河北工业大学化工学院姜艳军

daxiong

姜艳军，1980年5月生人，男，教授，博士生导师。主要从事环境友好的化工过程、生物催化与转化、生物质能源等方面的研究。河北省杰出青年基金获得者（2017年）、河北省高校百名优秀创新人才（2017年）、连云港市“高层次创新创业领军人才集聚工程”（2015年）、河北省“三三三人才工程”第三层次人选（2014年）、天津市创新人才推进计划青年科技优秀人才（2014年）、河北省首批青年拔尖人才（2013年）、天津市新长征突击手（2013年）以及2013年度中国石油和化学工业联合会科学技术奖二等奖一项（第五完成人）。
主持或完成国家自然科学基金2项、河北省杰出青年基金1项、河北省自然科学基金2项、天津市自然科学基金1项、河北省青年拔尖人才项目1项、河北省“三三三人才工程”培养经费1项、河北省高等学校科学技术研究项目（优秀青年基金）1项；作为第二主研人参与国家自然科学基金、河北省应用基础研究计划重点基础研究项目、河北省自然科学基金和天津市自然科学基金等4项。
在Chem. Soc. Rev.、 ACS Appl. Mater. Interfaces、Adv. Funct. Mater.、Chem. Commun.等期刊上发表SCI论文70余篇；申请国家发明专利6项，授权3项；在《Handbook of Biomimetics and Bioinspiration》中撰写“Biomimetic Protamine-templated Silicification”一章。
主持和参加科研项目情况
（1）国家自然科学基金面上项目（21276060），分级孔结构氧化硅整体柱固定化酶及催化制备新型凝油剂，2013.01~2016.12，78万元，主持；
（2）国家自然科学基金青年基金项目（21006020），仿生构建纳微结构多酶反应器及催化特性研究，2011.01~2013.12，19万元，主持；
（3）河北省自然科学基金杰出青年基金（B2017202056），三维有序大孔-介孔有机硅固定化脂肪酶的设计制备及构效关系，2017.1.1-2019.12.31，主持；
（4）河北省高层次人才资助项目（A2016002027），三维有序大孔-介孔材料固定化酶反应器的设计制备及催化特性，2017.1.1-2018.12.31，主持；
（5）河北省自然科学基金面上项目（B2015202082），新型介孔氧化硅固定化腈水合酶的制备与催化性能，2015.01~2017.12，6万元，主持；
（6）河北省自然科学基金青年基金项目（B2010000035），仿生制备纳米级磁性复合粒子及其用于固定化酶的研究，2010.01~2012.12，3万元，主持；
（7）天津市自然科学基金一般项目（16JCYBJC19800），鞣酸介导的介孔氧化硅固定脂肪酶及催化合成碳酸甘油酯，2016.04~2019.03，10万元，主持；
（8）河北省高等学校科学技术研究项目（YQ2013025），新型固定化脂肪酶的构建及催化制备凝油剂，2014.01~2016.12，6万元，主持；
（9）河北省首批青年拔尖人才项目，60万元，主持；
（10）生化工程国家重点实验室开放基金，Fe3O4/SiO2复合粒子的仿生制备及固定化漆酶的研究，2010.10-2012.09，5万元，主持；
（11）连云港市“555工程”第三批高层次创业创新人才项目，2016.01-2018.12，30万元，主持；
（12）国家自然科学基金面上项目（21276062），球化交联酶聚集体-氧化硅杂化生物催化剂的可控制备及催化特性，2013.01~2016.12，78万元，参加，排名第二；
（13）河北省应用基础研究计划重点基础研究项目（11965150D），多酶抗生物粘泥涂层的仿生构建和性能研究，2010.01-2013.12，20万元，参加，排名第二；
（14）天津市自然科学基金一般项目（13JCYBJC18500），腈水合酶交联酶聚集体-氧化硅催化剂的制备与催化性能，2013.04-2016.03，10万元，参加，排名第二；
（15）河北省自然科学基金面上项目（B2011202095），氧化石墨烯定向固定化葡萄糖氧化酶的研究，2011.1-2013.12，5万元，参加，排名第二。
发表论文情况
2017
75. Junkai Gao, Hao Lei, Zhi Han, Qian Shi, Yan Chen*, Yanjun Jiang*. Dopamine functionalized tannic-acid-templated mesoporous silica nanoparticles as a new sorbent for the efficient removal of Cu2+ from aqueous solution, Scientific Reports, 2017, 7:45215.
