苏州大学材料与化学化工学部材料学院张正彪

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姓名：张正彪
职称：教授、博士生导师
部门：材料学院
联系方式：
Tel: 86-512-65880819 (O)
Email: zhangzhengbiao@suda.edu.cn
学历及学术经历：张正彪，男，博士，1974年11月生。1997年本科毕业于苏州大学化学化工学院；2000年获高分子化学与物理专业硕士学位，并于同年留校工作。2007年在苏州大学化学化工学院获高分子化学与物理博士学位。主要开设《高分子化学》以及《化工原理》等课程。2007年8月至2008年8月赴新加坡国立大学E. T Kang教授和K. G. Neoh教授课题组作访问学者一年。 2012年2月至2013年2月美国阿克伦大学访问学者一年，合作导师：Stephen Z. D. Cheng 教授。
研究领域：大分子精密设计及其可控合成；可控自由基聚合机理及方法学研究；功能高分子的设计和合成。
获奖情况：
1. 江苏省高校“青蓝工程”优秀青年骨干教师培养对象，2014；
2. 教育部自然科学二等奖，排五，2010；
3. 江苏省自然科学进步二等奖，排五，2010；
4. 苏州大学优秀博士论文，2008；
5. 苏州大学苏鑫科研奖，2008；
6. 指导国家级大学生创新性实验计划（2010）和校级大学生创新性计划（2009）各1项，结题均为优秀。
7. 主讲《化工原理》课程获苏州大学精品课程。
主持项目：
1. 国家自然科学基金面上项目：基于非共价键相互作用和可控自由基聚合的大分子精密合成（21374068），83万元。2014.1-2017.12，主持。
2. 国家自然科学基金面上项目：室温下零价铁调控的“活性”/可控自由基聚合（21174094），62万元。2012.1-2015.12，主持。
3. 国家自然科学基金青年基金项目：单电子转移“活性”自由基聚合(SET-LRP)的机理研究（20904036），19万元，2010.1-2012.12，主持。
4. 江苏省高校自然科学研究重大项目：基于“活性”自由基聚合和分子间弱相互作用的大分子精密合成（12KJA150007），30万元，2012.8-2015.12，主持。

代表性论文：
1.        Yuwei Gu, Junfei Zhao, Qingqing Liu, Xiangqiang Pan, Wei Zhang, Zhengbiao Zhang*, Xiulin Zhu*, Zero valent metal/RAFT agent mediated CRP of functional monomers at room temperature: a promising catalyst system for CRP. Polym. Chem., 2015, 10.1039/ C4PY01248H.
2.        Yiwen Li, Hao Su, Xueyan Feng, Kan Yue, Zhao Wang, Zhiwei Lin, Xiulin Zhu, Qiang Fu, Zhengbiao Zhang*, Stephen Z. D. Cheng*, Wen-Bin Zhang*. Precision synthesis of macrocyclic giant surfactants tethered with two different polyhedral oligomeric silsesquioxanes at distinct ring locations via four consecutive "click" reactions. Polym. Chem., 2015, 10.1039/C4PY01360C.
3.        Zhiwei Lin, Pengtao Lu, Xinfei Yu, Wen-Bin Zhang, Mingjun Huang, Kan Wu, Kai Guo, Chrys Wesdemiotis, Xiulin Zhu, Zhengbiao Zhang*, Kan Yue* and Stephen Z. D. Cheng*. Sequential “Click” Synthesis of “Nano-Diamond-Ring-like” Giant Surfactants Based on Functionalized Hydrophilic POSS/C60 Tethered with Cyclic Polystyrenes. Macromolecules 2014, 47, 4160-4168.
4.        Yang Wu, Yanyan Zhou, Jian Zhu, Wei Zhang, Xiangqiang Pan, Zhengbiao Zhang*, Xiulin Zhu*. Fast conversion of terminal thiocarbonylthio group of RAFT polymer to "clickable" thiol group via the versatile sodium azide. Polym. Chem., 2014, 5, 5546-5550.
