武汉大学化学与分子科学学院物理化学研究所曹余良

darenw

曹余良，武汉大学化学与分子科学学院教授，珞珈特聘教授，博士生导师。主要研究领域是电化学能量储能与转换新体系。主持多项国家项目，包括国家重点研发计划“新能源汽车”领域课题、973子课题项目、国家自然科学基金面上项目等。在Nature Energy、Nature Nanotech.、Energy Environ. Sci.、Adv. Mater.、Nano. Lett.等国际顶尖学术期刊上发表论文200余篇，他引11000余次，h指数为58，ESI高被引论文18篇。获批发明专利8项，申请美国发明专利4项。相关工作获得2013年度国家技术发明二等奖，2012年获教育部“新世纪优秀人才支持计划”。

博士 , 教授
研究方向： 物理化学
联系电话： 027-68754526
Email: ylcao@whu.edu.cn

教育与研究经历

1997年7月于武汉大学化学系获学士学位，2003年6月于武汉大学化学系获博士学位。2002年9月在武汉大学化学与分子科学学院电化学研究所任教。

教学情况

物理化学（本科）、应用电化学（化院研究生）

承担项目与课题

主要研究方向是电化学能量储存与转化，内容涉及锂离子电池和钠离子电池体系。

近年来主持多项国家自然科学基金面上项目和重点研发计划等研究工作，包括主持“新能源汽车”领域重点研发计划课题项目“电池安全性和环境适应性研究”及参与“储能”领域重点研发课题项目“储钠材料设计、制备及储能机理研究”，并作为主要参加人员国家973计划课题《绿色二次电池新体系相关基础研究》项目子课题。

1.       方永进, 陈重学, 艾新平, 杨汉西, 曹余良*, 钠离子电池正极材料研究进展[J],物理化学学报, 33 (2017) 211-241.

2.       Y.Fang, L. Xiao, J. Qian, Y. Cao*, X. Ai, Y. Huang*, H. Yang*, 3D GrapheneDecorated NaTi2(PO4)(3) Microspheres as a Superior High-Rate andUltracycle-Stable Anode Material for Sodium Ion Batteries, Advanced EnergyMaterials, 6 (2016) 1502197.

3.       C.Fang, Y. Huang*, W. Zhang, J. Han, Z. Deng, Y. Cao*, H. Yang*, Routes to HighEnergy Cathodes of Sodium-Ion Batteries, Advanced Energy Materials, 6 (2016).

4.       Z.Zeng, X. Jiang, R. Li, D. Yuan, X. Ai, H. Yang, Y. Cao*, A Safer Sodium-IonBattery Based on Nonflammable Organic Phosphate Electrolyte, Advanced Science,3 (2016) 1600066.

5.       L.Xiao, Y. Cao*, W.A. Henderson, M.L. Sushko, Y. Shao, J. Xiao, W. Wang, M.H.Engelhard, Z. Nie, J. Liu*, Hard carbon nanoparticles as high-capacity,high-stability anodic materials for Na-ion batteries, Nano Energy, 19 (2016)279-288.

6.       Y.Gui, Y. Cao*, G. Li, X. Ai, X. Gao*, H. Yang*, A solar storable fuel cell withefficient photo-degradation of organic waste for direct electricity generation,Energy Storage Materials, 5 (2016) 165-170.

7.       J.S.Yang, L.F. Xiao, W. He, J.W. Fam, Z.X. Chen*, X.P. Ai, H.X. Yang, Y.L. Cao*,Understanding Voltage Decay in Lithium-Rich Manganese-Based Layered CathodeMaterials by Limiting Cutoff Voltage, ACS Applied Materials & Interfaces, 8(2016) 18867-18877.

8.       S.Qiu, X. Wu, L. Xiao*, X. Ai, H. Yang, Y. Cao*, Antimony NanocrystalsEncapsulated in Carbon Microspheres Synthesized by a Facile Self-CatalyzingSolvothermal Method for High-Performance Sodium-Ion Battery Anodes, Acs AppliedMaterials & Interfaces, 8 (2016) 1337-1343.

9.       H.Lu, L. Wu, L. Xiao, X. Ai, H. Yang, Y. Cao*, Investigation of the Effect ofFluoroethylene Carbonate Additive on Electrochemical Performance of Sb-BasedAnode for Sodium-Ion Batteries, Electrochimica Acta, 190 (2016) 402-408.

10.   X.Y. Jiang, X.M. Zhu, X.L.Liu, L.F. Xiao, X.P. Ai, H.X. Yang, Y.L. Cao*, Nanospherical-Like ManganeseMonoxide/Reduced Graphene Oxide Composite Synthesized by Electron BeamRadiation as Anode Material for High-Performance Lithium-Ion Batteries,Electrochimica Acta, 196 (2016) 431-439.

