山西师范大学化学与材料科学学院张献明

bingnuan

一、基本情况
张献明,教授，博士生导师，万人计划创新领军人才，国家杰出青年基金获得者，百千万人才工程国家级人选，三晋学者，全国优秀博士论文获得者，洪堡学者。1996年山西师范大学获学士学位，1999年内蒙古大学获理学硕士学位。1999年师从陈小明教授（中国科学院院士）攻读博士，2002年6月获中山大学理学博士学位。2003年4月获德国 “洪堡”奖学金资助，在海德堡大学做博士后研究工作，2004年6月返回山西师范大学工作。同年，博士论文被评为 “全国优秀博士学位论文”，2005年入选教育部“新世纪优秀人才支持计划”，2007年获 “山西省五一奖章”和“山西省333人才”，2008年获“中国化学会青年化学奖”并入选“山西省高等院校拔尖创新人才”。2009年获“国家杰出青年基金资助” 2010年获国务院特殊津贴。2011年，作为团队带头人，带领“分子磁性与磁性材料团队”入选教育部创新团队。2013年入选万人计划中“国家中青年科技创新领军人才”，同时被评为“百千万人才工程”国家级人选。
E-mail:zhangxm@dns.sxnu.edu.cn；xmzhang@sxnu.edu.cn;Tel:0357-2051402。
研究兴趣涉及分子磁体、金属簇链基配位聚合物和原位配体反应，主持国家杰出青年科学基金、国家自然科学基金面上和青年项目、973子课题等项目、教育部新世纪优秀人才基金、全国优秀博士学位论文作者专项基金、霍英东教育基金、山西省自然基金和山西省回国留学人员基金等多项国家和省部级基金，以第一作者或通讯作者在J.Am. Chem. Soc, Angew. Chem. Int. Ed., Adv. Mate.,Chem. Mater.,Coord. Chem. Rev.,J. Catal., Chem. Commun., ACS Appl. Mater. Interfaces, Inorg. Chem.等期刊发表研究论文130余篇，发表论文被他人引用5000多次，单篇论文被引超过100次的论文10篇。《配合物控制合成与晶体工程方法基础研究》获得国家自然科学二等奖（排名5）、《配位化合物的水热合成中的原位配体反应》获山西省科学技术奖一等奖（排名1）和中国化学会青年化学奖（个人）。  

二、研究方向
1.金属-有机框架
2.共价-有机框架
3.固体化学
4.团簇和催化化学

三、科研项目
1.《金属簇（链）基功能配位聚合物和原位配体反应》20925101国家杰出青年科学基金2010-2013年,200万,主持.
2.《磁性材料》教育部创新团队教育部“长江学者和创新团队发展计划”创新团队2012-2014年度,300万,主持.
3.《硼掺杂和金属修饰碳材料及其形成的复合材料储氢研究》21031003国家自然科学基金重点项目2011-2014,200万,参与.
4.《氮氧配体的配合物的原位合成、结构、性质和机理》111015第十一届高等院校青年教师基金2008-2010,1.6美元,主持.  
5.《配位化合物的超分子异构体的合成、结构与性质》20401011,国家自然科学基金,2005-2007,23万,主持.
6.《金属簇基的高连接的配位聚合物合成、结构和性质》20771069国家自然科学基金,2008-2010年,30.0,主持.  
7.《配合物和有机配体的原位合成、结构、性质和机理》2004022全国优秀博士论文作者专项基金2005-2009,54.0,主持.  
8.《功能配聚合物的水热合成、结构、性质和机理研究》(晋教计财[2004]67号),山西省青年学术带头人专项基金,2004-2006年,20.0,主持.  
9.编号：NECT-05-0270新世纪优秀人才支持计划2006-2008年,50.0,主持.  
10.《配合物和有机配体的原位合成、结构、性质和机理》(晋教计财[2004]67号),山西省回国留学人员基金,2005-2006，5.0,主持.  
11.(晋教财[2008]105号)山西省拔尖创新人才2008-2010,20.0,主持.  
12.（晋留管办发[2009]13号）山西省回国留学人员基金,2009-2010年,8.0,主持.  
13.《金属链基的功能配位聚合物》山西省留学回国人员择优资助项目2011-2012,12，主持.  
14.《多孔晶体合成方法学与组装机理研究》2012CB821701 .
15.国家重点基础研究发展计划资助(973项目)2012-2016180万,骨干.

四、荣誉
1.万人计划首批创新领军人才.中共中央组织部办公厅,2014
2.国家中青年科技领军人才.科技部,2013
3.百千万人才国家级人选.国家人社部,2013
4.山西省学术技术带头人.山西省人力资源与社会保障厅,2012
5.国务院特殊津贴.中华人民共和国国务院,2011
6.国家杰出青年基金获得者国家自然科学基金委,2009
7.新世纪学术带头人333人才工程山西省人事厅,2007
8.山西省五一奖章.山西劳动竞赛委员会.2007
9.山西省高等院校科技创新标兵.山西省教科文卫体工会联合会.2007
10.新世纪优秀人才.中华人民共和国教育部.2005
11.全国优秀博士学位：系列含氮氧配体的功能配(聚)合物的水热合成、结构、性质和机理研究.国务院学位委员会和中华人民共和国教育部.2004
12.山西省高等学校青年学术带头人. 山西省教育厅.2004
13.洪堡学者.德国洪堡基金会.2004

五、获奖
1.中国高被引学者，2014-2016.
2.《金属簇链基配位聚合物的结构和磁性调控》山西省科学技术奖二等奖（排名1）2014.  
3.《配位化合物的水热合成中的原位配体反应》山西省自然科学奖一等奖,2008.
4.《配合物控制合成与晶体工程方法基础研究》国家自然科学二等奖(排名5).中华人民共和国国务院,2007.
5.中国青年化学奖,中国化学会2007,化奖字第201号.  
6.《系列含氮氧配体的功能配(聚)合物的水热合成、结构、性质和机理研究》,全国优秀博士学位论文奖,国务院学位委员会和中华人民共和国教育部,2004 .  

