中国科学院福建物质结构研究所王瑞虎

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王瑞虎，博士，研究员，博士生导师。山东临沂人，1998.7于山东曲阜师范大学化学系获学士学位，1998.9-2004.8师从中国科学院福建物质结构研究所洪茂椿院士研究多功能有机配体超分子化合物的合成、结构和性质。2002.5-2003.2在香港理工大学陈新滋院士组从事手性金属有机化合物的合成和催化的研究。2004.9-2008.9先后在美国爱达荷大学化学系Jean'ne M. Shreeve组、美国堪萨斯大学Center for Environmentally Beneficial Catalysis 从事含金属的功能离子液体的合成和催化，绿色含能离子盐的合成、CO2溶胀介质中的可溶性聚合物负载铑催化的氢甲酰化反应研究。曾获中国科学院彭荫刚奖学金（2001），中科院院长奖学金优秀奖(2004)，中国科学院宝钢教育奖(2004)。已在国际重要学术期刊上发表论文100篇，被引用1500多次。2008年10月回中国科学院福建物质结构研究所应用化学研究室工作，2009年3月入选中国科学院百人计划，2012年4月入选福建省高层次创业创新人才。目前主持承担国家973计划课题，国家自然科学基金面上项目、福建省自然科学基金重点、面上项目等课题。主要从事多孔材料的纳米催化、能源存储和转化等研究。

联系电话：0591-63173155
电子邮件地址：ruihu@fjirsm.ac.cn
研究方向
主要从事以下研究：
1）多孔材料的纳米催化；
2）能源存储和转化；
3）污染物检测和分离。

