山东大学化学与化工学院分析化学占金华

shikeerzhi

占金华，男，1974年生，博士，现任山东大学化学与化工学院教授、博士生导师。研究兴趣涉及无机合成化学以及材料物理化学等领域，研究内容主要表现在原子或分子水平上控制纳米结构单元的尺寸、形状、分散度、微观结构以及表面，强调以特定的功能性质为目标实现纳米结构单元的组装，例如实现分子识别等特性。基于功能化纳米材料的优异性能，开发出可在能源、环境检测和治理以及生物医学方面有重要应用前景的材料，利用各种纳米自组装技术进一步设计出高性能微纳米器件。承担教育部“新世纪优秀人才支持计划”基金、国家自然科学基金青年基金“纳米材料与纳米结构”国家重大基础研究项目（“973”）子课题等项目。在影响因子大于10.0的期刊上发表论文30多篇，论文共获得国际刊物他引3000余次。        
【学习及工作经历】
2001.03-2002.12 台湾大学化学系
2003.02-2006.11 物质材料研究机构（日本）
2006.11-至今     山东大学化学与化工学院
电话：0531-8836-5017
【主讲课程】
分析化学
纳米材料学
环境纳米材料化学
【研究领域和兴趣】
1，纳米材料的可控合成以及功能调节
2，易挥发性有机物气敏传感器与痕量有害物的表面增强拉曼光谱检测
（与企业合作、质检机构合作）
3，污染物的催化转化（与南方环保合作）
4，纳米材料在诊断治疗学中的应用（与齐鲁医院合作）。
【主要论著】
2016
Biocompatible caramelized carbonaceous nanospheres supported paramagnetic ultrathinmanganese oxide nanosheets via self-sacrificing reduction as a MRI contrastagent for liver imaging. Carbon. 2016
Heteroepitaxial Growth of Well-Dispersed Co3O4 Nanocatalysts on Porous ZnONanoplates via Successive Hydrothermal Deposition. ChemNanoMat. 2016
3.A positively charged silver nanowire membrane for rapid on-site swabbingextraction and detection of trace inorganic explosives using a portable Ramanspectrometer. J. Nano Res. (2016) 9: 2487
Acetic acid inducedsynthesis of laminatedactivated carbon nitride nanostructures. Carbon 107(2016) 747-753
Dimolecular interaction between graphitic carbon nitride nanosheets andphenols: A mechanism study. Carbon 102 (2016) 462-469
Revealing the role of oxidation state in interaction betweennitro/amino-derived particulate matter and blood proteins. 2016;6: 25909
Surface enhanced Raman spectroscopy hyphenated with surface microextraction forin-situ detection of polycyclic aromatic hydrocarbons on food contact materials.Talanta 158 (2016) 322–329
Au-deposited porous single-crystalline ZnO nanoplates for gas sensing detectionof total volatile organic compounds. Rsc Advances, 2016, 6(44):37750-37756
Au-coated ZnO nanorods on stainless steel fiber for self-cleaning solid phasemicroextraction-surface enhanced Raman spectroscopy. Analytica Chimica Acta 923(2016) 66-73
Radar-Like MoS2 Nanoparticles as a High Efficient 808 nm Laser-InducedPhotothermal Agent for Cancer Therapy. RSC Adv, 2016, 6, 31031-31036
Facile synthesis and high formaldehyde-sensing performance of NiO–SnO 2 hybridnanospheres. RSC Adv., 2016, 6, 3919-3926
Sodium Diethyldithiocarbamate (DDTC) induced formation of positively chargedsilver nanoparticles for rapid in-situ identification of inorganic explosivesby surface enhanced Raman spectroscopy. RSC Adv., 2016, 6, 51823-51829
Fe3O4@β-CD nanocomposite as heterogeneous Fenton-like catalyst forenhanceddegradation of 4-chlorophenol (4-CP), Applied Catalysis B,Environmental,2016.01.071


2015
Hydrophobic gold nanostructuresvia electrochemical deposition for sensitive SERS detection of persistent toxicsubstances,RSC Advances,2015,5,18,13443-13450
Recent developments onnanomaterials-based optical sensors for Hg2+ detection, SCIENCE CHINA Materials,2015,58,223-240
Silver nanoplate-decoratedcopper wire for the on-site microextraction and detection of perchlorate usinga portable Raman spectrometer,Analyst,2015,140,2815-2822
Silver nanoparticles aggregateson metal fiber for solid phase microextraction-surface enhanced Ramanspectroscopy detection of polycyclic aromatic hydrocarbons,Analyst,2015,140,4668-4675
Core–shell superparamagneticFe3O4@β-CD composites for host–guest adsorption of polychlorinated biphenyls(PCBs), Journal of Colloid and Interface Science,2015,447,1-7