五、论文
2017
(1)Qu, M.; Li, H.; Xie, L.-H.; Yan, S.-T.; Li, J.-R.; Wang, J.-H.; Wei, C.-Y.; Wu, Y.-W.; Zhang, X.-M. Bidentate Phosphine–Assisted Synthesis of an All–Alkynyl–Protected Ag74 Nanocluster.J Am Chem Soc2017,accepted.
(2)Zhang, L.-J. Z. J. L. F.-Q. Z. X.-M. Water as a Proton Mediator for Dioxygen-Selective Oxidation of Alcohols by a Planar Dinuclear Butterfly-Like Cu-Cu Bonding Complex: A Combined Experimental and Computational Study.Journal of Catalysis.Accepted.
(3)Zhang, F.; Zhao, C.; Chen, S.; Li, H.; Yang, H.; Zhang, X.-M. In situ mosaic strategy generated Co-based N-doped mesoporous carbon for highly selective hydrogenation of nitroaromatics.Journal of Catalysis2017,348, 212-222.
(4)Zhang, Y.; Wang, L.; Yao, R.-X.; Zhang, X.-M. Fourfold-Interpenetrated MOF [Ni(pybz)2] as Coating Material in Gas Chromatographic Capillary Column for Separation.Inorganic Chemistry2017,56, 8912-8919.
(5)Zhao, Y.-W.; Wang, Y.; Zhang, X.-M. Homochiral MOF as Circular Dichroism Sensor for Enantioselective Recognition on Nature and Chirality of Unmodified Amino Acids.ACS Applied Materials & Interfaces2017,9, 20991-20999.
(6)Wei, T.; Sun, J.; Zhang, F.; Zhang, J.; Chen, J.; Li, H.; Zhang, X.-M. Acetylene mediated synthesis of Au/graphene nanocomposite for selective hydrogenation.Catalysis Communications2017,93, 43-46.
(7)Wang, J. H.; Zhang, Y.; Li, M.; Yan, S.; Li, D.; Zhang, X. M. Solvent-Assisted Metal Metathesis: A Highly Efficient and Versatile Route towards Synthetically Demanding Chromium Metal-Organic Frameworks.Angew. Chem. Int. Ed.2017,56, 6478-6482.
(8)Qu, M.; Li, H.; Xie, L.-H.; Yan, S.-T.; Li, J.-R.; Wang, J.-H.; Wei, C.-Y.; Wu, Y.-W.; Zhang, X.-M. Bidentate Phosphine–Assisted Synthesis of an All–Alkynyl–Protected Ag74 Nanocluster.J Am Chem Soc2017, revised July 06.
(9)Li, S.-L.; Wang, J.; Zhang, F.-Q.; Zhang, X.-M. Light and Heat Dually Responsive Luminescence in Organic Templated CdSO4-type Halogeno(cyano)cuprates with Disorder of Halogenide/Cyanide.Cryst. Growth. & Des.2017,17, 746-752.
(10)Jia, X.-X.; Yao, R.-X.; Zhang, F.-Q.; Zhang, X.-M. A Fluorescent Anionic MOF with Zn4(trz)2 Chain for Highly Selective Visual Sensing of Contaminants: Cr(III) Ion and TNP.Inorganic Chemistry2017,56, 2690-2696.
(11)Hou, J.-J.; Li, X.-Q.; Gao, P.; Sun, H.-Q.; Zhang, X.-M. Tunability in Metal Coordination Sphere, Ligand Coordination Mode, Network Topology, and Magnetism via Stepwise Dehydration Induced Single-Crystal to Single-Crystal Transformation.Cryst. Growth. & Des.2017.
(12)Du, Z.-L.; Dang, Q.-Q.; Zhang, X.-M. Heptazine-Based Porous Framework Supported Palladium Nanoparticles for Green Suzuki–Miyaura Reaction.Industrial & Engineering Chemistry Research2017,56, 4275-4280.
(13)Dang, Q.-Q.; Wan, H.-J.; Zhang, X.-M. Carbazolic Porous Framework with Tetrahedral Core for Gas Uptake and Tandem Detection of Iodide and Mercury.ACS Applied Materials & Interfaces2017,9, 21438-21446.
(14)Chen, Y.-G.; Yang, N.; Jiang, X.-X.; Guo, Y.; Zhang, X.-M. Pb@Pb8 Basket-like-Cluster-Based Lead Tellurate–Nitrate Kleinman-Forbidden Nonlinear-Optical Crystal: Pb9Te2O13(OH)(NO3)3.Inorganic Chemistry2017,56, 7900-7906.
(15)Chen, Y.-G.; Xing, M.-L.; Liu, P.-F.; Guo, Y.; Yang, N.; Zhang, X.-M. Two Phosphates: Noncentrosymmetric Cs6Mg6(PO3)18 and Centrosymmetric Cs2MgZn2(P2O7)2.Inorganic Chemistry2017,56, 845-851.
2016
(16)Zhao, Y.-W.; Zhang, F.-Q.; Zhang, X.-M. Single Component Lanthanide Hybrids Based on Metal–Organic Framework for Near-Ultraviolet White Light LED.ACS Applied Materials & Interfaces2016,8, 24123-24130.
(17)Zhang, X.-M.; Sarma, D.; Wu, Y.-Q.; Wang, L.; Ning, Z.-X.; Zhang, F.-Q.; Kanatzidis, M. G. Open-Framework Oxysulfide Based on the Supertetrahedral [In4Sn16O10S34]12– Cluster and Efficient Sequestration of Heavy Metals.J. Am. Chem. Soc.2016,138, 5543-5546.
(18)Zhang, L.-J.; Wang, Y.-H.; Liu, J.; Xu, M.-C.; Zhang, X.-M. Efficient and environmentally friendly Glaser coupling of terminal alkynes catalyzed by multinuclear copper complexes under base-free conditions.RSC Advances2016,6, 28653-28657.
(19)Zhang, L. J.; Xu, M. C.; Liu, J.; Zhang, X. M. Tandem cycloaddition-decarboxylation of α-keto acid and isocyanide under oxidant-free conditions towards monosubstituted oxazoles.RSC Advances2016,6, 73450-73453.
(20)Zhang, F.; Li, J.; Li, X.; Yang, M.; Yang, H.; Zhang, X.-M. In Situ Surface Engineering of Mesoporous Silica Generates Interfacial Activity and Catalytic Acceleration Effect.ACS Omega2016,1, 930-938.
(21)Yao, R.-X.; Qiao, X.-H.; Cui, X.; Jia, X.-X.; Zhang, X.-M. Hexagonal Co6and zigzag Co4cluster based magnetic MOFs with apcunet for selective catalysis.Inorganic Chemistry Frontiers2016,3, 78-85.
(22)Yao, R.-X.; Cui, X.; Jia, X.-X.; Zhang, F.-Q.; Zhang, X.-M. A Luminescent Zinc(II) Metal–Organic Framework (MOF) with Conjugated π-Electron Ligand for High Iodine Capture and Nitro-Explosive Detection.Inorganic Chemistry2016,55, 9270-9275.
(23)Yang, K.; Li, S.-L.; Zhang, F.-Q.; Zhang, X.-M. Simultaneous Luminescent Thermochromism, Vapochromism, Solvatochromism, and Mechanochromism in a C3-Symmetric Cubane [Cu4I4P4] Cluster without Cu–Cu Interaction.Inorganic Chemistry2016,55, 7323-7325.
(24)Wang, J.; Li, S.-L.; Zhang, X.-M. Photochromic and Nonphotochromic Luminescent Supramolecular Isomers Based on Carboxylate-Functionalized Bipyridinium Ligand: (4,4)-Net versus Interpenetrated (6,3)-Net.ACS Applied Materials & Interfaces2016,8, 24862-24869.
(25)Ren, H.-Y.; Zhang, X.-M. Enhanced Selective CO2 Capture upon Incorporation of Dimethylformamide in the Cobalt Metal–Organic Framework [Co3(OH)2(btca)2].Energy & Fuels2016,30, 526-530.
(26)Qu, M.; Chen, S.; Ma, W.; Chen, J.; Kong, K.; Zhang, F.; Li, H.; Hou, Z.; Zhang, X.-M. Phase Transfer of Nanoparticles Using an Amphiphilic Ionic Liquid.Langmuir2016,32, 13746-13751.
(27)Qin, Y.-L.; Wu, Y.-Q.; Hou, J.-J.; Zhang, X.-M. Cyanide-bridged mixed-valence copper(II/I) coordination polymers: Unique 7-connected sev-type 3D network versus anionic 2D host network encapsulated with cationic complex.Inorg. Chem.y Commun.2016,63, 101-106.
(28)Hou, J.-J.; Li, X.-Q.; Tian, B.-Q.; Zhang, X.-M. Genuine supramolecular isomers based on Y-shaped pyridinedicarboxylate ligands with distinct topology: 2D 63layer, kgd layer to 3D rtl net.CrystEngComm2016,18, 2065-2071.
(29)He, G.-X.; Chen, Y.-g.; Yang, N.; Xing, M.-L.; Zhang, X.-M. KSbI6O18: An antimony iodate semiconductor material with cyclic chiral S6-symmetric hexaiodate.Inorg. Chem.y Commun.2016,65, 13-15.
(30)Fu, D.; Li, H.; Zhang, X.-M.; Han, G.; Zhou, H.; Chang, Y. Flexible solid-state supercapacitor fabricated by metal-organic framework/graphene oxide hybrid interconnected with PEDOT.Materials Chemistry and Physics2016,179, 166-173.
(31)Fan, X.; Liu, Y.; Peng, Z.; Zhang, Z.; Zhou, H.; Zhang, X.; Yakobson, B. I.; Goddard, W. A.; Guo, X.; Hauge, R. H.; Tour, J. M. Atomic H-Induced Mo2C Hybrid as an Active and Stable Bifunctional Electrocatalyst.ACS Nano2016.
(32)Dang, Q.-Q.; Wang, X.-M.; Zhan, Y.-F.; Zhang, X.-M. An azo-linked porous triptycene network as an absorbent for CO2 and iodine uptake.Polymer Chemistry2016,7, 643-647.
2015
(33)秦英恋;李士利;姜宁;张献明.颜色可区分的氰桥五边形带经亲铜作用聚集的民金属多形体.无机化学学报2015,31, 1785-1779.
(34)Zhang, X.-M.; Hou, J.-J.; Guo, C.-H.; Li, C.-F. A New Class of Cuprous Bromide Cluster-Based Hybrid Materials: Direct Observation of the Stepwise Replacement of Hydrogen Bonds by Coordination Bonds.Inorganic Chemistry2015,54, 554-559.
(35)Zhang, L.-J.; Han, C.-Y.; Dang, Q.-Q.; Wang, Y.-H.; Zhang, X.-M. Solvent-Free Heterogeneous Catalysis for Cyanosily-lation in a Modified Sodalite-typed Cu(II)-MOF.RSC adavance2015,5, 24293-24298.
(36)Zhang, F.; Chen, S.; Li, H.; Zhang, X.-M.; Yang, H. Pd nanoparticles embedded in the outershell of a mesoporous core-shell catalyst for phenol hydrogenation in pure water.RSC Advances2015,5, 102811-102817.
