清华大学化学系王训

chengchuan

王训教授，国家杰出青年科学基金获得者，教育部“长江学者”特聘教授，清华大学化学系系主任，有机光电子与分子工程教育部重点实验室主任。94-01年就读于西北大学，获本科、硕士学位；04年获清华大学博士学位。04-07年任清华大学化学系助理研究员、副教授，07年起任清华大学教授。主要从事无机纳米材料化学研究，在无机纳米晶体新结构控制合成、形成机制及组装领域取得了一些进展。共发表SCI论文200余篇。兼任《化学学报》编委、《中国科学：化学》编委，Editorial board member of Advanced Materials，Editorial board member of Nano Research，Scientific Editor of Materials Horizon，Associate Editor of Science China Materials，Associate Editor of Science Bulletin，中国化学会副秘书长。曾获Hall of Fame ( Advanced Materials，2018)、国际溶剂热水热联合会ISHA Roy-Somiya Award ( 2018)、Fellow of the Royal Society of Chemistry (2015)、首届高等学校科学研究优秀成果奖(科学技术)青年科学奖(2015)、第八届“中国化学会-巴斯夫青年知识创新奖”、2009年第十一届中国青年科技奖、2009年“中国化学会-英国皇家化学会青年化学奖”、2005 IUPAC Prize for Young Chemists等奖励和荣誉。

王训 教授 博士生导师
Tel: 010-62792791
E-mail: wangxun@mail.tsinghua.edu.cn
讲授课程：无机化学、纳米化学、无机及分析化学试验
课题组主页：http://thuwangxungroup.com/
教育背景
1994.09－1998.07，西北大学化工系，学士
1998.09－2001.07，西北大学化工系，硕士
2001.09－2004.07，清华大学化学系，博士
工作履历
2004.08－2005.11，清华大学化学系，讲师
2005.12－2007.11，清华大学化学系，副教授
2007.12－至今，清华大学化学系，教授
学术兼职
中国化学会副秘书长（2014-）
中国化学会青年工作委员会副主任（2014-）
中国化学会纳米化学分会副秘书长（2013-）
中国材料研究学会纳米材料与器件分会副秘书长（2013-）
《科学通报》化学学科编委（2011-）
《化学学报》编委（2011-）
《中国科学 化学》青年编委会成员（2014-）
Editorial Board Member, Scientific Reports (Nature Publishing Group)（2013-）
Editorial Board Member, Nano Research（2014-）
Associate editor, Science China Materials（2014-）
研究领域
功能纳米材料控制合成、组装及性能研究
奖励与荣誉
2014年长江学者特聘教授
2014 IUMRS – MRS Singapore Young Researchers Award Nomination
中组部首批青年拔尖人才支持计划（2011年）
第六批“北京市优秀青年知识分子”（2010年）
北京市青年联合会第十届委员会委员（2010- ）
2009年第十一届中国青年科技奖
2009年第二届“中国化学会-英国皇家化学会青年化学奖”
2008年国家自然科学奖二等奖（第二获奖人）
2007年国家杰出青年基金
2007年霍英东青年教师基金
2006年全国优秀博士学位论文
2006年教育部新世纪优秀人才支持计划
2006年清华大学学术新人奖
2006年中国化学会青年化学奖
2005年度首届“中国化学会－约翰威立出版公司青年化学论文奖”
2005年度国际纯粹及应用化学联合会青年化学家奖（2005 IUPAC Prize for Young Chemists）