11.   X. Zhu, X. Jiang, X. Ai, H.Yang, Y. Cao*, TiO2 ceramic-grafted polyethylene separators for enhancedthermostability and electrochemical performance of lithium-ion batteries,Journal of Membrane Science, 504 (2016) 97-103.

12.   Y. Fang, L. Xiao, X. Ai, Y.Cao*, H. Yang, Hierarchical Carbon Framework Wrapped Na3V2(PO4)3 as a SuperiorHigh-Rate and Extended Lifespan Cathode for Sodium-Ion Batteries, AdvancedMaterials, 27 (2015) 5895-5900.

13.   Y. Fang, Q. Liu, L. Xiao*,X. Ai, H. Yang, Y. Cao*, High-Performance Olivine NaFePO4 Microsphere CathodeSynthesized by Aqueous Electrochemical Displacement Method for Sodium IonBatteries, Acs Applied Materials & Interfaces, 7 (2015) 17977-17984.

14.   L. Wu, H. Lu, L. Xiao*, X.Ai, H. Yang, Y. Cao*, Electrochemical properties and morphological evolution ofpitaya-like Sb@C microspheres as high-performance anode for sodium ionbatteries, Journal of Materials Chemistry A, 3 (2015) 5708-5713.

15.   L. Wu, H. Lu, L. Xiao, X.Ai, H. Yang, Y. Cao*, Improved sodium-storage performance of stannoussulfide@reduced graphene oxide composite as high capacity anodes for sodium-ionbatteries, Journal of Power Sources, 293 (2015) 784-789.

16.   Y.X. Wang, K.H. Shang, W.He, X.P. Ai, Y.L. Cao*, H.X. Yang, Magnesium-Doped Li1.2 Co0.13Ni0.13Mn0.54 O2for Lithium-Ion Battery Cathode with Enhanced Cycling Stability and RateCapability, Acs Applied Materials & Interfaces, 7 (2015) 13014-13021.

17.   D.D. Yuan, Y.X. Wang, Y.L.Cao*, X.P. Ai, H.X. Yang, Improved Electrochemical Performance ofFe-Substituted NaNi0.5Mn0.5O2 Cathode Materials for Sodium-Ion Batteries, AcsApplied Materials & Interfaces, 7 (2015) 8585-8591.

18.   X. Zhu, X. Jiang, X. Ai, H.Yang, Y. Cao*, A Highly Thermostable Ceramic-Grafted Microporous PolyethyleneSeparator for Safer Lithium-Ion Batteries, Acs Applied Materials &Interfaces, 7 (2015) 24119-24126.

19.   A Honeycomb-LayeredNa3Ni2SbO6: A High-Rate and Cycle-Stable Cathode for Sodium-Ion Batteries,Dingding Yuan, Xinmiao Liang, Lin Wu, Yuliang Cao,* Xinping Ai, Jiwen Feng andHanxi Yang*, Adv. Mater. 26 (2014) 6301.

20.   Mesoporous Amorphous FePO4Nanospheres as High-Performance Cathode Material for Sodium-Ion Batteries,Fang, Yongjin; Xiao, Lifen*; Qian, Jiangfeng; Ai, Xinping; Yang, Hanxi, Cao,Yuliang *, Nano Lett., 14 (2014) 3539.

21.   Sb-C nanofibers with longcycle life as an anode material for high-performance sodium-ion batteries, L.Wu, X.H. Hu, * J.F. Qian, F. Pei, F.Y. Wu, R.J. Mao, X.P. Ai, H.X. Yang, Y.L.Cao, * Energy & Environmental Science 7 (1) (2014) 323-328.

22.   D.D. Yuan, X.H. Hu*, J.F.Qian, F. Pei, F.Y. Wu, R.J. Mao, X.P. Ai, H.X. Yang, Y.L. Cao*, P2-typeNa0.67Mn0.65Fe0.2Ni0.15O2 Cathode Material with High-capacity for Sodium-ionBattery, Electrochimica Acta, 116 (2014) 300-305.

23.   Z.Q. Zeng, X.Y. Jiang, B.B.Wu, L.F. Xiao, X.P. Ai, H.X. Yang, Y.L. Cao*, Bis(2,2,2-trifluoroethyl)methylphosphonate: An Novel Flame-retardant Additive for Safe Lithium-ionBattery, Electrochimica Acta, 129 (2014) 300-304.

24.   L. Wu, H.Y. Lu, L.F. Xiao*,J.F. Qian, X.P. Ai, H.X. Yang, Y.L. Cao*, A tin(II) sulfide-carbon anodematerial based on combined conversion and alloying reactions for sodium-ionbatteries, Journal of Materials Chemistry A, 2 (2014) 16424-16428.