发表论文

2017年　
1.  Hui Pan, Zhibin Cheng, Zhubing Xiao, Xiaoju Li* and Ruihu Wang*, The Fusion of Imidazolium-based Ionic Polymer and Carbon Nanotubes: One Type of New Heteroatom-doped Carbon Precursors for High-performance Lithium-sulfur Batteries, Adv. Funct. Mater. 2017, 27, 1703936.
2. Hong Zhong, # Zhihua Fu,# Jared M. Taylor, Gang Xu,* and Ruihu Wang,* Inorganic Acid-Impregnated Covalent Organic Gels as High-Performance Proton-Conductive Materials at Subzero Temperatures, Adv. Funct. Mater. 2017, 27, 1701465 (Back Cover).
3.  Zhibin Cheng, Zhubing Xiao,* Hui Pan, Shiqing Wang and Ruihu Wang*, Elastic Sandwich-Type rGO-VS2/S Composites with High Tap Density: Structural and Chemical Cooperativity Enabling Lithium-Sulfur Batteries with High Energy Density, Adv. Energy Mater. 2017, ASAP.
4.  Zhubing Xiao, Zhi Yang,* Linjie Zhang, Hui Pan and Ruihu Wang*, Sandwich-Type NbS2@S@I-Doped Graphene for High-Sulfur-Loaded, Ultrahigh-Rate and Long-Life Lithium-Sulfur Batteries, ACS Nano 2017, 11, 8488-8498.
5.   Liuyi Li,# Lu Li,# Caiyan Cui, Hongjun Fan* and Ruihu Wang*, Hierarchical Hollow Covalent Organic Framework-derived Heteroatom-doped Carbon Spheres for Metal-free Catalysis, ChemSusChem 2017, ASAP.
6. Xiuyun Wang, Yi Liu, Tianhua Zhang, Yongjin Luo,* Zhixin Lan, Kai Zhang, Jiachang Zuo, Lilong Jiang* and Ruihu Wang,* Geometrical-Site-Dependent Catalytic Activity of Ordered Mesoporous Co-Based Spinel for Benzene Oxidation: In Situ DRIFTS Study Coupled with Raman and XAFS Spectroscopy, ACS Catal. 2017, 7, 1626-1636.
7. Zhubing Xiao, Zhi Yang,* Liujiang Zhou, Linjie Zhang,  Ruihu Wang,* Highly Conductive Porous Transition Metal Dichalcogenides via Water Steam Etching for High-Performance Lithium-Sulfur Batteries, ACS Appl. Mater. Interfaces 2017, 9, 18845-18855.
8. Hong Zhong, Yanqing Su, Caiyan Cui, Feng Zhou, Xiaoju Li* and Ruihu Wang,* Palladium Nanoparticles Supported by Carboxylate-functionalized Porous Organic Polymers for Additive-free Hydrogen Generation from Formic Acid, ACS Sustainable Chem. Eng. 2017,  5, 8061-8065.
9. Xiuyun Wang, Zhixin Lan, Kai Zhang, Jianjun Chen, Lilong Jiang* and Ruihu Wang,* Structure-Activity Relationships of AMn2O4 (A = Cu and Co) Spinels in Selective Catalytic Reduction of NOx: Experimental and Theoretical Study, J. Phys. Chem. C 2017, 121, 3339-3349.  
   2016年     
1. Xinxiong Li, Yangxin Wang, Ruihu Wang,* Caiyan Cui, Chongbin Tian, Guoyu Yang,* Designed Assembly of Heterometallic Cluster-Organic Frameworks Based on Anderson-type Polyoxometalate Clusters, Angew Chem. Int. Ed. 2016, 55, 6462-6466.
2. Hong Zhong, Caiping Liu, Yangxin Wang, Ruihu Wang,* Maochun Hong, Tailor-made Porosities of Fluorene-based Porous Organic Frameworks for Pre-designable Fabrication of Palladium Nanoparticles with Size, Location and Distribution Control, Chem. Sci. 2016, 7, 2188-2194.
3.  Liuyi Li, Caiyan Cui, Wenyue Su,* Yangxin Wang  and Ruihu Wang,* Hollow Click-Based Porous Organic Polymers for Heterogenization of Cationic Metal Complexes through Electrostatic Interactions, Nano Res. 2016, 9, 779-786.   
4. Yangxin Wang, Huaixia Zhao, Xinxiong Li and Ruihu Wang,* A Durable Luminescent Ionic Polymer for Rapid Detection and Efficient Removal of Toxic Cr2O72-, J. Mater. Chem. A 2016,
5. Yanqing Su, Yangxin Wang, Xiaoju Li,* Xinxiong Li and Ruihu Wang,* Durable Imidazolium-based Porous Organic Polymers: Anion Exchange-Drived Rapid Capture and Luminescent Probe of Cr2O72-, ACS Appl. Mater. Interfaces, 2016,  8, 18904-18911.
6. Yangxin Wang, Hong Zhong, Liuyi Li and Ruihu Wang,* Facile Synthesis and Tunable Porosities of Imidazolium-based Ionic Polymers Containing in situ Formed Palladium Nanoparticles, ChemCatChem 2016, 8,  2234-2240..   
7. Hong Zhong, Caiping Liu, Hanghui Zhou, Yangxin Wang and Ruihu Wang,* Pre-functionalized Porous Organic Polymers: Effective Supports of Surface Palladium Nanoparticles for the Enhancement of Catalytic Performances in Dehalogenation, Chem Eur J. 2016,  2016, 22, 12533-12541.
8.  Yanqing Su, Xiaoju Li,* Yangxin Wang, Hong Zhong and Ruihu Wang,* Gold Nanoparticles Supported by Imidazolium-based Porous Organic Polymers for Nitroarenes Reduction, Dalton Trans., 2016, 45, 16896-16903.
9. Xiuyun Wang, Jinxing Mi, Wu Wen, Zhilin Chen, Lilong Jiang* and Ruihu Wang,* Influence of Ce0.6Zr0.4O2 Loading on the Sulfur Poisoning and Regenerability of Pt/Ba/Al2O3-Ce0.6Zr0.4O2 in NOx Removal by Hydrogen, Mater. Res. Bull. 2016, 75, 41-46.
10. Wu Wen, Xiuyun Wang,* Si Jin and Ruihu Wang*, LaCoO3 Perovskite in Pt/LaCoO3/K/Al2O3 for the Improvement of NOx Storage and Reduction Performances, RSC Adv., 2016, 6, 74046-74052.
       2015年      
1.   Linjie Zhang, Xiuyun Wang, Ruihu Wang,* Maochun Hong, Structural Evolution from Metal-Organic Framework to Hybrids of Nitrogen-Doped Porous Carbon and Carbon Nanotube for Enhanced Oxygen Reduction Activity, Chem. Mater. 2015, 27, 7610-7619.
2.  Huaixia Zhao, Xinxiong Li, Liuyi Li and Ruihu Wang,* Solvent-induced Facile Synthesis of Cubic-, Spherical- and Honeycomb-shape Palladium N-Heterocyclic Carbene Particles and Catalytic Applications in Cyanosilylation, Small, 2015, 11, 3642-3647 (Frontispiece, Highlighted in http://www.materialsviewschina.com/2015/05) .
3.  Huaixia Zhao, Liuyi Li, Jinyun Wang and Ruihu Wang, The Spherical Core-shell Magnetic Particles Constructed by Main-chain Palladium N-Heterocyclic Carbenes, Nanoscale, 2015, 7, 3532-3538.
4. Liuyi Li, Chunshan Zhou, Huaixia Zhao,and Ruihu Wang*, Spatial Control of Palladium Nanoparticles in Flexible Click-based Porous Organic Polymers for Hydrogenation of Olefin and Nitrobenzene, Nano Res. 2015, 8, 709-721.
5.  Liuyi Li, Huaixia Zhao and Ruihu Wang*, Tailorable Synthesis of Porous Organic Polymers Decorating Ultrafine Palladium Nanoparticles for Hydrogenation of  Olefins, ACS Catal. 2015, 5, 948-955.  
6. Yangxin Wang, Chunshan Zhou and Ruihu Wang,* Copper-Catalyzed Hydroxylation of Aryl Halides: Efficient Synthesis of Phenols, Alkyl Aryl Ethers and Benzofuran Derivatives in Neat Water, Green Chem  2015, 17, 3910-3915.
7. Yangxin Wang, Lijun Wang, Caiping Liu and Ruihu Wang,* Benzimidazole-contained Porous Organic Polymers as Highly Active Heterogeneous Solid Base Catalysts, ChemCatChem 2015, 7, 1559-1565.
8.  Xiuyun Wang, Wen Wu, Jinxing Mi, Xinxiong Li and Ruihu Wang,* The Ordered Mesoporous Transition Metal Oxides for Selective Catalytic Reduction of NOx at Low Temperature, Appl. Catal. B: Environ. 2015, 176, 454-463..
9. Xiuyun Wang, Lilong Jiang, Jinyun Wang, Ruihu Wang*, Ag/bauxite Catalysts: Improved Low-temperature Activity and SO2 Tolerance for H2-promoted NH3-SCR of NOx, Appl. Catal. B: Environ., 2015, 165, 700-705.  
10. Xiuyun Wang, Wen Wu, Zhilin Chen and Ruihu Wang,*  Bauxite-supported Transition Metal Oxides: Promising Low-temperature and SO2-tolerant Catalysts for Selective Catalytic Reduction of NOx, Sci. Rep. 2015, 5, 9766.
11.  Zhilin Chen, Xiuyun Wang, Yuling Wang and Ruihu Wang*, Pt-Ru/Ba/Al2O3-Ce0.33Zr0.67O2: An effective catalyst for NOx storage and reduction, J. Mol. Catal. A-Chem. 2015, 396, 8-14.   