74. Li Ma, Liya Zhou, Yanjun Jiang*, Ying He, Lihui Wang, Jing Gao*. Lipase-based static emulsions as efficient biocatalysts for biodiesel production，Journal of Chemical Technology and Biotechnology, 2017.
73. Liya Zhou, Haixia Mou, Jing Gao*, Li Ma, Ying He, Yanjun Jiang*. Preparation of cross-linked enzyme aggregates of nitrile hydratase ES-NHT-118 from E. coli by macromolecular cross-linking agent, Chinese Journal of Chemical Engineering, 2016.
72. Junkai Gao, Yanjun Jiang, Jinshu Lu, Zhi Han, Jiajia Deng, Yan Chen. Dopamine-functionalized mesoporous onion-like silica as a new matrix for immobilization of lipase Candida sp. 99-125, Scientific Reports, 2017, 7: 4035.
71. Jing Gao, Yun Wang, Yingjie Du, Liya Zhou, Ying He, Li Ma, Luyan Yin, Weixi Kong, Yanjun Jiang. Construction of biocatalytic colloidosome using lipase-containing dendritic mesoporous silica nanospheres for enhanced enzyme catalysis, Chemical Engineering Journal, 2017, 317: 175-186.
70. Yanjun Jiang, Wenya Sun, Yaping Wang, Lihui Wang, Liya Zhou, Jing Gao, Ying He, Li Ma, Xu Zhang. Protein-based inverse opals: a novel support for enzyme immobilization, Enzyme and Microbial Technology, 2017, 96: 42-46.
69. Jing Gao, Weixi Kong, Liya Zhou, Ying He, Li Ma, Yun Wang, Luyan Yin, Yanjun Jiang*. Monodisperse core-shell magnetic organosilica nanoflowers with radial wrinkle for lipase immobilization, Chemical Engineering Journal, 2017, 309: 70-79.
68. Yanjun Jiang, Liteng Ma, Liya Zhou, Li Ma, Ying He, Xu Zhang, Jing Gao. Structured interlocked-microcapsules: a novel scaffold for enzyme immobilization, Catalysis Communications, 2017, 88: 35-38.
67. Jing Gao, Hao Yu, Liya Zhou, Ying He, Li Ma, Yanjun Jiang*. Formation of cross-linked nitrile hydratase aggregates in the pores of tannic-acid-templated magnetic mesoporous silica: characterization and catalytic application，Biochemical Engineering Journal, 2017, 117: 92-101.
2016
66. Jing Gao, Luyan Yin, Kai Feng, Liya Zhou, Li Ma, Ying He, Lihui Wang, Yanjun Jiang*. Lipase immobilization through the combination of bioimprinting and cross-linked protein-coated microcrystal technology for biodiesel production, Industrial & Engineering Chemistry Research, 2016, 55 (42): 11037-11043.
65. Liya Zhou, Wei Tang, Yanjun Jiang,* Li Ma, Ying He, Jing Gao*. Magnetic combined cross-linked enzyme aggregates of horseradish peroxidase and glucose oxidase: an efficient biocatalyst for dye decolourization, RSC Advances, 2016, 6(93): 90061-90068.
64. Yanjun Jiang, Pengju Zheng, Liya Zhou, Weixi Kong, Jing Gao, Jinxia Wang, Jinyan Gu, Xu Zhang, Xiaomei Wang. Immobilization of lipase in hierarchically ordered macroporous/mesoporous silica with improved catalytic performance, Journal of Molecular Catalysis B: Enzymatic, 2016, 130: 96-103.
63. Yanjun Jiang, Pengju Zheng, Dan Li, Liya Zhou, Lei Tian, Jinxia Wang, Biwei Yang, Xiaomei Wang, Xu Zhang, Jing Gao. Enzyme-containing silica inverse opals prepared by using water-soluble colloidal crystal templates: Characterization and application, Biochemical Engineering Journal , 2016, 112: 123-129.
62. Yanjun Jiang, Wenya Sun, Liya Zhou, Li Ma, Ying He, Jing Gao. Improved performance of lipase immobilized on tannic acid-templated mesoporous silica nanoparticles, Applied Biochemistry and Biotechnology, 2016, 179(7): 1155-1169.
2015
61. Jing Gao, Kai Feng, Hongwu Li, Yanjun Jiang*, Liya Zhou. Immobilized lipase on porous ceramic monoliths for the production of sugar-derived oil gelling agent, RSC Advances., 2015, 5(84): 68601-68609.