(37)Yao, R.-X.; Hailili, R.; Cui, X.; Wang, L.; Zhang, X.-M. A perfectly aligned 63 helical tubular cuprous bromide single crystal for selective photo-catalysis, luminescence and sensing of nitro-explosives.Dalton Trans.2015,44, 3410-3416.
(38)Yao, R.-X.; Cui, X.; Wang, J.; Zhang, X.-M. D3 Symmetric [(NaO3)Co3] Clusters Based Homochiral Magnet from Spontaneous Resolution to Absolute Chiral Induction.Chem. Commun.2015,51, 5108-5111.
(39)Wang, Y.-H.; Xu, M.-C.; Liu, J.; Zhang, L.-J.; Zhang, X.-M. Three-coordinate copper(I) 2-hydroxy-1,10-phenanthroline dinuclear complex catalyzed homocoupling of arylboronic acids towards biphenyls under air condition.Tetrahedron2015,71, 9598-9601.
(40)Ren, H.-Y.; Yao, R.-X.; Zhang, X.-M. Enhanced Catalysis Activity in a Coordinatively Unsaturated Cobalt-MOF Generated via Single-Crystal-to-Single-Crystal Dehydration.Inorganic Chemistry2015,54, 6312-6318.
(41)Liu, M.-M.; Bi, Y.-L.; Dang, Q.-Q.; Zhang, X.-M. Reversible single-crystal-to-single-crystal transformation from a mononuclear complex to a fourfold interpenetrated MOF with selective adsorption of CO2.Dalton Trans.2015,44, 19796-19799.
(42)Liu, J.; Qu, M.; Clerac, R.; Zhang, X.-M. A two-dimensional honeycomb coordination network based on fused triacontanuclear heterometallic {Co12Mn18} wheels.Chem. Commun.2015,51, 7356-7359.
(43)Li, S.-L.; Zhang, F.-Q.; Zhang, X.-M. An Organic-Ligand-Free Thermochromic Luminescent Cuprous Iodide Trinuclear Cluster: Evidence for Cluster Centered Emission and Configuration Distortion with Temperature.Chem. Commun.2015,51, 8062-8065.
(44)Hou, J.-J.; Xu, X.; Jiang, N.; Wu, Y.-Q.; Zhang, X.-M. Selective adsorption in two porous triazolate–oxalate-bridged antiferromagnetic metal-azolate frameworks obtained via in situ decarboxylation of 3-amino-1,2,4-triazole-5-carboxylic acid.Journal of Solid State Chemistry2015, 73-78.
(45)Han, C.-Y.; Qu, M.; Dang, Q.-Q.; Zhang, X.-M. An non-centrosymmetric mononuclear Zr complex exhibiting UV second-harmonic-generation.Functional Materials Letters2015,08, 1550029.
(46)Hailili, R.; Wang, L.; Qv, J.; Yao, R.; Zhang, X.-M.; Liu, H. Planar Mn4O Cluster Homochiral Metal–Organic Framework for HPLC Separation of Pharmaceutically Important (±)-Ibuprofen Racemate.Inorganic Chemistry2015,54, 3713-3715.
(47)Duan, L.-N.; Dang, Q.-Q.; Han, C.-Y.; Zhang, X.-M. An interpenetrated bioactive nonlinear optical MOF containing a coordinated quinolone-like drug and Zn(ii) for pH-responsive release.Dalton Trans.2015,44, 1800-1804.
(48)Dang, Q.-Q.; Zhan, Y.-F.; Wang, X.-M.; Zhang, X.-M. Heptazine-Based Porous Framework for Selective CO2 Sorption and Organocatalytic Performances.ACS Appl Mater Interfaces2015,7, 28452-28458.
(49)Dang, Q.-Q.; Zhan, Y.-F.; Duan, L.-N.; Zhang, X.-M. A pyridyl-decorated MOF-505 analogue exhibiting hierarchical porosity, selective CO2 capture and catalytic capacity.Dalton Trans.2015,44, 20027-20031.
(50)Cui, X.; Xu, M.-C.; Zhang, L.-J.; Yao, R.-X.; Zhang, X.-M. Solvent-free heterogeneous catalysis for cyanosilylation in a dynamic cobalt-MOF.Dalton Trans.2015,44, 12711-12716.
(51)Abudoureheman, M.; Wang, L.; Zhang, X.; Yu, H.; Yang, Z.; Lei, C.; Han, J.; Pan, S. Pb7O(OH)3(CO3)3(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation Response.Inorganic Chemistry2015,54, 4138-4142.
2014
(52)Yao, R.-X.; Xu, X.; Zhang, X.-M. Ferromagnetically Coupled Chiral Dysprosium Hydroxysulfate and Centrosymmetric Dysprosium Hydroxysulfate-oxalate: Dy4(OH)4 Cubane Based High-Connected Networks via In Situ Conversion of Organosulfur to Sulfate.RSC adavance2014,4, 53954 - 53959.
(53)Ren, H.-Y.; Ning, Z.-X.; Hou, J.-J. Ultrasound and solvent-induced reversible chromism in a luminescent chalcogenidostannate.Journal of Coordination Chemistry2014,67, 1079-1087.
(54)Ren, H.-Y.; Han, C.-Y.; Qu, M.; Zhang, X.-M. Luminescent Group 12 Metal Tetracarboxylate Networks for Probe Metal Ions.RSC adavance2014,4, 49090- 49097.
(55)Qu, M.; Liu, M.; Liu, J.; Zhang, X. Tunable Nonlinear Optical Property and Photocatalytic Activity on Luminescent Chiral Lanthanide Chains.Chinese Journal of Chemistry2014,32, 1259-1266.
(56)Qi, Z.-K.; Zhang, F.-Q.; Yao, R.-X.; Liu, J.-L.; Zhang, X.-M. Mixed CoN4Cl2 and CoCl4 units versus two CoN2Cl3 units in [Co2(Htbi)2Cl4] isomers.Inorg. Chem.y Commun.2014,39, 21-25.
(57)Qi, Z.-K.; Liu, J.-L.; Hou, J.-J.; Liu, M.-M.; Zhang, X.-M. Planar Cu2(ppz)2 Dimers as SBUs for Diverse Polyoxometalate-Based Metal Organic Frameworks.Cryst. Growth. & Des.2014,14, 5773-5783.
(58)Liu, M.-M.; Hou, J.-J.; Qi, Z.-k.; Duan, L. N.; Ji, W.-J.; Han, C.-y.; Zhang, X.-M. Tuning of Valence States, Bonding Types, Hierarchical Structures, and Physical Properties in Copper/Halide/Isonicotinate System.Inorganic Chemistry2014,53, 1430-4143.
(59)Liu, J.; Qu, M.; Rouzières, M.; Zhang, X.-M.; Clérac, R. A Single-Chain Magnet Based on {CoII4} Complexes and Azido/Picolinate Ligands.Inorganic Chemistry2014,53, 7870-7875.
(60)Li, S.-L.; Zhang, X.-M. Cu3I7 Trimer and Cu4I8 Tetramer Based Cuprous Iodide Polymorphs for Efficient Photocatalysis and Luminescent Sensing: Unveiling Possible Hierarchical Assembly Mechanism.Inorganic Chemistry2014,53, 8376-8383.
2013
(61)Yao, R.-X.; Qin, Y.-L.; Ji, F.; Zhao, Y.-F.; Zhang, X.-M. Triangle, square and delta-chain based cobalt tetrazolate magnets.Dalton Trans.2013,42, 6611-6618.
(62)Wu, Y.-Q.; Qin, Y.-L.; Li, C.-R.; Zhang, X.-M. (H2en)0.5[BiO(OH)2(H2O)]: The first organic templated layered bismuthate.Inorg. Chem.y Commun.2013,30, 133-135.
(63)Qin, Y.-L.; Yao, R.-X.; Wu, G.-X.; Liu, M.-M.; Zhang, X.-M. Heterometallic Mixed-Valence Copper(I,II) Cyanides that were Tuned by Using the Chelate Effect: Discovery of Famous Cairo Pentagonal Tiling and Unprecedented (3,4)-Connected {83}2{86} Topological 3D Net.Chemistry – An Asian Journal2013,8, 1587-1595.
(64)Liu, M.-M.; Han, C.-Y.; Qin, Y.-L.; Zhang, X.-M. Mn8@Na8 Cube-in-Cube SBBs-Based Heterometallic Coordination Network with Unprecedented (39.46)8 Topological Mn8(μ4-OMe)6 Cubes.Cryst. Growth. & Des.2013,13, 1386-1389.
(65)Liu, J.; Qin, Y. L.; Qu, M.; Clerac, R.; Zhang, X. M. Rung-defected ladder of azido-bridged Cu(II) chains linked by [Cu(picolinate)2] units.Dalton Trans.2013,42, 11571-11575.
(66)Li, S.-L.; Zhang, R.; Hou, J.-J.; Zhang, X.-M. Photoluminescent cuprous iodide polymorphs generated via in situ organic reactions.Inorg. Chem.y Commun.2013,32, 12-17.
(67)Jiang, D.-P.; Yao, R.-X.; Ji, F.; Zhang, X.-M. Cuprous Halide Coordination Polymers Based on Cationic [Cu4X2] and [Cu3X] Clusters and [Cu2Br]nLayers with Tetrazolates as Assembling Ligands: Highly Connected Networks and Halide-Dependent Luminescence.Eur. J. Inorg. Chem.2013, 556-562.
(68)Hou, J.-J.; Zhang, R.; Qin, Y.-L.; Zhang, X.-M. From (3,6)-Connected kgd, chiral anh to (3,8)-connected tfz-d Nets in Low Nuclear Metal Cluster-Based Networks with Triangular Pyridinedicarboxylate Ligand.Cryst. Growth. & Des.2013,13, 1618-1625.
2012
(69)Yao, R.-X.; Xu, X.; Zhang, X.-M. Magnetic Modulation and Cation-Exchange in a Series of Isostructural (4,8)-Connected Metal–Organic Frameworks with Butterfly-like [M4(OH)2(RCO2)8] Building Units.Chem. Mater.2012,24, 303-310.
(70)Qin, Y.-L.; Liu, J.; Hou, J.-J.; Yao, R.-X.; Zhang, X.-M. Reconstruction of a (6,3) Brick Wall Sheet Giving an Unprecedented Shubnikov-type (5,34) Sheet in Luminescent Cuprous Cyanide Supramolecular Isomers of Pseudo-polyrotaxane.Cryst. Growth. & Des.2012,12, 6068-6073.
(71)Gao, H.; Zhang, X.-M. Three novel Bi(III) complexes with in situ generated anilate ligands: unusual oxidation of cyclohexanedione to dihydroxy benzoquinone.Dalton Trans.2012,41, 1562-1567.
(72)Dang, Q.; Ji, F.; Zhang, X. A Unique Solvent-Induced Structural Transformation of Two Acentric [Zn2(H2O)(Hdtim)2] Isomers.Chinese Journal of Chemistry2012,30, 2232-2236.
2011