Nanoparticle-based screenprinting of copper zinc tin sulfide thin film as photocathode for quantum DoTsensitized solar cell, Materials Letters,2015,158,198-201

2014
A disordered silver nanowires membranefor extraction and surface-enhanced Raman spectroscopy detection, Analyst,2014,139, 2525-2530
Galvanicdisplacement induced reduction of graphene oxide, Carbon, 2014, 66, 738-741
The fabrication of oriented ZnO porousnanoplates on the silver foil with tunable hydrophobicity, CrystEngComm, 2014,16, 1831-1836
Forming Buried Junctions to Enhance thePhotovoltage Generated by Cuprous Oxide in Aqueous Solutions, Angewandte Chemie,2014,53,3493-3497
Tunable SERS-Tags-Hidden Gold Nanorattlesfor Theranosis of Cancer Cells with Single Laser Beam, Scientific Reports,2014,4,6709-6716
TheoreticalStudy of the Inclusion Complexation of TCDD with Cucurbit[n]urils, RSC Advances,2014,4(94)
Anti-TROP2 conjugated hollow goldnanospheres as a novel nanostructure for targeted photothermal destruction ofcervical cancer cells, Nanotechnology,2014, 25(34):345103
2013
Combination of Solid Phase Extraction and Surface-enhanced Raman Spectroscopy for Rapid,Analysis;  2013, 138, 2598-2603
Silver nanoparticles decorated filter paper via self-sacrificing reduction for membrane extraction surface-enhanced Raman spectroscopy detection; Analyst, 2013, 138, 2090-5
Electrospun porous CuO-Ag nanofibers for quantitative sensitive SERS detection，CrystEngComm，2013, 15, 1339-1344
Cysteamine-Modified Silver Nanoparticle Aggregates for Quantitative SERS Sensing of Pentachlorophenol with a Portable Raman Spectrometer ACS APPLIED MATERIALS & INTERFACES, 2013, 5, 6902-6908   
Chengbu Liu New Insight into the Formation Mechanism of PCDD/Fs from 2-Chlorophenol Precursor ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2013,  47, 8489-8498
Solar Hydrogen Generation by Silicon Nanowires Modified with Platinum Nanoparticle Catalysts by Atomic Layer Deposition；Angewandte Chemie；Volume 125，Issue 42，Pages 11325-11329，October 11，2013
Surface-enhanced Raman spectroscopy detection of polybrominated diphenylethers using a portable Raman spectrometer, TALANTA, 2013, 116, 14-17

2012
Synthesis of a beta-cyclodextrin-modified Ag film by the galvanic displacement on copper foil for SERS detection of PCBs，JOURNAL OF COLLOID AND INTERFACE SCIENCE，第365卷，第1期，122-126页，2012
Porous Copper Zinc Tin Sulfide Thin Film as Photocathode for Double Junction Photoelectrochemical Solar Cell，CHEMICAL COMMUNICATIONS，第48卷，第24期，3006-3008页，2012
A colorimetric and Surface-enhanced Raman scattering dual-signal sensor for Hg2+ based on Bismuthiol II-capped gold nanoparticles，ANALYTICA CHIMICA ACTA，第723卷，88-93页，2012
Phase Selective Synthesis of Metastable Orthorhombic Cu2ZnSnS4，JOURNAL OF MATERIALS CHEMISTRY，第22卷，第15期，7502-7506页，2012
Silver nanoparticle aggregates on copper foil for reliable quantitative SERS analysis of polycyclic aromatic hydrocarbons with a portable Raman spectrometer，ANALYST，第137卷，第17期，3995-4000页，2012
Magnetic nanoparticles and quantum dots co-loaded imprinted matrix for pentachlorophenol，Journal of Hazardous Materials，第63卷，第70期，237– 238页，2012
In situ fabrication of single-crystalline porous ZnO nanoplates on zinc foil to support silver nanoparticles as a stable SERS substrate，CrystEngComm，第14卷，,第18期,6023–6028页，2012
2011
Porous SnO2 nanospheres as sensitive gas sensors for volatile organic compounds detection Nanoscale,2011, 卷: 3 期: 4 页: 1646-1652