60. Hongwu Wang, Yanjun Jiang∗, Liya Zhou, Jing Gao∗. Bienzyme system immobilized in biomimetic silica for application in antifouling coatings, Chinese Journal of Chemical Engineering, 2015, 23(8): 1384-1388.
59. Jiafu Shi#, Yanjun Jiang# (co-first author), Zhongyi Jiang∗, Xueyan Wang, Xiaoli Wang, Shaohua Zhang, Pingping Han, Chen Yang. Enzymatic conversion of carbon dioxide, Chemical Society Reviews, 2015, 44(17): 5981-6000.
58. Yang Li, Yanjun Jiang, Jing Gao*. Heterogeneous catalyst derived from waste shells for biodiesel production, Energy Sources Part A: Recovery, Utilization, and Environmental Effects, 2015, 37(6): 598-605.
57. Yuan Shang, Yanjun Jiang, Jing Gao*. One-step synthesis of peanut shell-derived solid acid for biodiesel production, Energy Sources Part A: Recovery, Utilization, and Environmental Effects, 2015, 37(10): 1039-1045.
56. Xiaoyu Yan, Yanjun Jiang, Songping Zhang, Jing Gao∗, Yufei Zhang∗. Dual-functional OPH-immobilized polyamide nanofibrous membrane for effective organophosphorus toxic agents protection, Biochemical Engineering Journal, 2015, 98: 47-55.
55. Jing Gao, Qi Wang, Yanjun Jiang*, Junkai Gao, Zhihua Liu, liya Zhou, Yufei Zhang. Formation of nitrile hydratase CLEAs in mesoporous onion-like silica: preparation and catalytic properties, Industrial & Engineering Chemistry Research, 2015, 54 (1): 83-90.
54. Yanjun Jiang, Yaping Wang, Hua Wang, Liya Zhou, Jing Gao*, Yufei Zhang, Xu Zhang*, Xiaomei Wang, Jian Li. Facile immobilization of enzyme on three dimensionally ordered macroporous silica via a biomimetic coating, New Journal of Chemistry, 2015, 39(2): 978-984.
53. Liya Zhou, Yanjun Jiang*, Li Ma, Ying He, Jing Gao*. Immobilization of glucose oxidase on polydopamine-functionalized graphene oxide, Applied Biochemistry and Biotechnology, 2015, 175(2): 1007-1017.
2014
52. Jing Gao, Dan Li, Yanjun Jiang*, Li Ma, Liya Zhou, Ying He. Pickering emulsion stabilized by immobilized bienzyme nanoparticles: a novel and robust system for enzymatic purification of isomaltooligosaccharide, Industrial & Engineering Chemistry Research, 2014, 53 (47): 18163-18169.
51. Panpan Luan, Yanjun Jiang, Songping Zhang, Jing Gao, Zhiguo Su, Guanghui Ma, Yufei Zhang*. Chitosan-mediated formation of biomimetic silica nanoparticles: an effective method for manganese peroxidase immobilization and stabilization, Journal of Bioscience and Bioengineering, 2014, 118(5): 575-582.
50. Bin Zhao, Xinlong Liu, Yanjun Jiang*, Liya Zhou, Ying He, Jing Gao*. Immobilized lipase from Candida sp. 99-125 on hydrophobic silicate: characterization and applications, Applied Biochemistry and Biotechnology, 2014, 173(7): 1802-1814.
49. Jiafu Shi#, Yanjun Jiang# (co-first author), Xiaoli Wang, Hong Wu, Dong Yang, Fusheng Pan, Yanlei Su, Zhongyi Jiang, Zhongyi Jiang*. Design and synthesis of organic-inorganic hybrid capsules for biotechnological applications, Chemical Society Reviews, 2014, 43(15): 5192-5210. (review article)
48. Yanjun Jiang, Cuicui Cui, Liya Zhou, Ying He, Jing Gao*. Preparation and characterization of porous horseradish peroxidase microspheres for the removal of phenolic compound and dye, Industrial & Engineering Chemistry Research, 2014, 53 (18): 7591-7597.
47. Yanjun Jiang, Cuicui Cui, Yan Huang, Xu Zhang*, Jing Gao*. Enzyme-based inverse opal: a facile and promising platform for fabrication of biocatalysts, Chemical Communications, 2014, 50 (41): 5490-5493.