5.        Wenxiang Wang, Junfei Zhao, Nianchen Zhou, Jian Zhu, Wei Zhang, Xiangqiang Pan, Zhengbiao Zhang* and Xiulin Zhu* Reversible Deactivation Radical Polymerization in the Presence of Zero-Valent Metals: from Components to Precise Polymerization Polym. Chem. 2014, 5, 3533−3546.
6.        Ye Cai, Jinjie Lu, Feng Zhou, Xiaoji Zhou, Nianchen Zhou*, Zhengbiao Zhang*, Xiulin Zhu* Cyclic Amphiphilic Random Copolymers Bearing Azobenzene Side Chains: Facile Synthesis and Topological Effects on Self-Assembly and Photoisomerization. Macromol. Rapid Commun. 2014, 35, 901−907.
7.        Yuwei Gu, Junfei Zhao, Qingqing Liu, Nianchen Zhou, Zhengbiao Zhang*, Xiulin Zhu*. Zero-valent iron (Fe(0)) mediated RAFT miniemulsion polymerization: a facile approach for the fabrication of Fe(0)-encapsulated polymeric nanoparticles Polym. Chem., 2014, 5, 4215−4218.
8.        Yang Wu, Junfei Zhao, Xiaofei Zhang, Jian Zhu, Wei Zhang, Zhengbiao Zhang* and Xiulin Zhu* Zero-valent metal catalyzed removal of thiocarbonylthio end groups from RAFT-made polystyrene: producing controllable bimodal molecular weight distribution. Polym. Chem., 2014, 5, 1992−1998.
9.        Zhigui Zheng, Wenxiang Wang, Yuan Zhou, Zhengbiao Zhang* and Xiulin Zhu*. Manganese(III) acetylacetonate initiated RAFT polymerizations: an alternative and versatile RAFT initiator. Polym. Chem. 2014, 5, 37−42.
10.     Xiaofei Zhang, Wenxiang Wang, Kai Guo, Chrys Wesdemiotis, Zhengbiao Zhang*, Xiulin Zhu*. Zero-valent metal catalyzed radical-induced adjustable removal/modification of thiocarbonylthio end groups of RAFT polymer at ambient temperature. Polym. Chem., 2013, 4, 637–644.
11.     Xing Zhu, Nianchen Zhou*, Jian Zhu, Zhengbiao Zhang*, Xiulin Zhu*, Wei Zhang, Zhenping Cheng, Yingfeng Tu, Xiulin Zhu*. High-Efficiency Preparation of Macrocyclic Polymers via a Circulatory Extraction–Cyclization Strategy. Macromolecular Chemistry and Physics 2013, 214, 1107–1113.
12.     Xiaoji Zhou, Wenxiang Wang, Huali Yu, Junfei Zhao, Zhengbiao Zhang*, Xiulin Zhu* Hydrogen bonding assisted reversible-deactivation radical copolymerization of 4-vinylpyridine and styrene: a facile approach for adjusting polymerization behavior, polymer composition, etc. Polym. Chem., 2013, 4, 3575–3581.
13.     Wenxiang Wang, Junfei Zhao, Huali Yu, Nianchen Zhou, Zhengbiao Zhang*, Xiulin Zhu* Simultaneously improving controls over molecular weight and stereoregularity of Poly(4-vinylpyridine) via a hydrogen bonding-facilitated controlled radical polymerization.      Polymer  2013, 54, 3248–3253.
14.     Wenxiang Wang, Junfei Zhao, Wei Zhang, Jian Zhu, Zhengbiao Zhang*, Xiulin Zhu* Ligand-Free SET-DTLRP of MMA at Room Temperature.       J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 1872–1879.
15.     Xiao-fei Zhang, Yang Wu, Jun Huang, Xue-lang Miao, Zhengbiao Zhang*, Xiulin Zhu*. Copper(0)-mediated radical polymerization of styrene at room Temperature. Chinese Journal of Polymer Science 2013, 31, 702–712.
