北京大学化学与分子工程学院应用化学研究所翟茂林

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翟茂林，北京大学教授，博士生导师。1999年获得北京大学理学博士学位，2008-2009年，日本原子能研究机构特聘研究员(JAEA Fellow)。主讲课程：化学工程基础（本），高分子辐射化学（研）。研究领域为：天然高分子/生物高分子材料的功能化改性；聚合物质子/离子交换膜的合成及应用；特种性能高分子凝胶材料的合成、特异性溶胀行为研究；离子液体的辐射效应及其相关化学反应研究。



翟茂林 教授, 博士生导师
功能高分子材料，辐射化学
电 话/传真：010-62753794
电子信箱：mlzhai@pku.edu.cn
课题组主页：www.chem.pku.edu.cn/appliedchem/fuhua/index.htm
2009年，北京大学教授
2008-2009年，日本原子能研究机构特聘研究员 (JAEA Fellow)
2005年，北京大学博士生导师；2000年，北京大学副教授
2001-2002年，日本原子能研究所、东京大学日本学术振兴会资助博士后 (JSPS)
1998年，日本原子能研究所研究员 (Co-Researcher)
1999年，北京大学理学博士；
1993年，北京大学理学硕士；
1990年，北京理工大学工学学士。
主讲课程：
化工基础（本），高分子辐射化学（研）,前沿文献阅读（研）
出版教材及专著
1.        吴王锁，翟茂林，李首建、唐志刚，《放射化学与辐射化学实验教程》，兰州大学出版社，2013
2.        Zhai Maolin*, Zhao long, Huang Ling, Xu Ling, Yuan Liyong, Wang Min. Chitin, Chitosan, Oligosaccharides and Their Derivatives: Biological Activities and Applications. Chapter 31 Radiation Functionalization and Applications of Chitosan and Its Derivatives, CRC Press, 2010.
3.        翟茂林、伊敏、哈鸿飞，《高分子材料辐射加工技术及进展》，化工出版社，2004。
4.        北京大学、南京大学、南开大学编 （翟茂林主编），《化工基础实验》，北京大学出版社,2004。
5.        温瑞媛，严世强，江洪，翟茂林，《化学工程基础》，北京大学出版社，2002。
研究领域和兴趣
(1)特种功能高分子凝胶、微球及膜材料的辐射合成及其在超级电容器，钒液流电池，锂同位素分离，铬、铼等重金属废水吸附分离方面的应用研究；
(2)石墨烯、金属纳米材料的辐射制备及其在超级电容器、催化剂等方面的应用研究；
(3)先进核燃料循环中分离试剂的辐射化学研究, 包括次锕系/镧系萃取体系以及基于功能离子液体的新型萃取分离体系等的辐射效应研究;
(4)核辐射场及太空辐射环境中高分子及其复合材料的辐射效应研究,研发耐辐射稳定性的高分子复合材料;
学术兼职
中国核学会辐射研究与应用学会副理事长，中国同位素与辐射行业协会常务理事，北京核学会常务理事，IAEA/RCA辐射加工项目中国国家技术协调员，《辐射研究与辐射工艺学报》编委, 《核化学与放射化学》编委等。
代表性论文及专利(2011-2015 )
1.        Wang Shuojue, Ma Hui-Ling, Peng Jing, Zhang Youwei, Chen Jian, Wang Liangliang, Xu Ling, Li Jiuqiang, Zhai, Maolin* Facile Synthesis and Adsorption Behavior of Polymeric Ionic Liquid Gel for Cr(VI) Removal，Dalton Transaction 2015, 44，7618-7625.
2.        Ao Yinyong, Yuan Weijin, Yu Tianlin, Peng Jing, Li Jiuqiang, Zhai Maolin*, Zhao Long, Radiolysis of Crown Ether-ionic Liquid Systems: Identification of Radiolytic Products and Their Effect on the Removal of Sr2+ from Nitric Acid, Physical Chemistry Chemical Physics, 2015,17, 3457-3462.
3.        Yuan Jie, Peng Jing, Li Jiuqiang, Ju Xuecheng, Zhai Maolin*, Synthesis of Poly(dimethylaminoethyl methacrylate) with High Cloud Point by RAFT Polymerization under γ-Irradiation, Radiation Physics and Chemistry, 2015, 108, 95-101.
4.        Chen Jian, Wang Shuojue, Peng Jing, Li Jiuqiang, Zhai Maolin*, Novel Lipophilic Polyelectrolyte Gels Containing Quaternary Ammonium Salt with Superabsorbent Capacity for Organic Solvents, ACS Applied Materials & Interfaces 2014, 6 (17), 14894–14902.