46. Zhenwei Tong#, Yanjun Jiang#, Dong Yang, Jiafu Shi, Shaohua Zhang, Chuang Liu, Zhongyi Jiang*. Biomimetic and bioinspired synthesis of titania and titania-based materials, RSC Advances, 2014, 4(24): 12388-12403. (review article)
45. Yanjun Jiang, Lianlian Shi, Yan Huang, Jing Gao,* Xu Zhang,* Liya Zhou. Preparation of robust biocatalyst based on cross-linked enzyme aggregates entrapped in three-dimensionally ordered macroporous silica, 2014, ACS Applied Materials & Interfaces, 2014, 6 (4): 2622-2628.
44. Yanjun Jiang, Qi Wang, Ying He, Liya Zhou, Jing Gao. Co-aggregation of laccase and nature egg white: a simple method to prepare stable and recyclable biocatalyst, Applied Biochemistry and Biotechnology, 2014, 172(5): 2496-2506.
43. Yanjun Jiang, Xinlong Liu, Yafei Chen, Liya Zhou, Ying He, Li Ma, Jing Gao. Pickering emulsion stabilized by lipase-containing periodic mesoporous organosilica particles: a robust biocatalyst system for biodiesel production, Bioresource Technology, 2014, 153: 278-283.
42. Yanjun Jiang, Wei Tang, Jing Gao*, Liya Zhou, Ying He. Immobilization of horseradish peroxidase in phospholipid-templatedtitania and its applications in phenolic compounds and dye removal, Enzyme and Microbial Technology, 2014, 55: 1-6.
2013
41. Jing Gao, Lianlian Shi, Yanjun Jiang*, Liya Zhou, Ying He. Formation of lipase Candida sp. 99-125 CLEAs in mesoporous silica: characterization and catalytic properties, Catalysis Science & Technology, 2013, 3(12): 3353-3359.
40. Liya Zhou, Cui Wang, Yanjun Jiang, Jing Gao*. Immobilization of papain in biosilica matrix and its catalytic property, Chinese Journal of Chemical Engineering, 2013, 21(6): 670-675.
39. Yanjun Jiang, Dan Li, Yang Li, Jing Gao*, Liya Zhou, Ying He. In situ self-catalyzed reactive extraction of germinated oilseed with short-chained dialkyl carbonates for biodiesel production, Bioresource Technology, 2013, 150: 50-54.
38. Qian Xin, Yanjun Jiang*, Jing Gao*, Liya Zhou, Li Ma, Ying He, Fei Jia. Biomimetic preparation of organic-inorganic composite microcapsules for glucose oxidase immobilization, Chinese Journal of Catalysis, 2013, 34 (8): 1627-1633.
37. Hua Wang, Yanjun Jiang*, Liya Zhou, Ying He, Jing Gao*. Immobilization of penicillin G acylase on macrocellular heterogeneous silica-based monoliths, Journal of Molecular Catalysis B: Enzymatic, 2013, 96: 1-5.
36. Yanan Zhu, Yanjun Jiang*, Jing Gao*, Liya Zhou, Ying He, Fei Jia. Immobilization of glucose oxidase in liposome-templated biomimetic silica particles, Chinese Journal of Catalysis, 2013, 34(4): 741-750.
2012
35. Xiaobing Zheng, Qi Wang, Yanjun Jiang*, Jing Gao*. Biomimetic synthesis of magnetic composite particles for laccase immobilization, Industrial & Engineering Chemistry Research, 2012, 51(30): 10140-10146.
34. Yanjun Jiang, Hanqi Gu, Liya Zhou, Cuicui Cui, Jing Gao*. Novel in situ batch reactor with a facile catalyst separation device for biodiesel production, Industrial & Engineering Chemistry Research, 2012, 51(46): 14935-14940.
33. Liya Zhou, Yanjun Jiang, Jing Gao*, Xinqiang Zhao, Li Ma, Qianlin Zhou. Oriented immobilization of glucose oxidase on graphene oxide, Biochemical Engineering Journal, 2012, 69: 28-31.
32. Liya Zhou, Yanjun Jiang, Jing Gao*, Xinqiang Zhao, Li Ma. Graphene oxide as a matrix for the immobilization of glucose oxidase, Applied Biochemistry and Biotechnology, 2012, 168(6): 1635-1642.
31. Yanjun Jiang, Qi Wang, Wenqin Wang, Liya Zhou, Jing Gao. Preparation of immobilized lipase through combination of cross-linked enzyme aggregates and biomimetic silicification, Chinese Journal of Catalysis, 2012, 33(5): 857-862.