25.   B.B. Wu, X.Y. Jiang, L.F.Xiao, W.H. Zhang, J.X. Pan, X.P. Ai, H.X. Yang, Y.L. Cao*, Enhanced CyclingStability of Sulfur Cathode Surface-Modified by Poly(N-methylpyrrole),Electrochimica Acta, 135 (2014) 108-113.

26.   D.D. Yuan, W. He, F. Pei,F.Y. Wu, Y. Wu, J.F. Qian, Y.L. Cao,* X.P. Ai, H.X. Yang, * Synthesis andelectrochemical behaviors of layered Na0.67Mn0.65Co0.2Ni0.15O2 microflakes as astable cathode material for sodium-ion batteries, Journal of MaterialsChemistry A 1 (12) (2013) 3895-3899.

27.   L.F. Xiao, Y.L. Cao, * J.Xiao, B. Schwenzer, M.H. Engelhard, L.V. Saraf, Z.M. Nie, G.J. Exarhos, J. Liu,*Molecular structures of polymer/sulfur composites for lithium-sulfur batterieswith long cycle life, Journal of Materials Chemistry A 1 (33) (2013) 9517-9526.

28.   L. Wu, P. Pei, R.J. Mao,F.Y. Wu, Y. Wu, J.F. Qian, Y.L. Cao,* X.P. Ai, H.X. Yang, SiC-Sb-Cnanocomposites as high-capacity and cycling-stable anode for sodium-ionbatteries, Electrochimica Acta 87 (2013) 41-45.

29.   L. Wu, X.H. Hu, J.F. Qian,F. Pei, F.Y. Wu, R.J. Mao, X.P. Ai, H.X. Yang, Y.L. Cao*, A Sn-SnS-Cnanocomposite as anode host materials for Na-ion batteries, Journal ofMaterials Chemistry A 1 (24) (2013) 7181-7184.

30.   B.B. Wu, F. Pei, Y. Wu,R.J. Mao, X.P. Ai, H.X. Yang, Y.L. Cao*, An electrochemically compatible andflame-retardant electrolyte additive for safe lithium ion batteries, Journal ofPower Sources 227 (2013) 106-110.

31.   W. He, D.D. Yuan, J.F.Qian, X.P. Ai, H.X. Yang, Y.L. Cao*, Enhanced high-rate capability and cyclingstability of Na-stabilized layered Li-1.2 Co0.13Ni0.13Mn0.54 O-2 cathodematerial, Journal of Materials Chemistry A 1 (37) (2013) 11397-11403.

32.   Z.X. Chen, S. Qiu, Y.L.Cao*, J.F. Qian, X.P. Ai, K. Xie, X.B. Hong, H.X. Yang*, Hierarchical porousLi2FeSiO4/C composite with 2 Li storage capacity and long cycle stability foradvanced Li-ion batteries, Journal of Materials Chemistry A 1 (16) (2013)4988-4992.

33.   L.F. Xiao, Y.L. Cao, J.Xiao, W. Wang, L. Kovarik, Z.M. Nie, J. Liu*, High capacity, reversiblealloying reactions in SnSb/C nanocomposites for Na-ion battery applications,Chemical Communications 48 (27) (2012) 3321-3323.

34.   L.F. Xiao, Y.L. Cao*, J.Xiao, B. Schwenzer, M.H. Engelhard, L.V. Saraf, Z.M. Nie, G.J. Exarhos, J.Liu*, A Soft Approach to Encapsulate Sulfur: Polyaniline Nanotubes forLithium-Sulfur Batteries with Long Cycle Life, Advanced Materials 24 (9) (2012)1176-1181.

35.   W. He, J.F. Qian, Y.L.Cao*, X.P. Ai, H.X. Yang, Improved electrochemical performances ofnanocrystalline Li Li0.2Mn0.54Ni0.13Co0.13 O-2 cathode material for Li-ionbatteries, Rsc Advances 2 (8) (2012) 3423-3429.

36.   Z.X. Chen, S. Qiu, Y.L.Cao*, X.P. Ai, K. Xie, X.B. Hong, H.X. Yang*, Surface-oriented andnanoflake-stacked LiNi0.5Mn1.5O4 spinel for high-rate and long-cycle-lifelithium ion batteries, Journal of Materials Chemistry 22 (34) (2012)17768-17772.

37.   Z. Chen, M. Zhou, Y. Cao*,X. Ai, H. Yang, J. Liu*,  In Situ Generation of Few-Layer GrapheneCoatings on SnO2-SiC Core-Shell Nanoparticles for High-Performance Lithium-IonStorage, Advanced Energy Materials 2 (1) (2012) 95-102.