5.        Zhou Hanyang, Ao Yinyong, Yuan jie, Peng Jing*, Li Jiuqiang, Zhai Maolin*, Extraction mechanism and g-radiation effect on the removal of Eu3+ by a novel BTPhen/[Cnmim][NTf2] system in the presence of nitric acid, RSC Advance, 2014, 4, 45612-45618.
6.        Wang Shuojue, Liu Junzi, Yuan Liyong, Cui Zhenpeng, Peng Jing, Li Jiuqiang, Zhai Maolin*, Liu Wenjian*. Towards Understanding the Color Change of 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide during Gamma Irradiation: an Experimental and Theoretical Study, Physical Chemistry Chemical Physics, 2014, 16(35), 18729-18735.
7.        Ao Yinyong, Zhou Hanyang, Yuan Weijin, Wang Shuojue, Peng Jing, Zhai Maolin*, Wang Jianyong, Zhao Ziqiang*, Zhao, Long, Wei Yuezhou, α-Radiolysis of Ionic Liquid Irradiated with Helium Ion Beam and the Influence of Radiolytic Products on Dy3+ Extraction, Dalton Transaction 2014, 43 (14), 5580 - 5585
8.        Yuan Jie, Yu Chuhong, Pengjing, Wang Yu, Ma Jun, Qiu Jingyi, Li Jiuqiang, Zhai Maolin*, Facile Synthesis of Amphoteric Ion Exchange Membrane by Radiation Grafting of Sodium Styrene Sulfonate and N,N-dimethylaminoethyl Methacrylate for Vanadium Redox Flow Battery, Journal of Polymer Science, Part A, 2013, 51, 5194-5202.
9.        Yu Chuhong, Zhao Li，Wang Shuojue, Cui Zhenpeng, Peng Jing*, Li Jiuqiang, Zhai Maolin*, Huang Jianbin*, General and One-step Fabrication of Multi-responsive Micelles with Various Morphologies from Cyclic Compounds Containing Oxyethylene Units, Soft Matter, 2013, 9(25), 5959-5965.
10.        Ao Yingyong, Peng Jing, Cui Zhenpeng, Li Jiuqiang, Zhai Maolin*, The Identification of Radiolytic Products of [C4mim][NTf2] Anion under γ-Radiation and Their Effect for Sr2+ Extraction. Dalton Transaction 2013, 42(12), 4299-4305.
11.        Wang Shuojue, Zhang Youwei, Ma Hui-Ling, Zhang Qilu, Peng Jing, Li Jiuqiang, Zhai Maolin*, Ionic-liquid-assisted One-step Synthesis of Ag-reduced Oxide Graphene Nanocomposites by Gamma Irradiation. Carbon 2013, 55, 245-252.
12.        Zhang Qilu, Zhang Youwei, Gao Zhaohui, Ma Huiling, Wang Shuojue, Peng Jing, Li Jiuqiang, Zhai Maolin*, A Facile Syntheses of Platinum Nanoparticles Decorated Graphene by One-step -ray Induced Reduction for High Rate Supercapacitor, Journal of Materials Chemistry C, 2013, 1, 321-328.