学术成果
主要代表性论文：
1． Huiling Liu, Farhat Nosheen, Xun Wang*. Noble Metal Alloy Complex Nanostructures: Controlled Synthesis and Their Electrochemical Properties. Chem. Soc. Rev. 2015, accepted.
2． Biao Xu, Gang Zhou*, Xun Wang*. Rational Synthesis and Structure-Property Relationship of Nanoheterostrucutures: Combinative Study from Both Experiments and Theories. NPG Asia Mater. 2015, accepted.
3． Faisal Saleem, Biao Xu, Bing Ni, Huiling Liu, Farhat Nosheen, Haoyi Li, Xun Wang*. Atomically-Thick Pt-Cu Nanosheets: Self Assembled Sandwich and Nanoring Structures. Adv. Mater. 2015, DOI: 10.1002/adma.201405319.
4． Jie He, Huiling Liu, Biao Xu, Xun Wang*. Highly Flexible Sub-1nm Tungsten Oxide Nanobelts as Efficient Desulfurization Catalysts. Small 2014, smll.201401273.
5． Shi Hu, Haoyi Li, Huiling Liu, Peilei He, Xun Wang*. Nanocrystals of Uranium Oxide: Controlled Synthesis and Enhanced Electrochemical Performance of Hydrogen Evolution by Ce-doping. Small 2015, accepted.
6． Yanyan Zhao, Hongyu Sun, Limin Liu, Ruilong Zong, Huaqiang Cao, Zhicheng Zhang, Xun Wang, Jun Luo*, Jing Zhu*. Space-Confined Creation of Nanoframes In Situ on Reduced Graphene Oxide. Small 2015, published online.
7． Farhat Nosheen, Zhi-cheng Zhang, Guo-lei Xiang, Biao Xu, Yong Yang, Faisal Saleem, Xiao-bin Xu, Jing-Chao Zhang, Xun Wang*. Three-Dimensional Hierarchical Pt-Cu Superstructures. Nano Res. 2015, published online.
8． Da-Bing Huang, Pei-Lei He, Qiang Yuan*, Xun Wang*. Size-controllable Synthesis of Trimetallic RhPdPt Island-shaped Nanoalloys as Effective Electrocatalysts for Ethanol Oxidation in Alkaline Medium. Chem. Asian J. 2015, published online.
9． Yong Yang, Jingchao Zhang, Shitong Wang，Xiaobin Xu, Zhicheng Zhang, Pengpeng Wang, Zilong Tang, Xun Wang*. Facile and Generalized Encapsulations of Inorganic Nanocrystals with Nitrogen-doped Carbonaceous Coatings for Multifunctionality. Nanoscale 2015, 7, 3254-3262.
2014 年
10． Zhicheng Zhang, Biao Xu, Xun Wang*. Engineering Nanointerfaces for Nanocatalysis. Chem. Soc. Rev. 2014, 43, 7870-7886.
11． Zhicheng Zhang, Yifeng Chen, Su He, Jingchao Zhang, Xiaobin Xu, Yong Yang, Farhat Nosheen, Faisal Saleem, Wei He, and Xun Wang*. Hierarchical Zn/Ni-MOF-2 Nanosheet-Assembled Hollow Nanocubes for Multicomponent Catalytic Reactions. Angew. Chem. Int. Ed. 2014, 53, 12517-12521.
12． Biao Xu, Peilei He, Huiling Liu, Pengpeng Wang, Gang Zhou, Xun Wang*. 1D-2D Helical CdS-ZnIn2S4 Hetero-nanostructure. Angew. Chem. Int. Ed. 2014, 53, 2339-2343.
13． Zhi-cheng Zhang, Xiao-bin Xu, Jing-chao Zhang, Guo-lei Xiang, Biao Xu, Pei-lei He, Farhat Nosheen, Faisal Saleem, Xun Wang*. Well-defined Metal-Organic Framework Hollow Nanocages. Angew. Chem. Int. Ed. 2014, 53, 429-433.
14． Peilei He, Biao Xu, Peng-peng Wang, Huiling Liu, Xun Wang*. A Monolayer Polyoxometalate Superlattice. Adv. Mater. 2014, 26, 4339-4344.
15． Jingchao Zhang, Yong Yang, Zhicheng Zhang, Pengpeng Wang, Xun Wang*. Biomimetic Multifunctional Nanochannels based on the Asymmetric Wettability of Heterogeneous Nanowire Membrane. Adv. Mater. 2014, 26, 1071-1075.
16． Peng-peng Wang, Hongyu Sun, Yongjun Ji, Wenhai Li, Xun Wang*. Three-Dimensional Assembly of Single-Layered MoS2. Adv. Mater. 2014, 26, 964-969.
17． Biao Xu, Hao Yang, Gang Zhou, Xun Wang*. Strong Metal-Support Interactions in Size-Controlled Monodisperse Palladium-Hematite Nano- Heterostructures during a Liquid-Solid Heterogeneous Catalysis. Sci. China Mater. 2014, 57, 34-41.
18． Kai Wang, Zhicheng Zhang, Xun Wang*, Yadong Li. Inorganic nanocrystals: from molecular design to systematic engineering. Particuology 2014, 17, 1-10. (invited review)
19． Jingchao Zhang, Yong Yang, Zhicheng Zhang, Xiaobin Xu, Xun Wang*. Hierarchical Mesoporous Hollow NixCo3-x(PO4)2 Shells Showing Enhanced Electrocatalytic and Surpercapacitor Performances. J. Mater. Chem. A 2014, 2, 20182.
20． Junfeng Hui, Xun Wang*. Hydroxyapatite nanocrystals: colloidal chemistry, assembly and their biological applications. Inorg. Chem. Front. 2014, 1, 215-225. (invited review)
21． Guolei Xiang, Yong Long, Jie He, Biao Xu, Haitao Liu*, Xun Wang*. Unusual Enrichment and Assembly of TiO2 Nanocrystals at Water/Hydrophobic Interfaces in a Pure Inorganic Phase. Langmuir 2014, 30, 617-623.
22． Li Luo, Peng-peng Wang, Dengwei Jing*, Xun Wang*. Self-assembly of TiO2 Nanoparticles into Chains, Films and Honeycomb Networks. CrystEngCommun 2014, 16, 1584-1591. (themed issue of Nanocrystal Growth via Oriented Attachment)