InO2 microbundles constructed with well-aligned single-crystalline nanorods: F127-directed self-assembly and enhanced gas sensing performance; Journal of Colloid and Interface Science,Volume 354,Issue 1,2011,Pages 89-93
Facile synthesis of N-acetyl-l-cysteine capped ZnS quantum dots as aneco-friendly fluorescence sensor for Hg2+ ;Talanta ,85 , 1738– 1743,2011
Theoretical evaluation of the configurations and Raman spectra of 209polychlorinated biphenyl congeners;Chemosphere ,85 , 412–417,2011
Silver nanoplates prepared by modified galvanic displacement for surface-enhanced Raman spectroscopy;Nanoscale, 3, 2134;2011
2010
Determination of Pentachlorophenol at Carbon Nanotubes Modified Electrode Incorporated with beta-Cyclodextrin 来源出版物: JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY 卷: 10 期: 11 特刊: Sp. Iss. SI 页: 7654-7657 出版年: NOV 2010
Aqueous Synthesis of Highly Luminescent Amorphous CdSe Quantum Dots at Low Temperature 来源出版物: CHEMISTRY LETTERS 卷: 39 期: 9 页: 942-943 出版年: SEP 5 2010
Ethanol-thermal synthesis of Cd1-xZnxS nanoparticles with enhanced photodegradation of 4-chlorophenol 来源出版物: MATERIALS RESEARCH BULLETIN 卷: 45 期: 10 页: 1396-1400 出版年: OCT 2010
Morphology-Dependent Gas-Sensing Properties of ZnO Nanostructures for Chlorophenol来源出版物: CHEMISTRY-AN ASIAN JOURNAL 卷: 5期: 8 页: 1854-1859 出版年:2010
In2O3 Nanofibers and Nanoribbons: Preparation by Electrospinning and Their Formaldehyde Gas-Sensing Properties来源出版物: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 期: 21 页: 3348-3353 出版年: JUL 2010
Band-gap tunable (Cu2Sn)(x/3)Zn1-xS nanoparticles for solar cells.来源出版物: CHEMICAL COMMUNICATIONS 卷: 46 期: 31 页: 5749-5751 出版年:2010
One-pot Microwave Assisted Synthesis of Homogeneously Alloyed CdSexTe1-x Nanocrystals with Tunable Photoluminescence 来源出版物: MATERIALS LETTERS 卷: 64 期: 16 页: 1843-1845 出版年: AUG 31 2010
One-Pot Green Synthesis and Bioapplication of l-Arginine-Capped Superparamagnetic Fe3O4 Nanoparticles .NANOSCALE RESEARCH LETTERS 5 .2 .302-307 .:FEB 2010
Monodispersed cation-disordered cubic AgInS2 nanocrystals with enhanced fluorescence .APPLIED PHYSICS LETTERS 卷: 96 期: 1 文献编号: 013104 . JAN 4 2010
2009
Dmitri Golberg Synthesis of metal-semiconductor heterojunctions inside carbon nanotubes JOURNAL OF MATERIALS CHEMISTRY 2009, 19, 4414-4420
Catanionic-surfactant-controlled morphosynthesis and gas-sensing properties of corundum-type In2O3,NANOTECHNOLOGY 2009, 20, 285501
Synthesis of Starch-Stabilized Ag Nanoparticles and Hg2+ Recognition in Aqueous Media, Nanoscale Research Letters
One-Dimensional CdS/alpha-Fe2O3 and CdS/Fe3O4 Heterostructures: Epitaxial and Nonepitaxial Growth and Photocatalytic Activity Journal of Physical Chemistry C, 2009;113(32):14119-14125
Synthesis, Optical Properties, and Photocatalytic Activity of One-Dimensional CdS@ZnS Core-Shell Nanocomposites, Nanoscale Research Letters 2009,4, 558-564
Electroless Plating of Nickel Nanoparticles on CdS Nanowires, Eur. J. Inorg. Chem. 2009, 897–902
One-Pot Synthesis of Highly Luminescent CdTe Quantum Dots by Microwave Irradiation Reduction and Their Hg2+-Sensitive Properties, Nano Research 2009, 2, 67-76
2008
Fabrication and Gas-Sensing Properties of Porous ZnO Nanoplates, Advanced Materials 2008, 20, 4547–4551
Ga-Doped ZnS Nanowires as Precursors for ZnO/ZnGa2O4 Nanotubes, Adv. Mater. 2008, 20, 810–814
Unconventional Ribbon-Shaped Ga2O3 Tubes with Mobile Sn Nanowire Fillings, ACS Nano 2008, 2, 107–112.