13.        Hao Yan, Peng Jing*, Ao Yingyong，Li Jiuqiang, Zhai Maolin*, Radiation Effect of Microcrystalline Cellulose in 1-Butyl-3-methylimidazolium Chloride Ionic Liquid, Carbohydrate Polymers, 2012, 90, 1629-1633.
14.        Ma Jun, Wang Yu, Peng Jing, Qiu Jingyi, Li Jiuqiang, Zhai Maolin*, Designing a New Process to Prepare Amphoteric Ion Exchange Membrane with Well-distributed Grafted Chains for Vanadium Redox Flow Battery, Journal of Membrane Science 2012，419-420, 1-8.
15.        Zhang Youwei, Ma Huiling, Zhang Qilu, Peng Jing, Li Jiuqiang, Zhai Maolin*, Yu Zhongzhen*, Facile Synthesis of Well-dispersed Graphene by -Ray Induced Reduction of Graphene Oxide. Journal of Materials Chemistry, 2012, 22 (26), 13064 -13069.
16.        Ma Huiling, Zhang Youwei, Hu Qihui, Yan Dong, Yu Zhongzhen*, Zhai Maolin*, Chemical Reduction and Removal of Cr(VI) from Acidic Aqueous Solutions by Ethylenediamine-reduced Graphene Oxide, Journal of Materials Chemistry, 2012, 22, 5914-5916.
17.        Hu Guowen, Wang Yu, Ma Jun, Peng Jing, Li Jiuqiang, Zhai Maolin*, A Novel Amphoteric Ion Exchange Membrane synthesized by Radiation-induced Grafting α-Methylstyrene and N,N-dimethylaminoethyl Methacrylate for Vanadium Redox Flow Battery Application, Journal of Membrane Science，2012, 407-408, 184-192.
18.        Zhang Youwei, Xu Ling, Zhao Long, Peng Jing, Li Cancan, Li Jiuqiang, Zhai Maolin*, Radiation Synthesis and Cr(VI) Removal of Cellulose Microspheres Adsorbent, Carbohydrate Polymer. 2012, 88, 931-938.
19.        Cheng Qiang, Li Cancan, Xu Ling, Li Jiuqiang, Zhai Maolin*, Adsorption of Cr(Ⅵ) Using the Amphiphilic Gels Based on Dimethylaminoethyl Methacrylate Modified with 1-Bromoalkanes, Chemical Engineering Journal, 2011, 173, 42-48.
20.        Wang Yu, Qiu Jingyi, Zhai Maolin*, Peng Jing, Xu Ling, Li Jiuqiang, Study on the Chemical Stability of the Anion Exchange Membrane of Grafting Dimethylaminoethyl Methacrylate, Journal of Membrane Science, 2011, 376, 70-77.
课题组网址：www.chem.pku.edu.cn/appliedchem/fuhua/index.htm

yujiaxue

咪唑六氟磷酸盐聚离子液体凝胶电解质的辐射合成及性能研究

李幸晓,韩冬 ,林廷睿,崔雨,彭静,李久强,翟茂林,

北京大学化学与分子工程学院 教育部高分子化学与物理重点实验室 北京分子科学国家实验室 北京 100871

通讯作者: 翟茂林, mlzhai@pku.edu.cn
基金项目: 国家自然科学基金(基金号11375019)资助项目
摘要: stringUtils.convertMathHtml(以1-乙烯基-3-烷基咪唑六氟磷酸盐CnvimPF6(n=6, 12)为单体, (1, 6-亚己基)-双(3-乙烯基咪唑)六氟磷酸盐为交联剂, 六氟磷酸锂为添加剂, 混合碳酸酯为溶剂, 采用辐射引发聚合、交联合成了新型的聚离子液体凝胶电解质(简称PCnvimPF6-Li GPE), 并研究了离子液体单体侧链长度、单体浓度、交联剂含量对PCnvimPF6-Li GPE性能的影响.结果表明所合成的PCnvimPF6-Li GPE具有良好的力学性能和高离子电导率, 最大离子电导率可达7.18 mS/cm.)