2013 年
23． Shi Hu, Xun Wang*. Ultrathin Nanostructures: Smaller Size with New Phenomena. Chem. Soc. Rev. 2013, 42, 5577-5594.
24． Faisal Saleem, Zhicheng Zhang, Biao Xu, Xiaobin Xu, Peilei He, Xun Wang*. Ultrathin Pt-Cu Nanosheets and Nanocones. J. Am. Chem. Soc. 2013, 135, 18304-18307.
25． Shi Hu, Huiling Liu, Pengpeng Wang, Xun Wang*. Inorganic Nanostructure with Sizes Down to 1nm: a Macromolecule Analogue. J. Am. Chem. Soc. 2013, 135, 11115-11124.
26． Peng-peng Wang, Yong Yang, Jing Zhuang, Xun Wang*. Self-Adjustable Crystalline Inorganic Nanocoils. J. Am. Chem. Soc. 2013, 135, 6834-6837.
27． Peilei He, Biao Xu, Huiling Liu, Su He, Faisal Saleem, Xun Wang*. Polyoxometalate-based Supramolecular Gel. Scientific Reports 2013, 3, 1833; DOI:10.1038/srep01833.
28． Yong Yang, Peng-peng Wang, Zhi-cheng Zhang, Hui-ling Liu, Jingchao Zhang, Jing Zhuang, Xun Wang*. Nanowire Membrane-based Nanothermite: towards Processable and Tunable Interfacial Diffusion for Solid State Reactions. Scientific Reports 2013, 3, 1694; DOI:10.1038/srep01694.
29． Guolei Xiang, Yang-Gang Wang, Jun Li*, Jing Zhuang, Xun Wang*. Surface-Specific Interaction by Structure-Match Confined Pure High-Energy Facet of Unstable TiO2(B) Polymorph. Scientific Reports 2013, 3, 1411; DOI:10.1038/srep01411.
30． Zhicheng Zhang, Farhat Nosheen, Jingchao Zhang, Yong Yang, Pengpeng Wang, Jing Zhuang, Xun Wang*. An in-situ Facet-Selective Etching Growth Route towards Concave Polyhedral Pd Nanocrystals with 32 Facets. ChemSusChem 2013, 6, 1893-1897.
31． Zhicheng Zhang, Yong Yang, Farhat Nosheen, Pengpeng Wang, Jingchao Zhang, Jing Zhuang, and Xun Wang*. Fine Tuning of the Structure of Pt−Cu Alloy Nanocrystals by Glycine-Mediated Sequential Reduction Kinetics. Small 2013, 9, 3063-3069.
32． Biao Xu, Zhicheng Zhang, Xun Wang*. Formamide: An Efficient Solvent to Synthesize Water-Soluble, Sub-10-Nanometer Nanocrystals. Nanoscale 2013, 5, 4495-4505.
33． Farhat Nosheen, Zhi-cheng Zhang, Jing Zhuang, Xun Wang*. One-Pot Fabrication of Single-Crystalline Octahedral Pt−Cu Nanoframes and Their Enhanced Electrocatalytic Activity. Nanoscale 2013, 5, 3660-3663.
34． Yong Yang, Zhi-cheng Zhang, Peng-peng Wang, Jing-chao Zhang, Farhat Nosheen, Jing Zhuang, Xun Wang*. Hierarchical MnO2/SnO2 heterostructures for a novel free-standing ternary thermite membrane. Inorg. Chem. 2013, 92, 9449-9455.
35． Long Sun, Peilei He, Biao Xu, Xiaobin Xu and Xun Wang*. Promoting the catalytic efficiency of catalyst by hydrothermal method. RSC Adv. 2013, 3, 5819-5823.
36． Long Sun, Zhicheng Zhang, Biao Xu, Xun Wang*. One-pot Template-free Synthesis of Pd-Pt Single-Crystalline Hollow Cubes with Enhanced Catalytic Activity. Chem. Aisan J. 2013, 8, 1523-1529.
2012 年
37． Guolei Xiang, Xuejun Shi, Yulong Wu*, Jing Zhuang, Xun Wang*. Size effects in Atomic-Level Epitaxial Redistribution Process of RuO2 over TiO2. Scientific Reports 2012, 2, 801; DOI:10.1038/srep00801.
38． Yong Long, Jun-feng Hui, Peng-peng Wang, Guo-lei Xiang, Biao Xu, Shi Hu, Wan-cheng Zhu, Jing Zhuang, Xun Wang*. Hydrogen Bond Nanoscale Networks Showing Switchable Transport Performance. Scientific Reports 2012, 2, 612; DOI:10.1038/srep00612.
39． Qingquan Huang, Shi Hu, Jing Zhuang, Xun Wang*. MoO3-x-based Hybrids with Tunable Localized Surface Plasmon Resonances: Chemical Oxidation Driving Transformation from Ultrathin Nanosheets to Nanotubes. Chem. Eur. J. 2012, 18, 15283-15287.
40． Junfeng Hui, Qiyu Yu, Yong Long, Zhicheng Zhang, Yong Yang, Pengpeng Wang, Biao Xu, Xun Wang* Ca-PO4-CO3 solid solution ultrathin nanowires: controllable synthesis and their full color emission by rare earth doping. Chem. Eur. J. 2012, 18, 13702-13711.
41． Guolei Xiang, Yang-Gang Wang, Di Wu, Tianyang Li, Jie He, Jun Li, Xun Wang*. Size-Promoted Surface Activities of Rutile and Anatase TiO2 Nanocrystals: Enhanced Surface Modification and Photocatalytic Performance. Chem. Eur. J. 2012, 18, 4759-4765.
42． Zhi-Cheng Zhang, Xin Zhang*, Qi-Yu Yu, Zhi-Chang Liu, Chun-Ming Xu, Jin-Sen Gao, Jing Zhuang, Xun Wang*. Pd Cluster Nanowires as Efficient Catalysts for Selective Hydrogenation Reactions. Chem. Eur. J. 2012, 18, 2639-2645.
43． Junfeng Hui, Xiaoyong Zhang, Zhicheng Zhang, ShiQi Wang, Lei Tao, Yen Wei*, Xun Wang*. Fluoridated HAp:Ln3+ (Ln=Eu or Tb) NPs for cell-imaging. Nanoscale 2012, 4, 6967-6970.
44． Qiyu Yu, Junfeng Hui, Pengpeng Wang, Biao Xu, Jing Zhuang, Xun Wang*. Hydrothermal Synthesis of Mesoporous Silica Spheres: Insights into the Thermally Decoupled Dissolution and Regrowth of Silica. Nanoscale 2012, 4, 7114-7120.