38.   Y.L. Cao*, L.F. Xiao, M.L.Sushko, W. Wang, B. Schwenzer, J. Xiao, Z.M. Nie, L.V. Saraf, Z.G. Yang, J.Liu*, Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications,Nano Letters 12 (7) (2012) 3783-3787.

39.   Y.L. Cao*, L.F. Xiao, W.Wang, D.W. Choi, Z.M. Nie, J.G. Yu, L.V. Saraf, Z.G. Yang, J. Liu*, ReversibleSodium Ion Insertion in Single Crystalline Manganese Oxide Nanowires with LongCycle Life, Advanced Materials 23 (28) (2011) 3155.

40.   Y. Cao, X. Li, I.A. Aksay,J. Lemmon, Z. Nie, Z. Yang, J. Liu*, Sandwich-type functionalized graphenesheet-sulfur nanocomposite for rechargeable lithium batteries, PhysicalChemistry Chemical Physics 13 (17) (2011) 7660-7665.

41.   J.F. Qian, M. Zhou, Y.L.Cao*, X.P. Ai, H.X. Yang, Template-Free Hydrothermal Synthesis of NanoembossedMesoporous LiFePO4 Microspheres for High-Performance Lithium-Ion Batteries,Journal of Physical Chemistry C 114 (8) (2010) 3477-3482.

42.   Z.X. Chen, Y.L. Cao*, J.F.Qian, X.P. Ai, H.X. Yang*, Facile synthesis and stable lithium storageperformances of Sn- sandwiched nanoparticles as a high capacity anode material forrechargeable Li batteries, Journal of Materials Chemistry 20 (34) (2010)7266-7271.

43.   Z. Chen, Y. Cao*, J. Qian,X. Ai, H. Yang*, Antimony-Coated SiC Nanoparticles as Stable and High-CapacityAnode Materials for Li-Ion Batteries, Journal of Physical Chemistry C 114 (35)(2010) 15196-15201.

44.   J.F. Qian, P. Liu, Y. Xiao,Y. Jiang, Y.L. Cao*, X.P. Ai, H.X. Yang, TiO2-Coated Multilayered SnO2 HollowMicrospheres for Dye-Sensitized Solar Cells, Advanced Materials 21 (36) (2009)3663.

45.   Y.L. Cao, L.H. Yu, T. Li,X.P. Ai and H.X. Yang*，Synthesis and electrochemical characterization of carbon-coatednanocrystalline LiFePO4 prepared by polyacrylates-pyrolysis route， Journal ofPower Sources,  2007，172，913-918.

46.   Yuliang Cao, Wenchao Zhou,Xiaoyan Lia, Xinping Ai, Xueping Gao, Hanxi Yang*，Electrochemicalhydrogen storage behaviors of ultrafine Co–P particles prepared by directball-milling method， Electrochimica Acta 51 (2006) 4285–4290.

47.   W.C. Zhou, H.X. Yang, S.Y.Shao, X.P. Ai, Y.L. Cao*, Superior high rate capability of tin phosphide usedas high capacity anode for aqueous primary batteries, ElectrochemistryCommunications 8 (2006) 55–59.

48.   Lihong Yu  YuliangCao*  Hanxi Yang  Xinping Ai，Synthesis andelectrochemical properties of high-voltage LiNi0.5Mn1.5O4 electrode materialfor Li-ion batteries by the polymer-pyrolysis method， J. SolidState Electrochem., 10 (2006) 283–287

49.   Lihong Yu, Hanxi Yang,Xinping Ai and Yuliang Cao*.  Structural and Electrochemical Characterizationof Nanocrystalline Li[Li0.12Ni0.32Mn0.56]O2 Synthesized by a NovelPolymer-pyrolysis Route. J. Phys. Chem. B, 2005, 109 1148-1154.

50.   Y. Cao, H.Yang*, Improveddischarge capacity and depressed surface passivation of zinc anode in dilutealkaline solution using surfactant additives, J. Power Sources, 128(1), (2004)97-101.

51.   L.H. Yu, Y.L. Cao*, H.X.Yang, X.P. Ai, Y.Y. Ren，Preparation and electrochemical characterization of nanocrystallineLi[Li0.12Ni0.32Mn0.56]O2 pyrolyzed from polyacrylate salts，MaterialsChem. and Phys. 88 (2004) 353–356.

52.   Yuliang Cao, Lifen Xiao,Xinping Ai, and Hanxi Yang*.Surface-Modified Graphite as an ImprovedIntercalating Anode for Lithium-Ion Batteries. Electrochemical and Solid-StateLetters, 2003, 6(2): A30-33.

53.   Y.L. Cao, H.X. Yang*, X.P.Ai, L.F. Xiao．The mechanism of oxygen reduction on MnO2-catalyzed air cathode inalkaline solution． Journal of Electroanalytical Chemistry．2003, 557:127-134.