16.     Xing Zhu, Nianchen Zhou*, Jian Zhu, Zhengbiao Zhang*, Wei Zhang, Zhenping Cheng, Yingfeng Tu, Xiulin Zhu*. A High-Efficiency Strategy for Synthesizing Cyclic Polymers of Methacryates in One Pot. Macromol. Rapid Commun. 2013, 34, 1014−1019。
17.     Yiyu Zhan, Zhengbiao Zhang*, Xiangqiang Pan, Jian Zhu, Nianchen Zhou, Xiulin Zhu*. A Cyclic Diselenocarbamate as RAFT Agent in the Polymerization of VAc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 1475–1683
18.     Junfei Zhao, Wenxiang Wang, Liangjiu Bai, Lili Zhou, Zhenping Cheng, Zhengbiao Zhang* and Xiulin Zhu*. Reversible-deactivation radical polymerization mediated by CuSO4·5H2O: an alternative and promising copper(II)-based catalyst. Polym. Chem., 2012, 3, 3220–3223.
19.     Xiaofei Zhang, Wenxiang Wang, Kai Guo, Chrys Wesdemiotis, Zhengbiao Zhang* and Xiulin Zhu*, Zero-valent metal catalyzed radical-induced adjustable removal/modification of thiocarbonylthio end groups of RAFT polymer at ambient temperature. Polym. Chem., 2012, 4, 637–644.
20.     Wenxiang Wang, Zhengbiao Zhang*, Zhenping Cheng, Jian Zhu, Nianchen Zhou and Xiulin Zhu* Favorable hydrogen bonding in room-temperature Cu(0)-mediated controlled radical polymerization of 4-vinylpyridine. Polym. Chem., 2012, 3, 2731–2734.
21.     Lili Zhou, Zhengbiao Zhang*, Wenxiang Wang, Zhenping Cheng, Nianchen Zhou, Jian Zhu, Wei Zhang, Xiulin Zhu Zero-Valent Bimetallic Iron/Copper Catalyzed SET-LRP: A Dual Activation by Zero-Valent Iron. J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 936–943.
22.     Wenxiang Wang, Zhengbiao Zhang*, Yang Wu, Jian Zhu, Zhenping Cheng, Nianchen Zhou, Wei Zhang, Xiulin Zhu. Ligand-Free Cu(0)-Mediated Controlled Radical Polymerization of Methyl Methacrylate at Ambient Temperature J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 711–719.
23.     Qin Zhang, Zhengbiao Zhang*, Wenxiang Wang, Jian Zhu, Zhenping Cheng,Nianchen Zhou, Wei Zhang, Xiulin Zhu. SET-RAFT of MMA Mediated by Ascorbic Acid-Activated Copper Oxide, J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 1424–1433.
24.     Huali Yu, Yang Wu, Jinlong Gao,Wenxiang Wang, Zhengbiao Zhang*, Xiulin Zhu*. Copper(0)-mediated radical copolymerization of vinyl acetate and acrylonitrile in DMSO at ambient temperature. J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 4983–4989.
25.     Huali Yu, Zhengbiao Zhang*, Zhenping Cheng, Jian Zhu, Nianchen Zhou, Wei Zhang, Xiulin Zhu*. ATRP of styrene catalyzed by elemental Fe(0) and Br2: An easy and economical ATRP process. J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 2182–2187.
26.     Huali Yu, Qifeng Chen, Zhengbiao Zhang*, Jian Zhu, Zhenping Cheng, Nianchen Zhou, Wei Zhang, Xiulin Zhu*, 60Co γ-irradiation-initiated RAFT polymerization of VAc at room temperature, Reactive & Functional Polymers 2012, 72, 153–159.
27.     Lili Zhou, Zhengbiao Zhang*, Zhenping Cheng, Nianchen Zhou, Jian Zhu, Wei Zhang, Xiulin Zhu* Fe(0) Powder/CuBr2-Mediated “Living”/Controlled Radical Polymerization of Methyl Methacrylate and Styrene at Ambient Temperature Macromol. Chem. Phys.2012, 213, 439−446.