45． Zhi-Cheng Zhang, Jun-feng Hui, Zhen-Guo Guo, Qi-Yu Yu, Biao-Xu, Xin Zhang*, Zhi-Chang Liu, Chun-Ming Xu, Jin-Sen Gao, Xun Wang*. Hydrothermal Synthesis of Pt-Pd Alloys with Selective Shapes and Their Enhanced Electrocatalytic Activities. Nanoscale 2012, 4, 2633-2639.
46． Biao Xu, Ruji Wang, Xun Wang*. Simplifying the Growth of Hybrid Single Crystals by Using Nanoparticle Precursors: the Case of AgI. Nanoscale 2012, 4, 2713-2719.
47． Zhi-cheng Zhang, Jun-feng Hui, Zhi-Chang Liu*, Xin Zhang*, Jing Zhuang, Xun Wang*. Glycine-mediated syntheses of Pt concave nanocubes with high-index {hk0} facets and their enhanced electrocatalytic activities. Langmuir 2012, 28, 14845-14848.
48． Li Luo, Junfeng Hui, Qiyu Yu, Zhicheng Zhang, Dengwei Jing*, Pengpeng Wang, Yong Yang, Xun Wang*. Crystal growth by leaps and bounds based on self-assembly: Insight from titania. CrystEngCommun. 2012, 14, 7648-7655.
49． Qiyu Yu, Junfeng Hui, Peng-peng Wang, Xun Wang*. Anion-Exchange-Driven Disassembly of SiO2/CTAB Composite Mesophase: the Formation of Hollow Mesoporous Silica Spheres. Inorg. Chem. 2012, 51, 9539-9543.
50． Wancheng Zhu, Yan Yang, Shi Hu, Guolei Xiang, Biao Xu, Jing Zhuang, Xun Wang*. (Ni,Mg)3Si2O5(OH)4 Solid-Solution Nanotubes Supported Sub-0.06 wt% Pd for Suzuki-Miyaura Cross-Coupling Reactions. Inorg. Chem. 2012, 51, 6020-6031.
51． Shi Hu, Xun Wang*. From Cluster Assembly to Ultrathin Nanocrystals and Complex Nanostructures. Science China: Chemistry 2012, 55, 2257-2271. (invited review)
52． Amjad Nisar, Xun Wang*. Surfactant-Encapsulated Polyoxometalate Building Blocks: Controlled Assembly and their Catalytic Properties. Dalton Trans. 2012, 41, 9832 - 9845.
53． Biao Xu, Xun Wang*. Solvothermal Synthesis of Monodisperse Nanocrystals. Dalton Trans. 2012, 41, 4719-4725.
54． Yong Long, Jun-feng Hui, Peng-peng Wang, Shi Hu, Biao Xu, Guo-lei Xiang, Jing Zhuang, Xing-Qiang Lü*, Xun Wang*. α-MnO2 nanowires as building blocks for the construction of 3-D macro-assemblies. Chem. Commun. 2012, 48, 5925-5927.
55． Peng-peng Wang, Qiyu Yu, Yong Long, Shi Hu, Jing Zhuang, Xun Wang*. Multivalent assembly of small nanoparticles: 1D, 2D and 3D Architectures of 2 nm Gold Nanoparticles. Nano Res. 2012, 5, 283-291.
56． Lei Zhang, Gang Xie, Junfeng Hui, Biao Xu, Guolei Xiang, Xun Wang*. Shape control of Pd-based nanocrystals via quasi-solid-state reactions. RSC Adv. 2012, 2, 3204-3206.
2011 年
57． Amjad Nisar, Yao Lu, Jing Zhuang, and Xun Wang*. Polyoxometalate Nanocone Nanoreactors: Magnetic Manipulation and their Enhanced Catalytic Performances. Angew. Chem. Int. Ed. 2011, 50, 3187-3192.
58． Amjad Nisar, Jing Zhuang, Xun Wang*. Construction of Amphiphilic Polyoxometalate Mesostructures as Highly Efficient Desulfurization Catalyst. Adv. Mater. 2011, 23, 1130-1135.
59． 相国磊，王训*，纳米晶核的尺寸与表面对生长与组装过程影响的研究进展。无机化学学报，2011，27，2323-2331。(国际化学年邀请综述)
60． Junfeng Hui, Xun Wang*. Luminescent Colloidal F-Substituted Hydroxyapatite Nanocrystals. Chem. Eur. J. 2011, 17, 6926-6930.
61． Biao Xu, Xun Wang*. Thermally Stable AgI Quantum Dot-based Room Temperature Fast Ionic Conductors. Small 2011, 7, 3439-3444.
62． Yong Yang, Haixia Ma*, Jing Zhuang, Xun Wang*. Morphology-Controlled Synthesis of Hematite Nanocrystals and their Facet Effects on Gas-Sensing Properties. Inorg. Chem. 2011, 50, 10141-10151.
63． Guolei Xiang, Tianyang Li, Xun Wang*. Reactive facets covered mosaic spheres of anatase TiO2 and related pseudo isotropic effect. Inorg. Chem. 2011, 50, 6237-6242.
64． Yan Yang, Qingqin Liang, Jinghong Li*, Yuan Zhuang, Yunhua He, Bo Bai, Xun Wang*. Ni3Si2O5(OH)4 Multi-Walled Nanotubes with Tunable Magnetic Properties and Their Application as Anode Materials for Lithium Batteries. Nano Res. 2011, 4, 882-890.
65． Qiyu Yu, Pengpeng Wang, Shi Hu, Junfeng Hui, Jing Zhuang and Xun Wang*. Hydrothermal Synthesis of Hollow Silica Spheres under Acidic Conditions. Langmuir 2011, 27, 7185-7191.
66． Guolei Xiang, Di Wu, Jie He, Xun Wang*. Acquired pH-responsive and Reversible Enrichment of Organic Dyes by Peroxide Modified Ultrathin TiO2 Nanosheets. Chem. Commun. 2011, 47, 11456-11458.
67． Tianyang Li, Guolei Xiang, Jing Zhuang, Xun Wang*. Enhanced catalytic performance of assembled ceria necklace nanowires by Ni doping. Chem. Commun. 2011, 47, 6060-6062.
68． Guolei Xiang, Tianyang Li, Jie He, Jing Zhuang, Xun Wang*. Rapid Preparation of Noble Metal Nanocrystals via Facile Coreduction with Graphene Oxide and their Enhanced Catalytic Properties. Nanoscale 2011, 3, 3737-3742.