(73)Zhang, X.-M.; Lv, J.; Ji, F.; Wu, H.-S.; Jiao, H.; Schleyer, P. v. R. A Perfectly Square-Planar Tetracoordinated Oxygen in a Tetracopper Cluster-Based Coordination Polymer.J. Am. Chem. Soc.2011,133, 4788-4790.
(74)Zhang, X.-H.; Hao, Z.-M.; Zhang, X.-M. Spin Canting and Metamagnetism in the First Hybrid Cobalt–Hypoxanthine Open Framework with umr Topology.Chem. Eur. J.2011,17, 5588-5594.
(75)Qin, Y.-L.; Hou, J.-J.; Lv, J.; Zhang, X.-M. Organic Templated Cuprous Cyanide Open Frameworks Based on Cu2(CN)6 Dimer with Strong and Long-Lived Luminescence.Cryst. Growth. & Des.2011,11, 3101-3108.
(76)Hao, Z.-M.; Zhang, X.-M. Solvent induced molecular magnetic changes observed in single-crystal-to-single-crystal transformation.Dalton Trans.2011,40, 2092-2098.
2010
(77)Zhang, F.-Q.; Zhang, X.-M.; Fang, R.-Q.; Wu, H.-S. P6Mo18O73 heteropolyanion and its four-copper complex: theoretical and experimental investigation.Dalton Trans.2010,39, 8256-8260.
(78)Yao, R.-X.; Hao, Z.-M.; Guo, C.-H.; Zhang, X.-M. Enantiomers of conformation-flexible cyclopentane-1,2,3,4-tetracarboxylate in metala[euro sign]"organic frameworks.CrystEngComm2010,12, 4416-4423.
(79)Wu, G.-X.; Wu, H.-S.; Zhang, X.-M. A hybrid cobalt hydroxyacetate magnet: ionothermal synthesis, 3-D Co-O-Co connectivity and spin glass behavior.Dalton Trans.2010,39, 1179-1181.
(80)Jia, J.; Wu, H.-S.; Xu, X.-H.; Zhang, X.-M.; Jiao, H. Structure and Stability of Endohedral X@C60F, X@C60F2 (X = N, H), and (H@C60)2.J. Phys.l Chem. C2010,114, 7558-7562.
(81)Hou, J.-J.; Li, S.-L.; Li, C.-R.; Zhang, X.-M. In situ alkylation of N-heterocycles in organic templated cuprous halides.Dalton Trans.2010,39, 2701-2707.
(82)Hao, Z.-M.; Wang, J.; Zhang, X.-M. Red phosphorescent cuprous halide/pseudohalide coordination polymers with pyrimidine-2-thionates as Co-ligands.CrystEngComm2010,12, 1103-1109.
(83)Hao, Z.-M.; Li, S.-L.; Zhang, X.-M. Spin canting in a novel (3,4)-connected mixed-valence cobalt coordination polymer based on oxalates and [Co(Hbiim)3] (H2biim = 2,2'-biimidazole) building blocks.Inorg. Chem.y Commun.2010,13, 1100-1102.
(84)Hao, Z.-M.; Guo, C.-H.; Wu, H.-S.; Zhang, X.-M. Luminescent boracite-like metal-organic frameworks constructed by Cu-centered CuCu4 tetrahedra and CuCu3 triangles with an acentric cubic superlarge cell.CrystEngComm2010,12, 55-58.
(85)Guo, C.-H.; Song, J.-Y.; Jia, J.-F.; Zhang, X.-M.; Wu, H.-S. A DFT Study on the Mechanism of the Coupling Reaction between Chloromethyloxirane and Carbon Dioxide Catalyzed by Re(CO)5Br.Organometallics2010,29, 2069-2079.
2000-2009
(1)Zhao, Y.-W.; Wang, Y.; Zhang, X.-M. Homochiral MOF as Circular Dichroism Sensor for Enantioselective Recognition on Nature and Chirality of Unmodified Amino Acids.ACS Applied Materials & Interfaces2017,9, 20991-20999.
(2)Zhang, Y.; Wang, L.; Yao, R.-X.; Zhang, X.-M. Fourfold-Interpenetrated MOF [Ni(pybz)2] as Coating Material in Gas Chromatographic Capillary Column for Separation.Inorganic Chemistry2017,56, 8912-8919.
(3)Zhang, F.; Zhao, C.; Chen, S.; Li, H.; Yang, H.; Zhang, X.-M. In situ mosaic strategy generated Co-based N-doped mesoporous carbon for highly selective hydrogenation of nitroaromatics.Journal of Catalysis2017,348, 212-222.
(4)Zhang, F.; Ma, C.; Zhang, Y.; Zhao, L.; Li, H.; Fu, D.; Zhang, X.-M. N-doped Mesoporous Carbon Embedded Non-noble Metals for Highly Efficient and Stable H2 Generation from Ammonia Borane.ACS Catalysis2017, May-24 submitted.
(5)Yao, R.-X.; Yu, B.; Fu, H.-H.; Zhang, X.-M. Chiral Metal−Organic Frameworks Constructed by Four-fold Helical Chains SBUs for Enantioselective Recognition α-hydroxy/amino Acids.Inorg. Chem.2017, revision requested Jul-05.
(6)Wei, T.; Sun, J.; Zhang, F.; Zhang, J.; Chen, J.; Li, H.; Zhang, X.-M. Acetylene mediated synthesis of Au/graphene nanocomposite for selective hydrogenation.Catalysis Communications2017,93, 43-46.
(7)Wang, J. H.; Zhang, Y.; Li, M.; Yan, S.; Li, D.; Zhang, X. M. Solvent-Assisted Metal Metathesis: A Highly Efficient and Versatile Route towards Synthetically Demanding Chromium Metal-Organic Frameworks.Angew. Chem. Int. Ed.2017,56, 6478-6482.
(8)Qu, M.; Li, H.; Xie, L.-H.; Yan, S.-T.; Li, J.-R.; Wang, J.-H.; Wei, C.-Y.; Wu, Y.-W.; Zhang, X.-M. Bidentate Phosphine–Assisted Synthesis of an All–Alkynyl–Protected Ag74 Nanocluster.J Am Chem Soc2017, revised July 06.
(9)Li, S.-L.; Wang, J.; Zhang, F.-Q.; Zhang, X.-M. Light and Heat Dually Responsive Luminescence in Organic Templated CdSO4-type Halogeno(cyano)cuprates with Disorder of Halogenide/Cyanide.Cryst. Growth. & Des.2017,17, 746-752.
(10)Jia, X.-X.; Yao, R.-X.; Zhang, F.-Q.; Zhang, X.-M. A Fluorescent Anionic MOF with Zn4(trz)2 Chain for Highly Selective Visual Sensing of Contaminants: Cr(III) Ion and TNP.Inorganic Chemistry2017,56, 2690-2696.
(11)Hou, J.-J.; Li, X.-Q.; Gao, P.; Sun, H.-Q.; Zhang, X.-M. Tunability in Metal Coordination Sphere, Ligand Coordination Mode, Network Topology, and Magnetism via Stepwise Dehydration Induced Single-Crystal to Single-Crystal Transformation.Cryst. Growth. & Des.2017.
(12)Du, Z.-L.; Dang, Q.-Q.; Zhang, X.-M. Heptazine-Based Porous Framework Supported Palladium Nanoparticles for Green Suzuki–Miyaura Reaction.Industrial & Engineering Chemistry Research2017,56, 4275-4280.
(13)Dang, Q.-Q.; Wan, H.-J.; Zhang, X.-M. Carbazolic Porous Framework with Tetrahedral Core for Gas Uptake and Tandem Detection of Iodide and Mercury.ACS Applied Materials & Interfaces2017,9, 21438-21446.
(14)Chen, Y.-G.; Yang, N.; Jiang, X.-X.; Guo, Y.; Zhang, X.-M. Pb@Pb8 Basket-like-Cluster-Based Lead Tellurate–Nitrate Kleinman-Forbidden Nonlinear-Optical Crystal: Pb9Te2O13(OH)(NO3)3.Inorganic Chemistry2017,56, 7900-7906.
(15)Chen, Y.-G.; Xing, M.-L.; Liu, P.-F.; Guo, Y.; Yang, N.; Zhang, X.-M. Two Phosphates: Noncentrosymmetric Cs6Mg6(PO3)18 and Centrosymmetric Cs2MgZn2(P2O7)2.Inorganic Chemistry2017,56, 845-851.
(16)Zhao, Y.-W.; Zhang, F.-Q.; Zhang, X.-M. Single Component Lanthanide Hybrids Based on Metal–Organic Framework for Near-Ultraviolet White Light LED.ACS Applied Materials & Interfaces2016,8, 24123-24130.
(17)Zhang, X.-M.; Sarma, D.; Wu, Y.-Q.; Wang, L.; Ning, Z.-X.; Zhang, F.-Q.; Kanatzidis, M. G. Open-Framework Oxysulfide Based on the Supertetrahedral [In4Sn16O10S34]12– Cluster and Efficient Sequestration of Heavy Metals.J. Am. Chem. Soc.2016,138, 5543-5546.
(18)Zhang, L.-J.; Wang, Y.-H.; Liu, J.; Xu, M.-C.; Zhang, X.-M. Efficient and environmentally friendly Glaser coupling of terminal alkynes catalyzed by multinuclear copper complexes under base-free conditions.RSC Advances2016,6, 28653-28657.
(19)Zhang, L. J.; Xu, M. C.; Liu, J.; Zhang, X. M. Tandem cycloaddition-decarboxylation of α-keto acid and isocyanide under oxidant-free conditions towards monosubstituted oxazoles.RSC Advances2016,6, 73450-73453.
(20)Zhang, F.; Li, J.; Li, X.; Yang, M.; Yang, H.; Zhang, X.-M. In Situ Surface Engineering of Mesoporous Silica Generates Interfacial Activity and Catalytic Acceleration Effect.ACS Omega2016,1, 930-938.
(21)Yao, R.-X.; Qiao, X.-H.; Cui, X.; Jia, X.-X.; Zhang, X.-M. Hexagonal Co6and zigzag Co4cluster based magnetic MOFs with apcunet for selective catalysis.Inorganic Chemistry Frontiers2016,3, 78-85.
(22)Yao, R.-X.; Cui, X.; Jia, X.-X.; Zhang, F.-Q.; Zhang, X.-M. A Luminescent Zinc(II) Metal–Organic Framework (MOF) with Conjugated π-Electron Ligand for High Iodine Capture and Nitro-Explosive Detection.Inorganic Chemistry2016,55, 9270-9275.
(23)Yang, K.; Li, S.-L.; Zhang, F.-Q.; Zhang, X.-M. Simultaneous Luminescent Thermochromism, Vapochromism, Solvatochromism, and Mechanochromism in a C3-Symmetric Cubane [Cu4I4P4] Cluster without Cu–Cu Interaction.Inorganic Chemistry2016,55, 7323-7325.
(24)Wang, J.; Li, S.-L.; Zhang, X.-M. Photochromic and Nonphotochromic Luminescent Supramolecular Isomers Based on Carboxylate-Functionalized Bipyridinium Ligand: (4,4)-Net versus Interpenetrated (6,3)-Net.ACS Applied Materials & Interfaces2016,8, 24862-24869.
