辽宁大学化学院郭放

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郭放，英国卡迪夫大学博士、博士后。辽宁大学研究员，博士生导师。辽宁省百千万人才工程百人层次、辽宁大学辽河学者，第二梯队学术带头人，辽宁省高等学校优秀青年学者。

    研究方向为固态超分子化学及其晶体工程，主要包括超分子及其药物分子的晶体生长、同质多晶、结构与性能关系研究；“二次球”配位超分子化学；超分子化学的固态合成；有机化合物的粉末衍射结构测定。

近年来先后承担国家自然科学基金3项（2项面上，1项青年），辽宁省优秀人才青年学者资助计划、教育部回国留学人员基金等项目的研究工作。在J. Am. Chem. Soc.、Chem. Commun.、Cryst. Growth & Des.、J. Phys. Chem. C、Dolton.Trans.、Inorg. Chem.、CrystEngComm等国际期刊发表SCI论文60余篇，其中影响因子大于4.0的国际化学权威期刊20余篇。国内授权发明专利2项。曾荣获辽宁大学振兴奖，辽宁省自然科学学术成果奖多项。

主要论著（第一作者或者通讯作者）

1.        Exploitingpolymorphism in second sphere coordination: thermal transformation, NLOproperties and  selective mechanochemical synthesis, CrystEngComm, 2016,18, 2408–2412.

2.        Crystalengineering of a hybrid metal–organic host framework and itssingle-crystal-to-single-crystal guest exchange using second spherecoordination, CrystEngComm, 2016, 18, 2284–2288.

3.        High-EfficiencyDeep-Red Quantum-Dot Light-Emitting Diodes with Type-II CdSe/CdTe Core/ShellQuantum Dots as Emissive Layers, J. Mater. Chem. C, 2016, 4,7223-7229.

4.        SecondSphere Coordination of Hybrid Metal-Organic Materials: Solid StateReactivity, Dalton Trans., 2016, 45, 13648-13662. (Perspective)

5.        Insights into the formation of chiral secondsphere coordination complexes with aromatic tris amines: combined single   crystal X-ray crystallography and molecular modeling analyses, Dalton Trans., 2015, 44, 15960–15965.

6.        Tuningthe Inclusion Properties and Solid-State Reactivity of Second Sphere AdductsUsing Conformationally Flexible Bidentate Ligands, Cryst. GrowthDes., 2015, 15, 2842-2852.

7.        Cadmium-freequantum dots based violet light-emitting diodes: High-efficiency and brightnessvia optimization of organic hole transport layers, Org. Electronics, 2015,25: 178-183.

8.  Cyclic Interconversion amongMolecular Salts via Neat Grinding and Related PhotoluminescenceProperties, Cryst. Growth Des., 2014, 14, 6528−6536.

9.  A second sphere coordinationadduct containing one-dimensional water/methanol channels: X-ray structures,thermal stability and single crystal impedance spectroscopy analysis, CrystEngComm, 2014,16, 10888–10892.

10.  Synthesis of Chelating Complexesthrough Solid-State Dehydrochlorination Reactions viaSecond-Sphere-Coordination Interaction with Metal Chlorides: A CombinedExperimental−Molecular Modeling Study,Inorg. Chem. , 2014,53, 7438−7445.

11.  Mechanochemicaldehydrochlorination and chelation reaction in the solid state: from a molecularsalt to a coordination complex, CrystEngComm, 2014, 16,969-973.

12.  Solid statetransformations in stoichiometric hydrogen bonded molecular salts: ionicinterconversion and dehydration processes, CrystEngComm, 2013, 15,6237-6243.

13.  Polymorphism andphotoluminescence in a naphthalene-based ligand, and its supramolecular structuresthrough second-sphere coordination with the [CoCl4]2- anion, RSCAdv., 2013, 3, 11594.

14.  Co-crystal of [CuCl4]2- and L1and its inclusion compounds with three different guests (L1 = N, N, N′, N′ -tetra-p-methoxybenzyl – ethylenediamine), CrystEngComm, 2011, 13,6753-6758.

15.  Supramolecular inclusion of apillared double-layered host by anion-directed second-spherecoordination, Supramol. Chem., 2010, 22, 9, 548-553.

16.  Direct structural understandingof a topochemical solid state photopolymerization reaction, J. Phys.Chem. C, 2008, 112, 19793-11796.

17.  On the spontaneous induction ofchirality in the preparation of Werner’s complex cis-[CoBr(NH3) (en)2]Br2, Chem. Commun., 2006, 1854-1856.

18.  Abundant polymorphism in a systemwith multiple hydrogen-Bonding opportunities: oxalyl Dihydrazide, J.Am. Chem. Soc., 2006, 128, 8441-8452.

19.  Contrasting solid-Statestructures of trithiocyanuric acid and cyanuric acid, Cryst. Growth& Des., 2006, 6, 846-848.

20.  Structural understanding of amolecular material that is accessed only by a solid-State desolvation process:The Scope of Modern Powder X-ray Diffraction Techniques, J. Am. Chem.Soc., 2005, 127, 7314-7315.

专利

1.一种采用超分子二次球形配位识别分离富集钯的方法, ZL 2009 1 0010882.9,

2.包结结晶法提取蛇床子中甲氧基欧芹素和欧前胡素的方法，ZL 2011 1 0329004.0