69． Peng-peng Wang, Bo Bai, Lujie Huang, Shi Hu, Jing Zhuang, Xun Wang*. General Synthesis and Characterization of a family of Layered Lanthanide (Pr, Nd, Sm, Eu, and Gd) Hydroxides Nanowires？. Nanoscale 2011, 3, 2529-2535.
70． Shuling Shen, Jing Zhuang, Yan Yang, Xun Wang*. Highly Monodisperse Cu- and Ag-Based Bimetallic Nanocrystals for the Efficient Utilization of Noble Metals in Catalysis. Nanoscale 2011, 3, 272-279.
2010 年
71． Shi Hu, Xun Wang*. Fullerene-like Colloidal Nanocrystal of Nickel Hydroxychloride. J. Am. Chem. Soc. 2010, 132, 9573-9575.
72． Zhihong Tang, Shuling Shen, Jing Zhuang, Xun Wang*. Noble Metal-Promoted Three-Dimensional Macroassembly of Single-layered Graphene Oxide. Angew. Chem. Int. Ed. 2010, 49, 4603-4607.
73． Amjad Nisar, Yao Lu, Xun Wang*. Assembling Polyoxometalate Clusters into Advanced Nanoarchitectures. Chem. Mater. 2010, 22, 3511-3518.
74． Qiang Yuan, Zhiyou Zhou*, Jing Zhuang, Xun Wang*. Seed Displacement, Epitaxial Synthesis of Rh/Pt Bimetallic Ultrathin Nanowires for Highly Selective Oxidizing Ethanol to CO2. Chem. Mater. 2010, 22, 2395-2402.
75． Shi Hu, Xi Ling, Tian Lan, Xun Wang*. Cluster-Based Self Assembly Route toward MoO3 Single-Walled Nanotubes. Chem. Eur. J. 2010, 16, 1889-1896.
76． Shuling Shen, Zhihong Tang, Qing Liu and Xun Wang*. Precisely Controlled Growth of Hetero-structured Nanocrystals via Dissolution-Attachment Process. Inorg. Chem. 2010, 49, 7799-7807.
77． Qiang Yuan, Zhiyou Zhou*, Jing Zhuang, Xun Wang*. Tunable Aqueous Phase Synthesis and Shape-Dependent Electrochemical Properties of Rhodium Nanostructures. Inorg. Chem. 2010, 49, 5515-5521.
78． Shuling Shen, Xun Wang*. Controlled Growth of Inorganic Nanocrystals: Size and Surface Effects of Nuclei. Chem. Commun. 2010, 6891-6899.
79． Guolei Xiang, Tianyang Li, Jing Zhuang, Xun Wang*. Large-Scale Synthesis of Metastable TiO2(B) Nanosheets with Atomic Thickness and Their Photocatalytic Properties. Chem. Commun. 2010, 6801-6803.
80． Qiang Yuan, Zhiyou Zhou*, Jing Zhuang, Xun Wang*. Pd-Pt Random Alloy Nanocubes with Tunable Compositions and Their Enhanced Electrocatalytic Activities. Chem. Commun. 2010, 1491-1493.
81． Qiang Yuan, Xun Wang*. Aqueous-based Route toward Noble Metal Nanocrystals: Morphology-Controlled Synthesis and their Applications. Nanoscale 2010, 2, 2328-2335.
82． Yan Yang, Yuan Zhuang, Yunhua He, Bo Bai, Xun Wang*. Fine Tuning of the Dimensions of Zinc Silicate Nanostructures and Their Application as Highly Efficient Absorbents for Toxic Metal Ions. Nano Res. 2010, 3, 581-593.
83． Zhihong Tang, Jing Zhuang, Xun Wang*. Exfoliation of Graphene from Graphite and Their Self-Assemblies at Oil-Water Interface. Langmuir 2010, 26, 9045-9049.
2009 年
84． Peng-peng Wang, Bo Bai, Shi Hu, Jing Zhuang, Xun Wang*. Family of Multifunctional Layered-Lanthanum Crystalline Nanowires with Hierarchical Pores: Hydrothermal Synthesis and Applications. J. Am. Chem. Soc. 2009, 131, 16953-16960.
85． Amjad Nisar, Xiangxing Xu, Shuling Shen, Shi Hu and Xun Wang*. Noble Metal Nanocrystal-Incorporated Fullerene-like Polyoxometalate Based Microspheres. Adv. Func. Mater. 2009, 19, 860-865.
86． Xiangxing Xu, Xun Wang*. Fine Tuning of the Phases and Sizes of ZrO2 Nanocrystals. Nano Res. 2009, 2, 891-902.
87． Qiang Yuan, Jing Zhuang, Xun Wang*. Single-Phase Aqueous Approach toward Pd Sub-10nm Nanocubes and Pd-Pt Heterostructured Ultrathin Nanowires. Chem. Commun. 2009, 6613-6615.
88． Amjad Nisar, Jing Zhuang, Xun Wang*. Cluster-Based Self-Assembly: Reversible Formation of Polyoxometalate Nanocones and Nanotubes. Chem. Mater. 2009, 21, 3745-3751.
89． Guolei Xiang, Jing Zhuang, Xun Wang*. Morphology-Controlled Synthesis of Inorganic Nanocrystals via Surface Reconstruction of Nuclei. Inorg. Chem. 2009, 48, 10222-10230.
90． Junfeng Hui, Guolei Xiang, Xiangxing Xu, Jing Zhuang, Xun Wang*. Monodisperse F-Substituted Hydroxyapatite Single Crystal Nanotubes with Amphiphilic Surface Properties. Inorg. Chem. 2009, 48, 5614-5616.
91． Shuling Shen, Jing Zhuang, Xiangxing Xu, Amjad Nisar, Shi Hu and Xun Wang*. Size Effects in Oriented-Attachment Growth Process: The Case of Cu Nanoseeds. Inorg. Chem. 2009, 48, 5117-5128.
92． Xiangxing Xu, Xun Wang*. Size- and Surface-Determined Transformations: From Ultrathin InOOH Nanowires to Uniform c-In2O3 Nanocubes and rh-In2O3 Nanowires. Inorg. Chem. 2009, 48, 3890-3895.