28.     Qin Zhang, Zhengbiao Zhang*, Wenxiang Wang, Zhenping Cheng, Jian Zhu, Nianchen Zhou,Wei Zhang, Zhaoqiang Wu, Xiulin Zhu*. In Situ Cu(0) Catalyzed SET–LRP: the First Attempt. J. Polym. Sci., Part A: Polym. Chem. 2011, 49, 4694–4700.
29.     Zhengbiao Zhang, Wenxiang Wang, Zhenping Cheng, Jian Zhu, Nianchen Zhou, Yonggang Yang, Yingfeng Tu, and Xiulin Zhu*. Zero–valent Iron/RAFT Agent–Mediated Polymerization of Methyl Methacrylate at Ambient Temperature. Macromolecules 2010, 43, 7979–7984.
30.     Zhengbiao Zhang, ShaoJun Yuan, Xiulin Zhu, KG Neoh, ET Kang; Enzyme-mediated amperometric biosensors prepared via successive surface-initiated atom-transfer radical polymerization; Biosensors and Bioelectronics; 2010, 25, 1102–1108;
31.     Zhengbiao Zhang, Wenxiang Wang, Hongda Xia, Jian Zhu, Wei Zhang and Xiulin Zhu*. Single–Electron Transfer Living Radical Polymerization (SET–LRP) of Methyl Methacrylate (MMA) with a Typical RAFT Agent as an Initiator. Macromolecules 2009, 42, 7360–7366.
32.     Zhengbiao Zhang, Xiulin Zhu, FuJian Xu, KG Neoh, ET Kang. Temperature- and pH-sensitive nylon membranes prepared via consecutive surface-initiated atom transfer radical graft polymerizations; Journal of Membrane Science 2009, 342, 300–306.

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近日，中国化工学会在北京召开了第四十一届会员代表大会，会上公布了2022年度中国化学学会科学技术奖获奖名单。我校张正彪教授牵头完成的“高分子结构设计与精准合成”项目获得基础研究成果奖一等奖，系学校首次获得。
         张正彪教授团队瞄准高分子精准合成的世界难题，发展了“休眠单体”用于调控聚合物序列和分子量的新策略，开发了潜在调控剂实现聚合物分子量和拓扑结构调控的新方法，提出了聚合诱导手性组装和手性结构自保持的新途径，实现了高分子结构的多维度精准设计与合成。率先在国际上提出了潜在单体的合成策略，实现了高分子序列结构和拓扑结构的精准合成；基于马来酰胺和巯基的高效迈克尔加成反应，实现了单一分子量的高分子大量合成的重大突破，率先在国际上确立了基于精确序列高分子的数字高分子精准合成概念；基于光催化双键单加成策略，首次实现了光催化碘转移自由基聚合及光催化SUMI反应调控聚乙烯基醚分子量分布；发展了聚合诱导手性自组装策略，突破性的实现了高分子的多层次手性精确调控。有力推进了高分子序列结构、分子量及其分布以及聚集态结构精确调控的研究，解决了该领域中的关键基础科学问题。成果在高级防伪、智能高分子材料和先端高分子材料等领域得到了产业化应用，取得显著经济和社会效益。团队在Nature Communications、Angewandte Chemie International Edition等杂志上发表高质量论文247篇，授权发明专利87项，荣获高等学校科学研究优秀成果奖（科学技术）2项、江苏省科学技术奖2项。

         中国化工学会科学技术奖由中国化工学会于2019年设立，旨在鼓励和表彰在化工领域科学技术进步中做出突出贡献的单位和个人，促进我国化工领域科学技术进步和产业发展，推动创新型国家和世界科技强国建设。该奖项每年评选一次，共设技术发明奖、科技进步奖、基础研究成果奖三个子奖项，每年度科学技术奖授奖项目总数原则上不超过 60 项。