12. Xiuyun Wang, Wu Wen, Yanqing Su and Ruihu Wang*,  Influence of Transition Metals (M = Co, Fe and Mn) on Ordered Mesoporous CuM/CeO2 Catalysts and Applications in Selective Catalytic Reduction of NOx with H2, RCS Adv. 2015, 5, 63135-63141.
　　2014年      
1.  Liuyi Li, Huaixia Zhao, Jinyun Wang and Ruihu Wang*, Facile Fabrication of Ultrafine Palladium Nanoparticles with Size- and Location-Control in Click- Based Porous Organic Polymers, ACS Nano, 2014, 8, 5352-5364.
2.   Huaixia Zhao, Liuyi Li, Yangxin Wang and Ruihu Wang*, Shape-Controllable Formation of Poly-imidazolium Salts for Stable Palladium N-Heterocyclic Carbene Polymers, Sci. Rep. 2014, 4, 5478.
3.    Huaixia Zhao, Yangxin Wang and Ruihu Wang*, In situ Formation of Well-dispersed Palladium Nanoparticles Immobilized in Imidazolium-based Organic Ionic Polymers, Chem. Commun., 2014, 10871-10874.   
4.   Hong Zhong, Yaqiong Gong, Fengsen Zhang, Liuyi Li and Ruihu Wang*, Click-based Porous Organic Framework Containing Chelating Terdentate Units and its Application in Hydrogenation of Olefins, J. Mater. Chem. A, 2014, 2, 7502-7508.
5.    Liuyi Li, Tao Wu, Jinyun Wang and Ruihu Wang*, Water-soluble Ionic Palladium Complexes: Effect of Pendant Ionic Groups on Palladium Nanoparticles and Suzuki-Miyaura Reaction in Neat Water, ChemPlusChem 2014, 79, 257-265. 　
6.   Liuyi Li, Zhilin Chen, Hong Zhong and Ruihu Wang*, Urea-based Porous Organic Frameworks: Effective Supports for Catalysis in Neat Water, Chem Eur J. 2014, 20, 3050-3060.
7.   Hong Zhong, Jinyun Wang, Liuyi Li and Ruihu Wang*, Copper-free Sonogashira Cross-coupling Reaction Promoted by Palladium Complexes of Nitrogen-containing Chelating Ligand in Neat Water at Room Temperature, Dalton 2014, 43, 2098-2103.
8.    Xinxiong Li, Yaqiong Gong, Huaixia Zhao and Ruihu Wang*, Anion-Directed Assemblies of Cationic Metal-organic Frameworks Based on 4,4′-Bis(1,2,4-triazole): Syntheses, Structures, Luminescent and Anion Exchange Properties, Inorg. Chem., 2014, 53, 12127-12134.
9.   Xinxiong Li, Yaqiong Gong, Huaixia Zhao and Ruihu Wang*, Solvent-mediated Crystal-to-crystal Transformations from a Cationic Homometallic Metal–organic Framework to Heterometallic Frameworks, CrystEngComm, 2014, 16, 8818-8824.  
10.    Xiuyun Wang, Xinxin Qi, Zhilin Chen, Lilong Jiang, Ruihu Wang* and Kemei Wei*, Studies on SO2 Tolerance and Regeneration over Perovskite-Type LaCo1–xPtxO3 in NOx Storage and Reduction, J. Phys. Chem. C, 2014, 118, 13743-13751.   　
11.    Zhilin Chen, Xiuyun Wang, and Ruihu Wang*, PtM/Ba/Al2O3Ce0.6Zr0.4O2: Influence of Synergetic Interactions between Transition Metal and Platinum on NOx Storage and Reduction, ChemPlusChem, 2014, 79, 1167-1175.   
12.    Xiuyun Wang, Zhilin Chen, Yuling Wang, Ruihu Wang,* Rare Earth-doped Pt/Ba/Ce0.6Zr0.4O2-Al2O3 for NOx Storage and Reduction: Effect of Rare Earth Doping on Their Efficiency and Stability, ChemCatChem 2014, 6, 237-244.
　　2013-2010年     
1.    Xinxiong Li, Hongyan Xu, Fanzhen Kong and Ruihu Wang,* A Cationic Metal-Organic Framework Consisting of Nanoscale Cages: Capture, Separation and Luminescent Probing of Cr2O72- via a Single-crystal to Single-crystal Process, Angew Chem. Int. Ed. 2013,  52, 13769-137773.   