(25)Ren, H.-Y.; Zhang, X.-M. Enhanced Selective CO2 Capture upon Incorporation of Dimethylformamide in the Cobalt Metal–Organic Framework [Co3(OH)2(btca)2].Energy & Fuels2016,30, 526-530.
(26)Qu, M.; Chen, S.; Ma, W.; Chen, J.; Kong, K.; Zhang, F.; Li, H.; Hou, Z.; Zhang, X.-M. Phase Transfer of Nanoparticles Using an Amphiphilic Ionic Liquid.Langmuir2016,32, 13746-13751.
(27)Qin, Y.-L.; Wu, Y.-Q.; Hou, J.-J.; Zhang, X.-M. Cyanide-bridged mixed-valence copper(II/I) coordination polymers: Unique 7-connected sev-type 3D network versus anionic 2D host network encapsulated with cationic complex.Inorg. Chem.y Commun.2016,63, 101-106.
(28)Hou, J.-J.; Li, X.-Q.; Tian, B.-Q.; Zhang, X.-M. Genuine supramolecular isomers based on Y-shaped pyridinedicarboxylate ligands with distinct topology: 2D 63layer, kgd layer to 3D rtl net.CrystEngComm2016,18, 2065-2071.
(29)He, G.-X.; Chen, Y.-g.; Yang, N.; Xing, M.-L.; Zhang, X.-M. KSbI6O18: An antimony iodate semiconductor material with cyclic chiral S6-symmetric hexaiodate.Inorg. Chem.y Commun.2016,65, 13-15.
(30)Fu, D.; Li, H.; Zhang, X.-M.; Han, G.; Zhou, H.; Chang, Y. Flexible solid-state supercapacitor fabricated by metal-organic framework/graphene oxide hybrid interconnected with PEDOT.Materials Chemistry and Physics2016,179, 166-173.
(31)Fan, X.; Liu, Y.; Peng, Z.; Zhang, Z.; Zhou, H.; Zhang, X.; Yakobson, B. I.; Goddard, W. A.; Guo, X.; Hauge, R. H.; Tour, J. M. Atomic H-Induced Mo2C Hybrid as an Active and Stable Bifunctional Electrocatalyst.ACS Nano2016.
(32)Dang, Q.-Q.; Wang, X.-M.; Zhan, Y.-F.; Zhang, X.-M. An azo-linked porous triptycene network as an absorbent for CO2 and iodine uptake.Polymer Chemistry2016,7, 643-647.
(33)秦英恋;李士利;姜宁;张献明.颜色可区分的氰桥五边形带经亲铜作用聚集的民金属多形体.无机化学学报2015,31, 1785-1779.
(34)Zhang, X.-M.; Hou, J.-J.; Guo, C.-H.; Li, C.-F. A New Class of Cuprous Bromide Cluster-Based Hybrid Materials: Direct Observation of the Stepwise Replacement of Hydrogen Bonds by Coordination Bonds.Inorganic Chemistry2015,54, 554-559.
(35)Zhang, L.-J.; Han, C.-Y.; Dang, Q.-Q.; Wang, Y.-H.; Zhang, X.-M. Solvent-Free Heterogeneous Catalysis for Cyanosily-lation in a Modified Sodalite-typed Cu(II)-MOF.RSC adavance2015,5, 24293-24298.
(36)Zhang, F.; Chen, S.; Li, H.; Zhang, X.-M.; Yang, H. Pd nanoparticles embedded in the outershell of a mesoporous core-shell catalyst for phenol hydrogenation in pure water.RSC Advances2015,5, 102811-102817.
(37)Yao, R.-X.; Hailili, R.; Cui, X.; Wang, L.; Zhang, X.-M. A perfectly aligned 63 helical tubular cuprous bromide single crystal for selective photo-catalysis, luminescence and sensing of nitro-explosives.Dalton Trans.2015,44, 3410-3416.
(38)Yao, R.-X.; Cui, X.; Wang, J.; Zhang, X.-M. D3 Symmetric [(NaO3)Co3] Clusters Based Homochiral Magnet from Spontaneous Resolution to Absolute Chiral Induction.Chem. Commun.2015,51, 5108-5111.
(39)Wang, Y.-H.; Xu, M.-C.; Liu, J.; Zhang, L.-J.; Zhang, X.-M. Three-coordinate copper(I) 2-hydroxy-1,10-phenanthroline dinuclear complex catalyzed homocoupling of arylboronic acids towards biphenyls under air condition.Tetrahedron2015,71, 9598-9601.
(40)Ren, H.-Y.; Yao, R.-X.; Zhang, X.-M. Enhanced Catalysis Activity in a Coordinatively Unsaturated Cobalt-MOF Generated via Single-Crystal-to-Single-Crystal Dehydration.Inorganic Chemistry2015,54, 6312-6318.
(41)Liu, M.-M.; Bi, Y.-L.; Dang, Q.-Q.; Zhang, X.-M. Reversible single-crystal-to-single-crystal transformation from a mononuclear complex to a fourfold interpenetrated MOF with selective adsorption of CO2.Dalton Trans.2015,44, 19796-19799.
(42)Liu, J.; Qu, M.; Clerac, R.; Zhang, X.-M. A two-dimensional honeycomb coordination network based on fused triacontanuclear heterometallic {Co12Mn18} wheels.Chem. Commun.2015,51, 7356-7359.
(43)Li, S.-L.; Zhang, F.-Q.; Zhang, X.-M. An Organic-Ligand-Free Thermochromic Luminescent Cuprous Iodide Trinuclear Cluster: Evidence for Cluster Centered Emission and Configuration Distortion with Temperature.Chem. Commun.2015,51, 8062-8065.
(44)Hou, J.-J.; Xu, X.; Jiang, N.; Wu, Y.-Q.; Zhang, X.-M. Selective adsorption in two porous triazolate–oxalate-bridged antiferromagnetic metal-azolate frameworks obtained via in situ decarboxylation of 3-amino-1,2,4-triazole-5-carboxylic acid.Journal of Solid State Chemistry2015, 73-78.
(45)Han, C.-Y.; Qu, M.; Dang, Q.-Q.; Zhang, X.-M. An non-centrosymmetric mononuclear Zr complex exhibiting UV second-harmonic-generation.Functional Materials Letters2015,08, 1550029.
(46)Hailili, R.; Wang, L.; Qv, J.; Yao, R.; Zhang, X.-M.; Liu, H. Planar Mn4O Cluster Homochiral Metal–Organic Framework for HPLC Separation of Pharmaceutically Important (±)-Ibuprofen Racemate.Inorganic Chemistry2015,54, 3713-3715.
(47)Duan, L.-N.; Dang, Q.-Q.; Han, C.-Y.; Zhang, X.-M. An interpenetrated bioactive nonlinear optical MOF containing a coordinated quinolone-like drug and Zn(ii) for pH-responsive release.Dalton Trans.2015,44, 1800-1804.
(48)Dang, Q.-Q.; Zhan, Y.-F.; Wang, X.-M.; Zhang, X.-M. Heptazine-Based Porous Framework for Selective CO2 Sorption and Organocatalytic Performances.ACS Appl Mater Interfaces2015,7, 28452-28458.
(49)Dang, Q.-Q.; Zhan, Y.-F.; Duan, L.-N.; Zhang, X.-M. A pyridyl-decorated MOF-505 analogue exhibiting hierarchical porosity, selective CO2 capture and catalytic capacity.Dalton Trans.2015,44, 20027-20031.
(50)Cui, X.; Xu, M.-C.; Zhang, L.-J.; Yao, R.-X.; Zhang, X.-M. Solvent-free heterogeneous catalysis for cyanosilylation in a dynamic cobalt-MOF.Dalton Trans.2015,44, 12711-12716.
(51)Abudoureheman, M.; Wang, L.; Zhang, X.; Yu, H.; Yang, Z.; Lei, C.; Han, J.; Pan, S. Pb7O(OH)3(CO3)3(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation Response.Inorganic Chemistry2015,54, 4138-4142.
(52)Yao, R.-X.; Xu, X.; Zhang, X.-M. Ferromagnetically Coupled Chiral Dysprosium Hydroxysulfate and Centrosymmetric Dysprosium Hydroxysulfate-oxalate: Dy4(OH)4 Cubane Based High-Connected Networks via In Situ Conversion of Organosulfur to Sulfate.RSC adavance2014,4, 53954 - 53959.
(53)Ren, H.-Y.; Ning, Z.-X.; Hou, J.-J. Ultrasound and solvent-induced reversible chromism in a luminescent chalcogenidostannate.Journal of Coordination Chemistry2014,67, 1079-1087.
(54)Ren, H.-Y.; Han, C.-Y.; Qu, M.; Zhang, X.-M. Luminescent Group 12 Metal Tetracarboxylate Networks for Probe Metal Ions.RSC adavance2014,4, 49090- 49097.
(55)Qu, M.; Liu, M.; Liu, J.; Zhang, X. Tunable Nonlinear Optical Property and Photocatalytic Activity on Luminescent Chiral Lanthanide Chains.Chinese Journal of Chemistry2014,32, 1259-1266.
(56)Qi, Z.-K.; Zhang, F.-Q.; Yao, R.-X.; Liu, J.-L.; Zhang, X.-M. Mixed CoN4Cl2 and CoCl4 units versus two CoN2Cl3 units in [Co2(Htbi)2Cl4] isomers.Inorg. Chem.y Commun.2014,39, 21-25.
(57)Qi, Z.-K.; Liu, J.-L.; Hou, J.-J.; Liu, M.-M.; Zhang, X.-M. Planar Cu2(ppz)2 Dimers as SBUs for Diverse Polyoxometalate-Based Metal Organic Frameworks.Cryst. Growth. & Des.2014,14, 5773-5783.
(58)Liu, M.-M.; Hou, J.-J.; Qi, Z.-k.; Duan, L. N.; Ji, W.-J.; Han, C.-y.; Zhang, X.-M. Tuning of Valence States, Bonding Types, Hierarchical Structures, and Physical Properties in Copper/Halide/Isonicotinate System.Inorganic Chemistry2014,53, 1430-4143.
(59)Liu, J.; Qu, M.; Rouzières, M.; Zhang, X.-M.; Clérac, R. A Single-Chain Magnet Based on {CoII4} Complexes and Azido/Picolinate Ligands.Inorganic Chemistry2014,53, 7870-7875.
(60)Li, S.-L.; Zhang, X.-M. Cu3I7 Trimer and Cu4I8 Tetramer Based Cuprous Iodide Polymorphs for Efficient Photocatalysis and Luminescent Sensing: Unveiling Possible Hierarchical Assembly Mechanism.Inorganic Chemistry2014,53, 8376-8383.
(61)Yao, R.-X.; Qin, Y.-L.; Ji, F.; Zhao, Y.-F.; Zhang, X.-M. Triangle, square and delta-chain based cobalt tetrazolate magnets.Dalton Trans.2013,42, 6611-6618.
(62)Wu, Y.-Q.; Qin, Y.-L.; Li, C.-R.; Zhang, X.-M. (H2en)0.5[BiO(OH)2(H2O)]: The first organic templated layered bismuthate.Inorg. Chem.y Commun.2013,30, 133-135.