93． Yuan Zhuang, Yan Yang, Guolei Xiang, Xun Wang*. Magnesium Silicate Hollow Nanostructures as Highly Efficient Absorbents for Toxic Metal Ions. J. Phys. Chem. C 2009, 113, 10441-10445.
94． Xiangxing Xu, Xun Wang*. Combinatorial Two-Dimensional Architectures from Nanocrystal Building Blocks: Controlled Assembly and Their Applications. J. Mater. Chem. 2009, 19, 3572-3575. (Highlight, Cover Picture)
2008 年
95． Xiangxing Xu, Jing Zhuang and Xun Wang*. SnO2 Quantum Dots and Quantum Wires: Controllable Synthesis, Self-assembled 2D Architectures and Their Gas Sensing Properties. J. Am. Chem. Soc. 2008, 130, 12527-12535.
96． Shi Hu, Xun Wang*. Single-Walled MoO3 Nanotubes. J. Am. Chem. Soc. 2008,130, 8126-8127.
97． Xin Liang, Xun Wang*, Yuan Zhuang, Biao Xu, Simin Kuang, Yadong Li*. Formation of CeO2-ZrO2 Solid Solution Nanocages with Controllable Structures via Kirkendall Effect. J. Am. Chem. Soc. 2008, 130, 2736-2737.
98． Xin Liang, Biao Xu, Simin Kuang, Xun Wang*, Multi-Functional Inorganic-Organic Hybrid Rare Earth Microcapsules. Adv. Mater. 2008, 20, 3739-3744.
99． Xiangxing Xu, Xun Wang*, Amjad Nisar, Xin Liang, Jing Zhuang, Shi Hu, Yuan Zhuang. Combinatorial Hierarchically-ordered 2-D Architectures self-assembled from Nanocrystal Building Blocks. Adv. Mater. 2008, 20, 3702-3708.
100． Xun Wang*, Jing Zhuang, Ziyang Huo, Shi Hu, Yadong Li. Covalence-like Interactions between Artificial Atoms inside Silver Supercrystals. Inorg. Chem. 2008, 47, 543-547.
2007 年及以前
101． Xun Wang, Qing Peng, Yadong Li*. Interface-mediated Growth of Monodisperse Nanostructures. Acc. Chem. Res. 2007, 40, 635-643. (Invited review)
102． Xin Liang, Xun Wang*, Jing Zhuang, Qing Peng, Yadong Li*. Synthesis of NaYF4 Nanocrystals with Predictable Phase and Shape. Adv. Func. Mater. 2007, 17, 2757-2765.
103． Xin Liang, Xun Wang*, Jing Zhuang, Qing Peng, Yadong Li*. Branched NaYF4 Nanocrystals with Luminescent Properties. Inorg. Chem. 2007. 46, 6050-6055.
104． Xun Wang, Yadong Li*. Monodisperse Nanocrystals: General Synthesis, Self Assembly, and Their Applications. Chem. Commun. 2007, 2901-2910. (Feature article)
105． Xun Wang*, Jing Zhuang, Qing Peng, Yadong Li*. Liquid-solid-solution Synthesis of Biomedical Hydroxyapatite Nanorods, Adv. Mater. 2006, 18, 2031-2034.
106． Xin Liang, Xun Wang*, Jing Zhuang, Yongtao Cheng, Dingsheng Wang, Yadong Li*. Synthesis of Nearly Monodisperse Iron Oxide and Oxyhydroxide Nanocrystals, Adv. Func. Mater. 2006, 16, 1805-1813.
107． Xun Wang*, Jing Zhuang, Qing Peng, Yadong Li*. Hydrothermal Synthesis of Rare-earth Fluoride Nanocrystals, Inorg. Chem. 2006, 45, 6661-6665.
108． Xun Wang, Yadong Li*. Solution-based Synthetic Strategies for 1-D Nanostructures. Inorg. Chem. 2006, 45, 7522-7534. (Forum article)
109． Xun Wang*, Jing Zhuang, Qing Peng, Yadong Li*. Synthesis and Characterization of Sulfide and Selenide Colloidal Semiconductor Nanocrystals. Langmuir 2006, 22, 7364-7368.
110． Xun Wang*, Yadong Li, Solution-based Routes to Transitional Metal Oxides One-dimensional Nanostructures, Pure Appl. Chem. 2006, 78, 45-64. (Invited review)
111． Xin Liang, Xun Wang*, Leyu Wang, Ruoxue Yan, Qing Peng, Yadong Li. Synthesis and Characterization of Ternary NH4Ln2F7 (Ln = Y, Ho, Er, Tm, Yb, Lu) Nanocages. Eur. J. Inorg. Chem. 2006, 2186-2191.
112． Xun Wang, Jing Zhuang, Qing Peng, Yadong Li*, A General Strategy for Nanocrystal Synthesis. Nature 2005, 437, 121-124.
113． Xun Wang, Jing Zhuang, Jun Chen, Kebin Zhou, Yadong Li*. Thermally Stable Silicate Nanotubes. Angew. Chem. Int. Ed. 2004, 43, 2017-2020.
114． Xun Wang, Yadong Li*, Fullerene-like Rare Earth Nanoparticles. Angew. Chem. Int. Ed. 2003, 42, 3497-3500.
115． Xun Wang, Yadong Li*, et al., Rare earth compound nanotubes, Adv. Mater. 2003, 15, 1442-1445.
116． Xun Wang, Yadong Li*, Rare earth Compound Nanowires, nanotubes and fullerene-like nanoparticles: Synthesis, characterization and properties, Chem. Eur. J. 2003, 9, 5627-5635.
117． Xun Wang, Yadong Li*, Synthesis and Formation Mechanism of Manganese Dioxides Nanowires/ nanorods, Chem. Eur. J. 2003, 9, 300-306.
118． Xun Wang, Yadong Li*, Synthesis and Characterization of Lanthanide Hydroxides Single Crystal Nanowires. Angew. Chem. Int. Ed. 2002, 41, 4190-4193.
119． Xun Wang, Yadong Li*, Rational Synthesis of Alpha MnO2 Nanorods, Chem. Commun. 2002, 764-765.
120． Xun Wang, Yadong Li*, Selected-Control Hydrothermal Synthesis of Alpha- and Beta MnO2 nanowires. J. Am. Chem. Soc. 2002, 124, 2880-2881.