Synthesis, Structure, and Multiply Enhanced Field-Emission Properties of Branched ZnS Nanotube-In Nanowire Core-Shell Heterostructures, ACS Nano 2008, 2, 1015–1021.
2007
Mg3N2-Ga: Nanoscale Semiconductor–Liquid Metal Heterojunctions inside Graphitic Carbon Nanotubes, Adv. Mater. 2007, 19, 1342–1346
High-Yield Synthesis of Rhombohedral BN Triangular Nanoplates, Advanced Materials 2007, 19, 2141-2144.
2006
Hollow and Polygonous Microtubes of Mono-Crystalline Indium Germanate. Angewandte Chemie International Edition 2006, 2, 228-231  
Fabrication of ZnO nanoplate-nanorod junctions. Small 2006, 2, 62-65.
Nanofabrication on ZnO nanowires, Applied Physics Letters 2006, 89, 243111.
Carbon Nanotubes as Nanoreactors for Fabrication of Single-Crystalline Mg3N2 Nanowires, Nano Letters . 2006, 6，1136-140
Dmitri Golberg Twinning in ultrathin silicon nanowires. International Journal of Materials Research-Zeitschrift für Metallkunde, 2006, 513-516 (invited paper in the special issue for Professor Aldinger).
Silica fibers with triangular cross sections, Advanced Materials, 2006, 18, 1852.
Tapered carbon nanotubes from activated carbon powders,Advanced Materials, 2006, 18, 197-200
2005
Fabrication of Metal–Semiconductor Nanowire Heterojunctions, Angewandte Chemie International Edition 2005, 44, 2140-2144
Single-Catalyst Confined Growth of ZnS/Si Composite Nanowires,Advanced Materials 2005, 17, 225-230.
Biomimetic Formation of Hydroxyapatite Nanorods by a Single-Crystal-to-Single-Crystal Transformation, Advanced Functional Materials 2005, 15, 2005-2010
Unconventional Gallium Oxide Nanowires, Small 2005, 1, 883-888
Liquid Gallium Columns Sheathed with Carbon: Bulk Synthesis and Manipulation, Journal of the Physical Chemistry B 2005, 109, 11580-11584.
Synthesis and microstructure of Cd4SiS6/Si composite nanowires, Journal of Electron Microscopy, 2005, 54, 485-491 (invited paper in memory of the late Professor John M. Cowley)
Uniform and high-quality submicrometer tubes of GaS layered crystals,  Applied Physics Letters 2005, 87, 153112.
A Liquid-Ga-Filled Carbon Nanotube: A Miniaturized Temperature Sensor and Electrical Switch，Small 2005, 1, 1088-1093
Single-crystalline nanotubes of IIB-VI semiconductors，Applied Physics Letters 2005, 87, 113107.
Fabrication of Silica-Shielded Ga-ZnS metal-Semiconductor Nanowire heterojunctions，Advanced Materials 2005, 17, 1964-1969
A ssembled Highly Faceted Wurtzite-Type ZnS Single-Crystalline Nanotubes with Hexagonal Cross-Sections， Advanced Materials 2005, 17 1972-1977
Growth of wurtzite ZnS micrometer-sized diskettes and nanoribbon arrays with improved luminescence，Advanced Functional Materials 2005, 15, 757-762
Self-assembly of SiO2 nanowires and Si microwires into hierarchical heterostructures on a large scale Advanced Materials 2005, 17, 971-975.