(63)Qin, Y.-L.; Yao, R.-X.; Wu, G.-X.; Liu, M.-M.; Zhang, X.-M. Heterometallic Mixed-Valence Copper(I,II) Cyanides that were Tuned by Using the Chelate Effect: Discovery of Famous Cairo Pentagonal Tiling and Unprecedented (3,4)-Connected {83}2{86} Topological 3D Net.Chemistry – An Asian Journal2013,8, 1587-1595.
(64)Liu, M.-M.; Han, C.-Y.; Qin, Y.-L.; Zhang, X.-M. Mn8@Na8 Cube-in-Cube SBBs-Based Heterometallic Coordination Network with Unprecedented (39.46)8 Topological Mn8(μ4-OMe)6 Cubes.Cryst. Growth. & Des.2013,13, 1386-1389.
(65)Liu, J.; Qin, Y. L.; Qu, M.; Clerac, R.; Zhang, X. M. Rung-defected ladder of azido-bridged Cu(II) chains linked by [Cu(picolinate)2] units.Dalton Trans.2013,42, 11571-11575.
(66)Li, S.-L.; Zhang, R.; Hou, J.-J.; Zhang, X.-M. Photoluminescent cuprous iodide polymorphs generated via in situ organic reactions.Inorg. Chem.y Commun.2013,32, 12-17.
(67)Jiang, D.-P.; Yao, R.-X.; Ji, F.; Zhang, X.-M. Cuprous Halide Coordination Polymers Based on Cationic [Cu4X2] and [Cu3X] Clusters and [Cu2Br]nLayers with Tetrazolates as Assembling Ligands: Highly Connected Networks and Halide-Dependent Luminescence.Eur. J. Inorg. Chem.2013, 556-562.
(68)Hou, J.-J.; Zhang, R.; Qin, Y.-L.; Zhang, X.-M. From (3,6)-Connected kgd, chiral anh to (3,8)-connected tfz-d Nets in Low Nuclear Metal Cluster-Based Networks with Triangular Pyridinedicarboxylate Ligand.Cryst. Growth. & Des.2013,13, 1618-1625.
(69)Yao, R.-X.; Xu, X.; Zhang, X.-M. Magnetic Modulation and Cation-Exchange in a Series of Isostructural (4,8)-Connected Metal–Organic Frameworks with Butterfly-like [M4(OH)2(RCO2)8] Building Units.Chem. Mater.2012,24, 303-310.
(70)Qin, Y.-L.; Liu, J.; Hou, J.-J.; Yao, R.-X.; Zhang, X.-M. Reconstruction of a (6,3) Brick Wall Sheet Giving an Unprecedented Shubnikov-type (5,34) Sheet in Luminescent Cuprous Cyanide Supramolecular Isomers of Pseudo-polyrotaxane.Cryst. Growth. & Des.2012,12, 6068-6073.
(71)Gao, H.; Zhang, X.-M. Three novel Bi(III) complexes with in situ generated anilate ligands: unusual oxidation of cyclohexanedione to dihydroxy benzoquinone.Dalton Trans.2012,41, 1562-1567.
(72)Dang, Q.; Ji, F.; Zhang, X. A Unique Solvent-Induced Structural Transformation of Two Acentric [Zn2(H2O)(Hdtim)2] Isomers.Chinese Journal of Chemistry2012,30, 2232-2236.
(73)Zhang, X.-M.; Lv, J.; Ji, F.; Wu, H.-S.; Jiao, H.; Schleyer, P. v. R. A Perfectly Square-Planar Tetracoordinated Oxygen in a Tetracopper Cluster-Based Coordination Polymer.J. Am. Chem. Soc.2011,133, 4788-4790.
(74)Zhang, X.-H.; Hao, Z.-M.; Zhang, X.-M. Spin Canting and Metamagnetism in the First Hybrid Cobalt–Hypoxanthine Open Framework with umr Topology.Chem. Eur. J.2011,17, 5588-5594.
(75)Qin, Y.-L.; Hou, J.-J.; Lv, J.; Zhang, X.-M. Organic Templated Cuprous Cyanide Open Frameworks Based on Cu2(CN)6 Dimer with Strong and Long-Lived Luminescence.Cryst. Growth. & Des.2011,11, 3101-3108.
(76)Hao, Z.-M.; Zhang, X.-M. Solvent induced molecular magnetic changes observed in single-crystal-to-single-crystal transformation.Dalton Trans.2011,40, 2092-2098.
(77)Zhang, F.-Q.; Zhang, X.-M.; Fang, R.-Q.; Wu, H.-S. P6Mo18O73 heteropolyanion and its four-copper complex: theoretical and experimental investigation.Dalton Trans.2010,39, 8256-8260.
(78)Yao, R.-X.; Hao, Z.-M.; Guo, C.-H.; Zhang, X.-M. Enantiomers of conformation-flexible cyclopentane-1,2,3,4-tetracarboxylate in metala[euro sign]"organic frameworks.CrystEngComm2010,12, 4416-4423.
(79)Wu, G.-X.; Wu, H.-S.; Zhang, X.-M. A hybrid cobalt hydroxyacetate magnet: ionothermal synthesis, 3-D Co-O-Co connectivity and spin glass behavior.Dalton Trans.2010,39, 1179-1181.
(80)Jia, J.; Wu, H.-S.; Xu, X.-H.; Zhang, X.-M.; Jiao, H. Structure and Stability of Endohedral X@C60F, X@C60F2 (X = N, H), and (H@C60)2.J. Phys.l Chem. C2010,114, 7558-7562.
(81)Hou, J.-J.; Li, S.-L.; Li, C.-R.; Zhang, X.-M. In situ alkylation of N-heterocycles in organic templated cuprous halides.Dalton Trans.2010,39, 2701-2707.
(82)Hao, Z.-M.; Wang, J.; Zhang, X.-M. Red phosphorescent cuprous halide/pseudohalide coordination polymers with pyrimidine-2-thionates as Co-ligands.CrystEngComm2010,12, 1103-1109.
(83)Hao, Z.-M.; Li, S.-L.; Zhang, X.-M. Spin canting in a novel (3,4)-connected mixed-valence cobalt coordination polymer based on oxalates and [Co(Hbiim)3] (H2biim = 2,2'-biimidazole) building blocks.Inorg. Chem.y Commun.2010,13, 1100-1102.
(84)Hao, Z.-M.; Guo, C.-H.; Wu, H.-S.; Zhang, X.-M. Luminescent boracite-like metal-organic frameworks constructed by Cu-centered CuCu4 tetrahedra and CuCu3 triangles with an acentric cubic superlarge cell.CrystEngComm2010,12, 55-58.
(85)Guo, C.-H.; Song, J.-Y.; Jia, J.-F.; Zhang, X.-M.; Wu, H.-S. A DFT Study on the Mechanism of the Coupling Reaction between Chloromethyloxirane and Carbon Dioxide Catalyzed by Re(CO)5Br.Organometallics2010,29, 2069-2079.
(86)Zhang, X.-M.; Jiang, T.; Wu, H.-S.; Zeng, M.-H. Spin Frustration and Long-Range Ordering in an AlB2-like Metal-Organic Framework with Unprecedented N,N,N-Tris-tetrazol-5-yl-amine Ligand.Inorganic Chemistry2009,48, 4536-4541.
(87)Li, C.-R.; Li, S.-L.; Zhang, X.-M. D3-Symmetric Supramolecular Cation {(Me2NH2)6(SO4)}4+ As a New Template for 3D Homochiral (10,3)-a Metal Oxalates.Cryst. Growth. & Des.2009,9, 1702-1707.
(88)Hao, Z.-M.; Liu, H.-P.; Han, H.-H.; Wang, W.-T.; Zhang, X.-M. A luminescent [Ag3S3]n-tube based metal-organic framework.Inorg. Chem.y Commun.2009,12, 375-377.
(89)Guo, C.-H.; Wu, H.-S.; Zhang, X.-M.; Song, J.-Y.; Zhang, X. A Comprehensive Theoretical Study on the Coupling Reaction Mechanism of Propylene Oxide with Carbon Dioxide Catalyzed by Copper(I) Cyanomethyl.J. Phys. Chem. A2009,113, 6710-6723.
(90)Zhang, X.-M.; Zhang, X.-H.; Wu, H.-S.; Tong, M.-L.; Ng, S. W. Hybrid Cobalt Hydroxyoxalate Material Containing 3D Co−O−Co Connectivity and Showing Ferrimagnetic Ordering.Inorganic Chemistry2008,47, 7462-7464.
(91)Zhang, X.-M.; Qing, Y.-L.; Wu, H.-S. Two Cuprous Cyanide Polymorphs: Diamond Net versus 3,4-Connected Net.Inorganic Chemistry2008,47, 2255-2257.
(92)Zhang, X.-M.; Li, C.-R.; Zhang, X.-H.; Zhang, W.-X.; Chen, X.-M. Unusual Slow Magnetic Relaxation in Helical Co3(OH)2 Ferrimagnetic Chain Based Cobalt Hydroxysulfates.Chem. Mater.2008,20, 2298-2305.
(93)Jiang, T.; Zhang, X.-M. Temperature Tuned Synthesis of Zinc N,N-bis-(1(2)H-tetrazol-5-yl)-amine Complexes: From Zn3O Cluster-Based 3-Connected 63-hcb and (3,6)-Connected (43)2(46)-kgd Layers to Zn5(OH)4 Chain-Based 3D Open Framework.Cryst. Growth. & Des.2008,8, 3077-3083.
(94)Jia, J.; Wu, H.-S.; Xu, X.-H.; Zhang, X.-M.; Jiao, H. Fused Five-Membered Rings Determine the Stability of C60F60.J. Am. Chem. Soc.2008,130, 3985-3988.
(95)Jia, J.; Wu, H.-S.; Xu, X.-H.; Zhang, X.-M.; Jiao, H. Tube and Cage C60H60: A Comparison with C60F60.Org. Lett.2008,10, 2573-2576.
(96)Hao, Z.-M.; Zhang, X.-M. Phosphorescent Acentric Cuprous Halide Coordination Polymers for Nolinear Optical Materials.Cryst. Growth. & Des.2008,8, 2359-2363.
(97)Hao, Z.-M.; Fang, R.-Q.; Wu, H.-S.; Zhang, X.-M. Cu6S4 Cluster Based Twelve-Connected Face-Centered Cubic and Cu19I4S12 Cluster Based Fourteen-Connected Body-Centered Cubic Topological Coordination Polymers.Inorganic Chemistry2008,47, 8197-8203.
(98)Zhang, X.-M.; Zheng, Y.-Z.; Li, C.-R.; Zhang, W.-X.; Chen, X.-M. Unprecedented (3,9)-Connected (42.6)3(46.621.89) Net Constructed by Trinuclear Mixed-Valence Cobalt Clusters.Cryst. Growth. & Des.2007,7, 980-983.
(99)Zhang, X.-M.; Hao, Z.-M.; Zhang, W.-X.; Chen, X.-M. Dehydration-Induced Conversion from a Single-Chain Magnet into a Metamagnet in a Homometallic Nanoporous Metal–Organic Framework.Angew. Chem. Int. Ed.2007,46, 3456-3459.
(100)Zhang, X. M.; Zhao, Y. F.; Zhang, X. W.; Chen, X. M. A Tetrazolate- and Cyano-Bridged Homometallic Mixed-Valence Copper(I,II) Molecular Ferrimagnet.Adv. Mater.2007,19, 2843-2846.