huaihuaxiang

2017国家重点研发计划“变革性技术关键科学问题”重点专项

项目编号        项目名称        项目牵头承担单位        项目负责人        中央财政经费 （万元）        项目实施周期 （年）

2017YFA0700100        甲烷和二氧化碳催化转化及外场耦合化学键精准重构        清华大学        王训        2810.00        5

yangtao

题目: Sub-1nm Ultrathin Nanocrystals
讲座人: 王训 教授、清华大学
             国家杰出青年基金获得者、长江学者特聘教授
时间: 5月25日（周五）上午10:00-11:00
地点: 厦门大学卢嘉锡楼202报告厅


嘉宾介绍：
清华大学化学系教授，国家杰出青年科学基金获得者，教育部“长江学者”特聘教授，化学系系主任，有机光电子与分子工程教育部重点实验室主任。主要从事无机纳米材料化学研究，在无机纳米晶体、纳米催化剂控制合成、形成机制及组装领域取得了一些进展。共发表SCI论文200余篇，论文SCI总引用17000余次。入选第三批国家“万人计划”科技创新领军人才、首批中组部青年拔尖人才支持计划。

wish

shenhuhu

清华王训Chem综述: 金属相过渡金属硫族纳米催化剂在能源转化中的应用

电催化或光驱动水裂解制备氢气技术因其工艺简单、环境友好、产品纯度高和原料来源经济等特点一直广受研究者的青睐，有望实现电能或光伏能向化学能的高效转化和存储，成为降低社会对化石燃料依赖的有效途径。然而，目前这种技术中所用到的贵金属催化剂昂贵的价格和较低的自然丰度限制了其大规模工业化应用，同时其较高的过电势以及不良的循环稳定性严重降低了能源转换效率。因此，开发制备新型高性能、廉价的水裂解催化剂迫在眉睫。金属相过渡金属硫族化合物是一类新兴的水裂解催化剂，其本征催化活性高、活性位点数量多、导电性好、廉价易制备，有希望代替铂基贵金属催化剂应用在实际电解水体系中。

清华大学有机光电与分子工程重点实验室王训教授课题组，近日应邀在Chem上发表题为“Metallic Transition-Metal Dichalcogenide Nanocatalysts for Energy Conversion” 的Review文章（Chem, 2018, 4, 1510）。本文深入介绍了金属相过渡金属硫族纳米催化剂的合成策略、结构特点、特殊性质以及能源转化应用。特别地，作者在文中强调了此类催化剂本征活性高的内在原因，重点介绍了电催化剂、光催化剂以及光电催化剂的创新设计及应用。最后，作者展望了该领域未来的机遇与挑战。

文章首先指出设计并制备高性能、廉价易得的水裂解催化剂是目前新能源转化与储存领域，尤其是电催化和光催化领域的热点及难点问题。作者从金属相过渡金属硫族化合物的基本结构和特殊物理、化学及电学等性质出发，从催化位点的本征活性、活性位点数量和导电性三个影响催化性能的方面分析了此类催化剂的优势。通过对催化剂结构、形貌、组分的设计，来调控催化位点的本征活性、活性位点数量、导电性以及催化传质，从而实现催化性能的提升。

近年来，随着以石墨烯为代表的二维材料的蓬勃发展，研究者对于二维材料的研究展现出了浓厚的兴趣。其中，类石墨烯的过渡金属硫族化合物因其独特的物理、化学、电学性质在电催化和光催化领域有广泛的应用。通过对其电子结构的调控，能够实现过渡金属硫族化合物的相控制合成，这对催化性能的提升具有重要意义。

过渡金属硫族化合物可分为半导体相和金属相，相比于半导体相，金属相过渡金属硫族化合物导电性有显著提升，能够加快催化反应动力学并且降低电子传输损失。同时，其较大的活性位点数量和较高的本征催化活性使得发展制备高效水裂解催化剂应用在实际工业生产中成为可能。虽然该领域在发展过程中还存在很多亟待解决的问题，但是其发展空间较大，值得继续深入探索。
由于金属相过渡金属硫族纳米催化剂在能源转换领域的巨大优势，本文重点综述了此类催化剂的结构、形貌及组分的设计合成及其能源转化催化应用，揭示了其本征活性高的内在机理和影响催化活性的因素，进而展望了该领域的未来发展方向。
从基础研究和实际应用的角度出发，作者也着重指出，大多数金属相过渡金属硫族化合物属于亚稳态，在一定条件下这种材料容易转变回其相对稳定的半导体相。因此，在催化过程中，研究者需要注意金属相过渡金属硫族纳米催化剂的稳定性，是否能够持续提供高催化活性也是限制此类催化剂发展的重要因素。目前，已有一些稳定策略相继被报道出来，相信未来在实际催化过程中困扰研究者的稳定性问题终将解决。
最后作者提到，目前关于金属相过渡金属硫族纳米催化剂在能源转化领域的应用工作被大量报道，其电催化和光催化制备氢气的效率在不断提升，这也标志着该领域有巨大的发展前景。但是，对于未来的实际工业化应用来说，此类催化剂的大规模制备以及实际应用的可行性仍旧是该领域的关键挑战之一。对于基础研究来说，此类催化剂的催化机理研究还远远不够，从原子、分子层面深入揭示其催化行为也同样是该领域未来的发展方向。当然，也有理由相信，在未来对于金属相过渡金属硫族纳米催化剂将会有更为全面而深刻的认识。

