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段伟良，陕西师范大学教授。2007年于日本京都大学获得博士学位后，2008年在中科院上海有机所独立开展研究工作，共主持3项国家自然科学基金面上项目，1项青年基金，参与973项目手性催化的重要科学基础。入选陕西省“百人计划”，2015年获The Distinguished Lectureship Award from Chemical Society of Japan，2017年获 Thieme Chemistry Journals Award。研究兴趣着重在不对称催化合成手性膦化合物方向和过渡金属催化碳氢键活化方向上。发展了一种钳形钯催化剂，实现了首例二芳基膦氢对不饱和烯酮及其他各种缺电子烯烃的高对映选择性1，4加成反应。所得各种高光学活性的手性膦化合物可被衍生化作为手性膦配体在不对称催化反应中进一步应用。在碳氢键活化反应方面，发展了双齿单负离子含氮配体，能实现无导向基团芳烃的碳氢键活化反应，以及发展了利用手性磷酰胺，磷酸控制不对称碳氢键活化反应的立体选择性的策略。自独立工作以来，以通讯作者在包括J. Am. Chem. Soc.; Angew. Chem. Int. Ed.; Chem. Commun.; Org. Lett.等国际期刊上发表多篇研究论文。
段伟良
职 称：教授（博士生导师）
毕业学校：日本京都大学
电 话：
电子邮箱：wlduan@snnu.edu.cn
研究方向：碳氢键活化；不对称催化
独立发表文章目录
18. Lin, Z.-Q.; Wang, W.-Z.; Yan, S.-B.; Duan, W.-L.*. Palladium-Catalyzed Enantioselective C–H Arylation for the Synthesis of P-Stereogenic Compounds. Angew. Chem. Int. Ed. 2015, 54, 6265.
17. Yan,S.-B.; Zhang, S.; Duan, W.-L.* Palladium-Catalyzed Asymmetric Arylation of C(sp3)–H Bonds of Aliphatic Amides: Controlling Enantioselectivity Using Chiral Phosphoric Amides/Acids. Org. Lett. 2015, 17, 2458.
16. Ying, C.-H.; Duan, W.-L.*Palladium-Catalyzed Direct C–H Allyation of Arenes without Directing Groups, Org. Chem. Front. 2014, 1, 546.
15. Li, C.; Li, W.-X.; Xu, S.; Duan, W.-L.* Palladium-Catalyzed 1,4-Addition of Secondary AlkylphenylPhosphines to α,β-Unsaturated Carbonyl Compounds for the Synthesis of Phosphorus- and Carbon-Stereogenic Compounds. Org. Chem. Front. 2014, 1, 541.
14. Chen, Y.-R.; Duan, W.-L.* Palladium-Catalyzed Intramolecular Direct Arylation for Phosphorus Heterocycle Synthesis.Synthesis. 2014, 46, 1067.
13. Ying, C.-H.; Yan, S.-B.; Duan, W.-L.* 2-Hydroxy-1,10-phenanthroline vs 1,10-Phenanthroline: Significant Ligand Acceleration Effects in the Palladium-Catalyzed Oxidative Heck Reaction of Arenes. Org. Lett. 2014, 16, 500.
12. Huang, J.; Zhao, M.-X.; Duan, W.-L.* Palladium-Catalyzed Asymmetric 1,6-Addition of Diphenylphosphine to (4-Aryl-1,3-butadienylidene)bis(phosphonates) for the Synthesis of Chiral Phosphines. Tetrahedron: Lett. 2014, 55, 629.
11. Chen, Y.-R.; Feng, J.-J.; Duan, W.-L.* NHC–Copper-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to α,β-Unsaturated Ketones. Tetrahedron: Lett. 2014, 55, 595.
10. Lu, J.; Ye, J.; Duan, W.-L.*Palladium-Catalyzed Asymmetric 1,6-Addition of Diarylphosphines to a,ß,c,d-Unsaturated Sulfonic Esters: Controlling Regioselectivity by Rational Selection of Electron-Withdrawing Groups. Chem.Commun. 2014, 50, 698.
9. Chen, Y.-R.; Duan, W.-L.* Silver-Mediated Oxidative C–H/P–H Functionalization: An Efficient Route for the Synthesis of Benzophosphole Oxides. J. Am. Chem. Soc. 2013, 135, 16754.
8. Lu, J.; Ye, J.; Duan, W.-L.*Palladium-Catalyzed Asymmetric Addition of Diarylphosphines to α,β-Unsaturated Sulfonic Esters for the Synthesis of Chiral Phosphine Sulfonate Compounds.Org. Lett. 2013, 15, 5016.
7. Li, C.; Li, W.-X.; Xu, S.; Duan, W.-L.* Pd-Catalyzed Asymmetric Alkylation of Methylphenylphosphine withAlkyl Halides for the Synthesis of P-stereogenic Compounds. Chin. J. Org. Chem. 2013, 33, 799.
6. Du, D.; Lin, Z.-Q.; Lu, J.-Z.; Li, C.; Duan, W.-L.* Palladium-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to α,β-Unsaturated Carboxylic Esters. Asian J. Org. Chem. 2013, 2. 392.
5. Huang, M.; Li, C.; Duan, W.-L.*; Xu, S. Palladium-Catalyzed Asymmetric Addition of Diarylphosphines to N-tosylimines. Chem.Commun. 2012, 48, 11148.
4. Feng, J.-J.; Huang, M.; Lin, Z.-Q. Duan, W.-L.* Palladium-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to Nitroalkenes for the Synthesis of Chiral P,N-Compounds. Adv. Synth. Catal. 2012, 354, 3122.
3. Chen, Y.-R.; Duan, W.-L.* Palladium-Catalyzed 1,4-Addition of Diarylphosphines to α,β-Unsaturated Aldehydes. Org. Lett. 2011, 13, 5824.