(101)Zhang, F.-Q.; Zhang, X.-M.; Wu, H.-S.; Li, Y.-W.; Jiao, H. Inversed Stability Order in Keggin Polyoxothiometalate Isomers: A DFT Study of 12-Electron Reduced α, β, γ, δ, and ε [(MoO4)Mo12O12S12(OH)12]2- Anions.J. Phys. Chem. A2007,111, 1683-1687.
(102)Zhang, F.-Q.; Zhang, X.-M.; Wu, H.-S.; Jiao, H. Structural and Electronic Properties of Hetero-Transition-Metal Keggin Anions: A DFT Study of α/β-[XW12O40]n- (X = CrVI, VV, TiIV, FeIII, CoIII, NiIII, CoII, and ZnII) Relative Stability.J. Phys. Chem. A2007,111, 159-166.
(103)Jiang, T.; Zhao, Y.-F.; Zhang, X.-M. Blue-green photoluminescent 5- and 10-connected metal 5-(4'-carboxy-phenyl)tetrazolate coordination polymers.Inorg. Chem.y Commun.2007,10, 1194-1197.
(104)Hou, J.-J.; Hao, Z.-M.; Zhang, X.-M. Double salts of copper(I) chloride incorporated hydroxylpyrimidine and tetrazole ligands.Inorg. Chim. Acta2007,360, 14-20.
(105)Hao, Z.-M.; Zhang, X.-M. Ligand Concentration Controlled Supramolecular Isomerism in Two CuSCN Based Coordination Polymers with in Situ Synthesized 4,4‘-Dipyridylsulfide as a Co-Ligand.Cryst. Growth. & Des.2007,7, 64-68.
(106)Zhang, X.-M.; Zhao, Y.-F.; Wu, H.-S.; Batten, S. R.; Weng Ng, S. Syntheses and structures of metal tetrazole coordination polymers.Dalton Trans.2006, 3170-3178.
(107)Zhang, X.-M.; Hou, J.-J.; Zhang, W.-X.; Chen, X.-M. Two Mixed-Valence Vanadium(III,IV) Phosphonoacetates with 16-Ring Channels: H2(DABCO)[VIVO(H2O)VIII(OH)(O3PCH2CO2)2]·2.5H2O and H2(PIP)[VIVO(H2O)VIII(OH)(O3PCH2CO2)2]·2.5H2O.Inorganic Chemistry2006,45, 8120-8125.
(108)Hou, J.-J.; Zhang, X.-M. Structures and Magnetic Properties of a Series of Metal Phosphonoacetates Synthesized from in Situ Hydrolysis of Triethyl Phosphonoacetate.Cryst. Growth. & Des.2006,6, 1445-1452.
(109)Hou, J.-J.; Guo, C.-H.; Zhang, X.-M. In situ alkylation of 4,4'-bipyridine in hydrothermal synthesis of one-dimensional copper(I) bromide compounds.Inorg. Chim. Acta2006,359, 3991-3995.
(110)Hao, Z.-M.; Zhang, X.-M. One-dimensional cobalt and zinc complexes involving in situ reaction of ethylenediamine and acetonitrile to form imidazoline ligand.Inorg. Chem.y Commun.2006,9, 57-59.
(111)Fang, R.-Q.; Zhao, Y.-F.; Zhang, X.-M. Syntheses and structures of two copper-molybdate complexes: The 3-D [Cu(4,4'-bpy)(MoO4)] and 1-D [Cu2(HDABCO)2(H2Mo8O27)] · 4H2O.Inorg. Chim. Acta2006,359, 2023-2028.
(112)Fang, R.-Q.; Zhang, X.-M. Diversity of Coordination Architecture of Metal 4,5-Dicarboxyimidazole.Inorganic Chemistry2006,45, 4801-4810.
(113)Fang, R.-Q.; Zhang, X.-H.; Zhang, X.-M. A NaCl-like Metal−Organic Framework Constructed by Unprecedented Tetrahedral Cd4O6 and Cd5O6 Units.Cryst. Growth. & Des.2006,6, 2637-2639.
(114)Zhang, X.-M.; Hao, Z.-M.; Wu, H.-S. Cuprophilicity-Induced Cocrystallization of [Cu2(4,4‘-bpy)(CN)2]n Sheets and [Cu(SCN)]n Chains into a 3-D Pseudopolyrotaxane.Inorganic Chemistry2005,44, 7301-7303.
(115)Zhang, X.-M.; Fang, R.-Q.; Wu, H.-S. New double-layered open metal-organic frameworks with nanosized channels encapsulated removable 2,5-bis(4-pyridyl)-1,3,4-thiadiazole molecules.CrystEngComm2005,7, 96-101.
(116)Zhang, X.-M.; Fang, R.-Q.; Wu, H.-S. A Twelve-Connected Cu6S4 Cluster-Based Coordination Polymer.J. Am. Chem. Soc.2005,127, 7670-7671.
(117)Zhang, X.-M.; Fang, R.-Q.; Wu, H.-S. Extended Water Tapes of Cyclic Hexamers Encapsulated in the Channels of a Metal Phosphonocarboxylate Network.Cryst. Growth. & Des.2005,5, 1335-1337.
(118)Zhang, X.-M.; Fang, R.-Q. Hydrothermal Syntheses and Structures of Two Mixed-Valence Copper(I,II) 2-Pyrazinecarboxylate Coordination Polymers.Inorganic Chemistry2005,44, 3955-3959.
(119)Zhang, X.-M. Hydro(solvo)thermal in situ ligand syntheses.Coordin. Chem. Rev.2005,249, 1201-1219.
(120)Zhang, X.-M. Syntheses, structures and properties of three metal pyridinecarboxylates.Inorg. Chim. Acta2005,358, 1865-1872.
(121)Zhang, X.-M.; Wu, H.-S.; Zhang, F.-Q.; Prikhod'ko, A.; Kuwata, S.; Comba, P. The three-electron heteropoly blue [P6Mo18O73]11- with a basket-shaped skeleton.Chem. Commun.2004, 2046-2047.
(122)Zhang, X.-M.; Hou, J.-J.; Wu, H.-S. In situ formation of meso-2,2[prime or minute]-oxydisuccinate via intermolecular dehydration coupling of d,l-malic acid: first coordination polymer of 2,2[prime or minute]-oxydisuccinate involving ether oxygen coordination: [Cd2(meso-odsc)(H2O)].Dalton Trans.2004, 3437-3439.
(123)Zhang, X.-M.; Chen, J.-S.; Xu, K.-Y.; Ding, C.-R.; She, W.-L.; Chen, X.-M. Syntheses, structures and properties of three cluster-based coordination polymers: influence of the metal ions on the ligand coordination mode and crystal chirality.Inorg. Chim. Acta2004,357, 1389-1396.
(124)Zhang, X.-M. A Microporous Zinc Phosphonocarboxylate with a Zeolite ABW Framework via the Trialkyl Phosphonocarboxylate Route: In situ Synthesis and Characterization of Na[Zn(O3PC2H4CO2)]·H2O.Eur. J. Inorg. Chem.2004,2004, 544-548.
(125)Zhu, H.-L.; Zhang, X.-M.; Liu, X.-Y.; Wang, X.-J.; Liu, G.-F.; Usman, A.; Fun, H.-K. Clear Ag-Ag bonds in three silver(I) carboxylate complexes with high cytotoxicity properties.Inorg. Chem.y Commun.2003,6, 1113-1116.
(126)Zhang, X.-M.; Wu, H.-S.; Chen, X.-M. Linear and Helical Chains in Hydrothermally Synthesized Coordination Polymers [Co(bpdc)(H2O)2] and [Ni(bpdc)(H2O)3]·H2O Involving in situ Ligand Synthesis.Eur. J. Inorg. Chem.2003,2003, 2959-2964.
(127)Zhang, X.-M.; Tong, M.-L.; Gong, M.-L.; Chen, X.-M. Supramolecular Organisation of Polymeric Coordination Chains into a Three-Dimensional Network with Nanosized Channels that Clathrate Large Organic Molecules.Eur. J. Inorg. Chem.2003,2003, 138-142.
(128)Zhang, X.-M.; Chen, X.-M. A New Porous 3-D Framework Constructed From Fivefold Parallel Interpenetration of 2-D (6,3) Nets: A Mixed-Valence Copper(I,II) Coordination Polymer [CuI2CuII(4,4′-bpy)2(pydc)2]·4H2O.Eur. J. Inorg. Chem.2003,2003, 413-417.
(129)Zhang, X.-M.; Chen, X.-M. Cover Picture.Eur. J. Inorg. Chem.2003,2003, 383-383.
(130)Zhang, X.-M.; Chen, X.-M. Three-dimensional supramolecular arrays supported by decavanadate clusters: syntheses and crystal structures of (NH4)2[M(dod)(H2O)4]2V10O28·6H2O, (M=Zn, Mn).Inorg. Chem.y Commun.2003,6, 206-209.
(131)Zhang, L.-Y.; Liu, G.-F.; Zheng, S.-L.; Ye, B.-H.; Zhang, X.-M.; Chen, X.-M. Helical Ribbons of Cadmium(II) and Zinc(II) Dicarboxylates with Bipyridyl-Like Chelates − Syntheses, Crystal Structures and Photoluminescence.Eur. J. Inorg. Chem.2003,2003, 2965-2971.
(132)Zhang, X.-M.; Tong, M.-L.; Gong, M.-L.; Lee, H.-K.; Luo, L.; Li, K.-F.; Tong, Y.-X.; Chen, X.-M. Syntheses, Crystal Structures, and Physical Properties of Dinuclear Copper(I) and Tetranuclear Mixed-Valence Copper(I,II) Complexes with Hydroxylated Bipyridyl-Like Ligands.Chem. Eur. J.2002,8, 3187-3194.
(133)Zhang, X.-M.; Tong, M.-L.; Chen, X.-M. Hydroxylation of N-Heterocycle Ligands Observed in Two Unusual Mixed-Valence CuI/CuII Complexes.Angew. Chem. Int. Ed.2002,41, 1029-1031.
(134)Zhang, X.-M.; Tong, M.-L.; Feng, S.-H.; Chen, X.-M. The unique dual role of zinc atoms in a mixed zinc-vanadium phosphate [Zn(phen)Zn(VO)(PO4)2].J. Chem. Soc., Daton Trans.2001, 2069-2070.
(135)Zhang, X. M.; Tong, M. L.; Lee, H. K.; Chen, X. M. The first noncluster vanadium(IV) coordination polymers: Solvothermal syntheses, crystal structure, and ion exchange.Journal of Solid State Chemistry2001,160, 118-122.
(136)Tao, J.; Zhang, X.-M.; Tong, M.-L.; Chen, X.-M. A novel polycatenated double-layered hybrid organic-inorganic material constructed from [Zn2(tp)(4,4[prime or minute]-bpy)]2 layers and V4O124- pillars.J. Chem. Soc., Daton Trans.2001, 770-771.
(137)Zhang, X.-M.; Tong, M.-L.; Chen, X.-M. Hydrothermal synthesis and crystal structures of two bimetallic chain-like and cluster complexes [{Co(phen)2}2V6O17] and [{Cu(phen)2}4V10O29][middle dot]6H2O.Chem. Commun.2000, 1817-1818.