原文链接：https://www.cell.com/chem/fulltext/S2451-9294(18)30125-6
免费下载链接：https://authors.elsevier.com/a/1XNev8jWHD-Vz8

shicong

8月8～11日，第六届国际溶剂热水热联合会（ISHA）会议在日本仙台东北大学（Tohoku University）举行。8月10日，国际溶剂热水热联合会主席、美国罗格斯大学（Rutgers University）理查德·里曼教授（Richard E Riman）在会上宣布：国际溶剂热水热联合会资深理事会经过投票，决定将2018年度Roy-Somiya 奖章授予清华大学化学系王训教授，表彰他对国际水热和溶剂热反应研究领域所作出的突出贡献。王训应邀出席了颁奖仪式，并在11日做了题为“水/溶剂热合成：从纳米到亚1nm的纳米晶（Hydro/Solvothermal Synthesis: from Nano to Sub-1nm Nanocrystals）”的学术报告。

国际溶剂热水热联合会主席理查德·里曼为王训颁发奖章

Roy-Somiya奖章由国际溶剂热水热联合会设立于2008年，以该联合会的两位赞助人——国际著名材料学家和溶剂热/水热研究学者、美国宾夕法尼亚州立大学资深教授鲁斯图姆·罗伊（Rustum Roy）和日本东京工业大学资深教授宗宫重行（Shigeyuki Somiya）的名字共同命名，每两年由该联合会国际资深理事会从全球范围内遴选一位45岁以下的中青年优秀科学家，表彰其在溶剂热/水热研究领域所作出的创造性贡献。

王训教授主要从事无机纳米材料化学研究。2008年开始独立领导课题组开展研究工作，在系统总结了水热/溶剂热条件下成核生长规律以及纳米晶尺寸限制规律的基础上，提出了“亚纳米尺度材料”的概念，发展了系列亚纳米尺度材料合成方法；基于亚纳米尺寸厚度（氧化）石墨烯及单层MoS2的独特组装规律，在国际上首次实现了三维（氧化）石墨烯组装体、单层MoS2三维组装体构建；发现了亚纳米尺度材料类大分子特性，并以此为基础开展了力学、光学、催化等方向的系统性研究工作。

该系列研究长期得到国家自然科学基金委、科技部、教育部的经费支持。

jidianqi

清华大学王训Chem. Mater.：超薄钨青铜纳米线具有高效的光热转换性能

王训等人介绍了一种简单的一步溶剂热制备超薄钨青铜纳米线（QTBNWs）的方法。而只需改变碱碳酸盐和钨酸盐的起始类型，就可以制备出一系列碱金属掺杂的QTBNWs。这种合成的QTBNWs具有强的近红外(NIR)吸收能力、较高的可见光透射能力和好的光热转换性能，其性能优于钨青铜纳米棒和三元TBNWs。其优异的光热性能应归功于表面等离子体共振(SPR)效应。

Zhang S M, Shi Y A, et al. Ultrathin tungstenbronze nanowires with efficient photo-to-thermal conversion behavior[J]. Chemistry of Materials, 2018.

DOI: 10.1021/acs.chemmater.8b04437

https://pubs.acs.org/doi/10.1021/acs.chemmater.8b04437

xinqing

二维杂化亚纳米材料（2D HSNMs）由于尺寸效应导致更多的表面活性中心充分暴露；同时，较大的比表面积和多组分可能产生的协同效应，使其在催化领域具有广阔的应用前景。多酸（POM）团簇作为一种具有明确结构，尺寸介于原子/分子与纳米晶体之间的凝聚态物质，由于团簇内部的电子离域特性，导致其易于接收和失去电子。如果能够在亚纳米尺度上实现无机化合物与POM的有序结合，POM中电子的转移，很有可能间接实现对无机化合物中金属价态的调节，进而提升材料整体的催化性能。
        基于此，清华大学王训教授团队近日在Small Structures上报道了题为“功能导向精准合成氧化锰-多酸二维杂化亚纳米片超结构”的工作。在该工作中，他们从功能导向的角度出发，设计、构筑了三种能够在温和条件下高效催化芳基醇选择性氧化为芳基醛的MnO-POM二维杂化亚纳米片。即通过将三种不同分子构型，尺寸约为1纳米的钨基多酸团簇（H3PW12O40, [TBA]2W6O19, [TBA]4W10O32）分别引入MnO反应体系，利用多酸团簇干预材料成核过程，将无机晶核限制在亚纳米尺度，尺寸相近的多酸团簇与MnO无机晶核共组装，最终生长形成三种形貌相近、结构高度有序的二维杂化亚纳米片超结构。分子动力学模拟的结果表明，多组分间的静电相互作用和范德华相互作用是驱动该类亚纳米片形成的主要驱动力。此外，该团队运用密度泛函理论（DFT）进一步探究了该类催化剂的构效关系。DFT计算结果表明，引入的POM不仅可以与MnO结合形成MnO-POM二维杂化亚纳米片，而且，POM还可以轻微氧化Mn2+，从而提高MnO的氧化性能。上述工作为功能导向无机精准合成二维亚纳米材料提供了新的思路。

图1. 功能导向精准合成MnO-POM二维杂化亚纳米片的示意图。

        论文信息
        Functionally Guided Precise Synthesis of Manganous Oxide-Polyoxometalate 2D Hybrid Sub-1 nm Nanosheet Superstructures
Junli Liu, Wenxiong Shi*, Siyang Nie*, Xun Wang*
        Small Structures
       DOI: 10.1002/sstr.202200039


https://onlinelibrary.wiley.com/doi/full/10.1002/sstr.202200039