. Syntheses, Characterization and Crystal Structures of Benzidine Radical Cations, Chem. - Eur. J, 2012,18,11828-11836
- X. Wang,* P. P. Power,* Structural Characterization, Infrared Spectroscopy and Theoretical Calculations for B(C6F5)3 Stabilized Benzene-Ammonia and Benzene-Water Complexes, Angew. Chem. Int. Ed. 2011,50,10965.
- D. Aris, J. Beck, A. Decken, I. Dionne, J. S. A. D. Gunne, W. Hoffbauer, T. Kochner, I. Krossing, J. Passmore,* E. Rivard, F. Steden, X. Wang, Metastable Se6 as a ligand for Ag+: from isolated molecular to polymeric 1D and 2D structures, Dalton Transitions, 2011, 40, 5865 – 5880. (18) X. Wang, Y. Peng, M. M. Olmstaead, H. Hope, P. P. Power*. A ditetrylyne as a π donor:synthesis and characterization of [AgAr'GeGeAr']+SbF6- and [Ag2Ar'GeGe(F)Ar']+SbF6-(Ar'=C6H3-2,6(C6H3-2,6-Pri2)2), J. Am. Chem. Soc. 2010, 132, 13150 - 13151.
- X. Wang, Y. Peng, Z. Zhu, J. C. Fettinger, P. P. Power*, J. Guo, S. Nagase. Synthesis and characterization of two of the three isomer models of a germanium substituted bicyclo[2.2.0]hexane diradicaloid: stretching the Ge-Ge bond, Angew. Chem. Int. Ed. 2010, 49, 4593 - 4597.
- T. Summerscales, X. Wang, P. P. Power*. Cleavage of the Sn Sn Multiple Bond in a Distannyne by Cyclooctatetraene: Formation of the π-Bound Inverse Sandwich Complex [(Ar′Sn)2(μ2-η2:η3-cot)], Angew. Chem. Int. Ed. 2010, 49, 4788 – 47905.
- Y. Peng, X. Wang, J. C. Fettinger, P. P. Power,* Reversible complexation of? isocyanides by the distannyne Ar'SnSnAr' (Ar' = C6H3-2,6(C6H3-2,6-iPr2), Chem. Commun. 2010, 46, 943.
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发表于 2018-2-20 08:02:26
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