2. Du, D.; Duan, W.-L.* Palladium-Catalyzed 1,4-Addition of Diarylphosphines to α,β-Unsaturated N-Acylpyrroles. Chem.Commun. 2011, 47, 11101.
1. Feng. J.-J.; Chen. X.-F.; Shi, M.; Duan, W.-L.* Palladium-Catalyzed Asymmetric Addition of Diarylphosphines to Enones toward the Synthesis of Chiral Phosphines J. Am. Chem. Soc. 2010, 132, 5562.
独立工作之前发表文章目录
17. Shintani, R.*; Park, S.; Duan, W.-L.; Hayashi, T.* Palladium-Catalyzed Asymmetric [3 + 3] Cycloaddition of Trimethylenemethane Derivatives with Nitrones.Angew. Chem., Int. Ed. 2007, 46, 5901.
16. Nakao, Y.*; Chen, J. S.; Imanaka, H.; Hiyama, T.*; Ichikawa, Y.; Duan, W.-L.; Shintani, R.; Hayashi, T*. Organo[2-(hydroxymethyl)phenyl]dimethylsilanes as Mild and Reproducible Agents for Rhodium-Catalyzed 1,4-Addition Reactions. J. Am. Chem. Soc. 2007, 129, 9137.
15. Duan, W.-L.; Imazaki, Y.; Shintani, R.*; Hayashi, T.* Asymmetric Construction of Chiral C–N Axes through Rhodium-Catalyzed 1,4-Addition. Tetrahedron 2007, 63, 8529.
14. Duan, W.-L.; Iwamura, H,; Shintani, R.*; Hayashi, T.* Chiral Phosphine–Olefin Ligands in the Rhodium-Catalyzed Asymmetric 1,4-Addition Reactions. J. Am. Chem. Soc. 2007, 129, 2130.
13. Shintani, R.; Duan, W.-L.; Park, S.; Hayashi, T.* Rhodium-Catalyzed Isomerization of Unactivated Alkynes to 1,3-Dienes. Chem. Commun. 2006, 3646.
12. Shintani, R.; Duan, W.-L.; Hayashi, T.* Rhodium-Catalyzed Asymmetric Construction of Quaternary Carbon Stereocenters: Ligand-Dependent Regiocontrol in the 1,4-Addition to Substituted Maleimides. J. Am. Chem. Soc. 2006, 128, 5628.
11. Shintani, R.; Duan, W.-L.; Okomoto, K.; Hayashi, T.* Palladium/Chiral Phosphine–Olefin Complexes: X-ray Crystallographic Analysis and the Use in Catalytic Asymmetric Allylic Alkylation. Tetrahedron: Asymmetry 2005, 16, 3400.
10. Shintani, R.; Duan, W.-L.; Nagano, T.; Okada, A.; Hayashi, T.* Chiral Phosphine–Olefin Bidentate Ligands in Asymmetric Catalysis: Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl Boronic Acids to Maleimides.Angew. Chem., Int. Ed. 2005, 44, 4611.
9. Xu, Q.; Duan, W.-L.; Lei, Z.-Y.; Zhu, Z.-B.; Shi, M.* A Novel cis-Chelated Pd(II)–NHC Complex for Catalyzing Suzuki and Heck-Type Cross-Coupling Reactions. Tetrahedron 2005, 61, 11225.
8. Shi, M.*; Duan, W.-L. Synthesis of an Axially Chiral Ir–NHC Complex Derived from BINAM. Appl. Organomet. Chem. 2005, 19, 40.
7. Shi, M.*; Duan, W.-L.; Rong, G.-B. Axially Dissymmetric N-thioacylated (S)-(-)-1,1'-Binaphthyl-2,2'-Diamine Ligands for Copper-Catalyzed Asymmetric Michael Addition of Diethylzinc to a,b-Unsaturated Ketone. Chirality 2004, 16, 642-651.
6. Shen, Y.-M.; Duan, W.-L.; Shi, M.* Chemical Fixation of Carbon Dioxide co-Catalyzed by a Combination of Schiff Bases or Phenols and Organic Bases. Eur. J. Org. Chem. 2004, 14, 3080.
5. Shi, M.*; Duan, W.-L. Synthesis of Two Novel Cobalt Complexes and Their Crystal Structures. Appl. Organomet. Chem. 2003, 17, 175.Appl. Organomet. Chem. 2005, 19, 40.
4. Duan, W-L.; Shi, M.*; Rong, G.-B. Synthesis of Novel Axially Chiral Rh-NHC Complexes Derived from BINAM and Application in the Enantioselective Hydrosilylation of Methyl Ketones. Chem. Commun. 2003, 2916.
3. Sheng, Y.-M.; Duan, W.-L.; Shi, M.* Phenol and Organic Bases Co-Catalyzed Chemical Fixation of Carbon Dioxide with Terminal Epoxides to Form Cyclic Carbonates. Adv. Synth. Catal. 2003, 345, 337.
2. Sheng, Y.-M.; Duan, W.-L.; Shi, M.* Chemical Fixation of Carbon Dioxide Catalyzed by Binaphthyldiamino Zn, Cu, Co Salen Type Complexes. J. Org. Chem. 2003, 68, 1559.
1. Shi, Min.*; Duan, W.-L.; Rong, G.-B. Axially Dissymmetric Chiral (R)-N,N′-Bis(2-hydroxy-3,5-di-tert-butyl-arylmethyl)-1,1′-binaphthalene-2,2′-diamine as Chiral Ligands in the Reaction of Diethylzinc to Aldehydes.Chin. J. Chem. 2002, 20, 1319.
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发表于 2018-4-23 16:59:52
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