2.    Huaixia Zhao, Xinxiong Li, Jinyun Wang, Liuyi Li and Ruihu Wang,* Synthesis and Crystal Structures of Coordination Complexes Containing Cu2I2 Units and Their Application in Luminescence and Catalysis, ChemPlusChem, 2013, 78, 1491-1502.   
3.    Fanzhen Kong, Chunshan Zhou, Jinyun Wang, Zhangyu Yu* and Ruihu Wang,* Water-Soluble Palladium Click Chelating Complex: an Efficient and Reusable Precatalyst for Suzuki-Miyaura and Hiyama Reactions in Water, ChemPlusChem, 2013, 78, 536-545.   
4.    Rui Lv, Yangxin Wang, Chunshan Zhou, Liuyi Li and Ruihu Wang,* Efficient Copper-catalyzed Ullmann Reaction of Aryl Bromides with Imidazoles in Water Promoted by a pH-responsive Ligand, ChemCatChem, 2013, 5, 2978-2982.   
5.    Xiuyun Wang, Zhilin Chen, Yongjin Luo, Lilong Jiang and Ruihu Wang,* Cu/Ba/bauxite: an Inexpensive and Efficient Alternative for Pt/Ba/Al2O3 in NOx Removal. Sci. Rep. 2013, 3, 1559.   
6.    Liuyi Li, Jinyun Wang, Tao Wu and Ruihu Wang,* Click Ionic Liquids: a Family of Promising Tunable Solvents and Application in Suzuki-Miyaura Cross-coupling Reaction, Chem. Eur. J. 2012, 18, 7842-7851.   
7.    Dong Zhang, Chunshan Zhou and Ruihu Wang,* Palladium Nanoparticles Immobilized by Click Ionic Copolymers: Efficient and Recyclable Catalysts for Suzuki-Miyaura Cross-coupling Reaction in Water, Cat. Commun. 2012, 22, 83-88.   
8.    Chunshan Zhou, Jinyun Wang, Liuyi Li, Ruihu Wang* and Maochun Hong, A Palladium Chelating Complex of Ionic Water-soluble Nitrogen-containing Ligand: the Efficient Precatalyst for Suzuki-Miyaura Reaction in Water, Green Chem., 2011, 13, 2100-2106.   
9.    Liuyi Li, Jinyun Wang, Chunshan Zhou, Ruihu Wang* and Maochun Hong, pH-Responsive Chelating N-Heterocyclic Dicarbene Palladium(II) Complexes: Recoverable Precatalysts for Suzuki-Miyaura Reaction in Pure Water, Green Chem., 2011, 13, 2071-2077.   
10.    Ruihu Wang,* Yong Guo, Rongjian Sa and Jean’ne M. Shreeve* Nitroguanidine-Fused Bicyclic Guanidinium Salts: A Family of High-Density Energetic Materials, Chem. Eur. J. 2010, 16, 8522-8529.

11.    Ruihu Wang,* Hongyan Xu, Yong Guo, Rongjian Sa and Jean’ne M. Shreeve* Bis[3-(5-nitroimino- 1,2,4-triazolate)]-Based Energetic Salts: Synthesis and Promising Properties of a New Family of High-Density Insensitive Materials, J. Am. Chem. Soc. 2010, 132, 11904-11905.