Single-crystalline, submicrometer-sized ZnSe tubes,Advanced Materials 2005, 17, 975-979
2004
Synthesis and field-emission properties of Ga2O3-C nanocables,Chemistry of Materials 2004, 16, 5158-5161.
Bulk Synthesis of Single-Crystalline Magnesium Oxide Nanotubes, Inorganic Chemistry 2004, 43, 2462-2464.
Fabrication of ZnS/SiC nanocables, SiC-shelled ZnS nanoribbons (and sheets), and SiC nanotubes (and tubes), Applied Physics Letters 2004, 85, 2932-2934.
Si/ZnS and Si/ZnSe core/shell nanocrystal structures, Applied Physics Letters2004, 85, 3593-3595.
Sn-filled single-crystalline Wurtzite-type ZnS nanotubes, Angewandte Chemie International Edition 2004, 43, 4606-4609.
Growth of single-crystalline cubic GaN nanotubes with rectangular cross sections, Advanced Materials 2004, 16, 1465-1468.
Unusual freezing and melting of gallium encapsulated in carbon nanotubes, Physical Review Letters 2004, 93, 095504-1-4
High resolution P-31 NMR study of octacalcium phosphate,Solid State Nuclear Magnetic Resonance 2004, 26, 99-104.
The first template-free growth of crystalline silicon microtubes,Advanced Functional Materials 2004, 16, 610-614.
Growth and field-emission properties of crystalline, thin-walled carbon microtubes, Advanced Materials 2004, 16, 153-156.
Two-dimensional extremely thin single-crystalline alpha-Si3N4microribbons, Applied Physics Letters 2004, 84, 804-806.
Synthesis of crystalline silicon tubular nanostructures with ZnS nanowires as removable templates, Angewandte Chemie International Edition 2004, 43, 63-66.
2003年
Biomimetic formation of porous single-crystalline CaCO3 via nanocrystal aggregation,Advanced Materials 2003, 15, 621-623.
Epitaxial heterostructures: Side-to-side Si-ZnS, Si-ZnSe biaxial nanowires, and sandwichlike ZnS-Si-ZnS triaxial nanowires, Journal of the American Chemical Society 2003, 125, 11306-11313.
Two-dimensional micrometer-sized single-crystalline ZnO thin nanosheets, Applied Physics Letters 2003, 83, 4414-4416.


【科研项目】
1）国家自然科学基金 ；2015
2)  国家科技部重大研究计划 “973”项目课题；2014
4）国家自然科学基金面上项目；2010-2012
5）国家自然科学基金重大研究计划；2011-2013
6）国家自然科学基金；2011-2013
7）山东省自然科学基金杰出青年项目；2011-2013
8）山东大学自主创新基金-杰出青年培育项目；2010-2012
【科研成果】
【所获专利】
一种氧化铟纳米线聚集体的制备方法(200710114642.4)
一维CdS/TiO2复合半导体光催化纳米材料及其制备方法(200710116037.0)
片状多孔结构的ZnO纳米粉体的制备方法(200710114004.2)
一维CdS-Ni 半导体-磁性功能复合纳米材料及其制备方法(200710114838.3)
SiO2/TiO2空心复合结构材料及其制备方法与应用（200710116036.6）
一种超顺磁四氧化三铁纳米粒子的制备方法（200910015366.5）
Ca-Bi-O系可见光光催化材料及其制备方法(200910016262.6)
一种以表面覆盖银纳米结构的铜粉为填料的导电浆料的制备方法(201010197864.9)
一种在铜材料上覆盖银纳米片的方法（201010115658.9）
可图案化环境催化材料及其浆料的制备（201210278777.6）
一种水相合成铜锌锡硒纳米颗粒的制备方法(201110094002.8)
可调禁带宽度的Cu-Sn-Zn-S半导体材料及其制备方法(201010121968.1)
【联合培养情况】
与美国、日本、澳大利亚等多个研究小组保持着长期的合作关系，并聘请了美国加州大学的Yadong Yin教授、王敦伟教授，日本的Yoshio Bando教授等人为本实验室的合作指导教师，学生可以根据实际情况前往合作研究、联合培养或者继续深造。