hecongqu

Nature Communications：缺陷富集的氟化铁 - 氧化物纳米多孔薄膜双功能催化剂用于水分解

电催化剂中的缺陷强烈影响其化学性质和电子结构，并且可以显着提高电催化性能。 然而，在碱性介质中具有高效和稳定的水电解活性的缺陷激活的电催化剂的发展仍然是一个挑战，并且对催化起源的理解仍然有限。近日，山西大学的张献明教授和范修军报道一种缺陷富集双功能电催化剂，即三维氟化氧化物纳米多孔膜，通过阳极氧化/氟化过程制造。 具有高电导率的异质薄膜在晶格中具有嵌入的无序相，并且包含许多分散的缺陷，包括界面边界，堆垛层错，氧空位以及表面/界面上的位错。 异构催化剂有效地催化碱性电解质中的水分解，具有显着的稳定性。 实验研究和第一性原理计算表明，表面/边缘缺陷对其高性能有重大贡献。

文献链接：Defect-enriched iron fluoride-oxide nanoporous thin films bifunctional catalyst for water splitting(Nat. Commun.2018,DOI：10.1038/s41467-018-04248-y)

maichun

2018自然科学基金项目-超四面体金属硫氧簇基开放框架的合成及重金属和放射性金属的选择性离子交换
批准号        21871167        学科分类        固体表面与界面化学 ( B010503 )
负责人        张献明        职称                单位名称        山西师范大学
资助金额        66万元        项目类别        面上项目        起止年月        2019年01月01日 至 2022年12月31日

xiangshanxing

晶态材料研究所在电催化水裂解纳米材料的研究方面取得重要进展，相关工作以“(003)-Facet-Exposed Ni3S2 Nanoporous Thin Films on Nickel Foil for Efficient Water Splitting”为题发表在国际化学类重要学术期刊 Appl.   Catal. B Environ. 上，该期刊为催化领域顶级期刊，影响因子为11.698。张献明教授和范修军教授是本文通讯作者，博士生董静是本文第一作者。

Ni3S2(003) 晶面上HER和OER的反应机理示意图

可再生电催化裂解水被认为是一种利用丰富的水资源生产清洁氢能的能源转换技术。裂解水中析氢半反应(HER) 和析氧半反应 (OER) 缓慢的动力学过程是限制电解水大规模应用的重要瓶颈。因此，开发高效低成本的双功能电催化剂是该领域的研究重点。

活性晶面的选择性暴露和纳米结构的优化是制备高性能催化剂的有效且富有挑战的技术手段。本工作利用电化学阳极氧化和气相沉积的方法，在镍片上构筑了 (003) 晶面暴露的Ni3S2纳米多孔薄膜。通过调控材料的结晶纯度和微观形貌，合成了具有超小孔道、亲水疏气表面、较强晶面择优取向的催化剂。由该双功能材料组装的碱性电解池，在1.61 V电压下可获得10 mA/cm2的电流密度。Ni3S2纳米薄膜原位垂直生长于镍箔基底上，形成具有大量活性位点的纳米多孔结构。Ni3S2纳米薄膜良好的导电性和多孔结构为电化学反应中的电子和离子提供了短的传输路径。该一体化电极结构具有良好的循环稳定性，可直接应用于电解水催化反应而不需要粘结剂。实验结果和第一性原理 (DFT) 计算共同揭示了Ni3S2(003) 晶面在电解水过程中的催化机理。Ni3S2(003) 晶面上配位不饱和的镍三角结构可以有效降低HER过程中水裂解的活化能，Ni3S2和表面原位产生的NiOOH对OER起协同催化作用。该工作对开发和研究一体化过渡金属基纳米材料在能源转换与存储中的应用提供了有效思路。

本工作得到国家自然科学基金委、山西省“1331工程”、三晋学者、山西省研究生创新项目的经费支持。

（文章链接：https://doi.org/10.1016/j.apcatb.2018.11.003）