2011
30. 王翠, 姜艳军, 周丽亚, 高静. 纳米氧化硅固定辣根过氧化物酶处理苯酚废水, 2011, 62(7): 2026-2032.
29. Wenqin Wang, Yanjun Jiang, Liya Zhou, Jing Gao*. Comparison of the properties of lipase immobilized onto mesoporous resins by different methods, Applied Biochemistry and Biotechnology, 2011, 164(5): 561-572.
28. Hanqi Gu, Yanjun Jiang, Liya Zhou, Jing Gao*. Reactive extraction and in situ self-catalyzed methanolysis of germinated oilseed for biodiesel production, Energy & Environmental Science, 2011, 4(4): 1337-1344.
27. Qi Wang, Liya Zhou, Yanjun Jiang, Jing Gao*. Improved stability of the carbon nanotubes-enzyme bioconjugates by biomimetic silicification, Enzyme and Microbial Technology, 2011, 49(1): 11-16.
26. Lei Zhang, Jiafu Shi, Zhongyi Jiang, Yanjun Jiang, Shizhang Qiao, Jian Li, Rui Wang, Ruijie Meng, Yuanyuan Zhu, Yang Zheng. Bioinspired preparation of polydopamine microcapsule for multienzyme system construction, Green Chemistry, 2011, 13(2): 300-306.
25. Lei Zhang, Jiafu Shi, Zhongyi Jiang, Yanjun Jiang, Ruijie Meng, Yuanyuan Zhu，Yanpeng Liang, Yang Zheng. Facile preparation of robust microcapsules by manipulating metal-coordination interaction between biomineral layer and bioadhesive layer, ACS Applied Materials & Interfaces, 2011, 3(2): 597-605.
2010
24. Jiangna Sun, Yanjun Jiang, Liya Zhou, Jing Gao. Immobilization of Candida antarctica lipase B by adsorption in organic medium, New Biotechnology, 2010, 27(1): 53-58.
23. Jiangna Sun, Yanjun Jiang, Liya Zhou, Jing Gao. Optimization of immobilized lipase-catalyzed synthesis of ethyl lactate and kinetic study, Biocatalysis Biotransformation, 2010, 28(4): 279-287.
22. Weitao Liu, Yanjun Jiang, Jing Gao*, Li Ma, Liya Zhou. Lipase-catalyzed synthesis of biodiesel from crude cottonseed oil, Power and Energy Engineering Conference (APPEEC), 2010 Asia-Pacific. IEEE, 2010: 1-4.
21.Yingying Wang, Yanjun Jiang, Liya Zhou, Jing Gao*. Enzymatic esterification of ammonium lactate with ethanol in organic solvent: kinetics study, Bioinformatics and Biomedical Engineering (iCBBE), 2010 4th International Conference on IEEE, 2010: 1-4.
20. Lei Zhang, Yanlei Su, Yang Zheng, Zhongyi Jiang, Jiafu Shi, Yuanyuan Zhu, Yanjun Jiang. Sandwich-structured enzyme membrane reactor for efficient conversion of maltose into isomaltooligosaccharides, Bioresource Technology, 2010, 101(23): 9144-9149.
19. Jian Li, Zhongyi Jiang, Hong Wu, Lei Zhang, Lianhua Long, Yanjun Jiang. Constructing inorganic shell onto LBL microcapsule through biomimetic mineralization: a novel and facile method for fabrication of microbioreactors, Soft Matter, 2010, 6(3): 542-550.
2009
18. Yanjun Jiang, Dong Yang, Lei Zhang, Qianyun Sun, Xiaohui Sun, Jian Li, Zhongyi Jiang. Preparation of protamine-titania microcapsules through synergy between layer-by-layer assembly and biomimetic mineralization, Advanced Functional Materials, 2009, 19(1):150-156.
17. Yanjun Jiang, Qianyun Sun, Lei Zhang, Zhongyi Jiang. Capsules-in-bead scaffold: a rational architecture for spatially separated multienzyme cascade system, Journal of Materials Chemistry, 2009, 19(47): 9068-9074.
16. Yanjun Jiang, Qianyun Sun, Zhongyi Jiang*, Lei Zhang, Jian Li, Lin Li, Xiaohui Sun. The improved stability of enzyme encapsulated in biomimetic titania particles, Materials Science and Engineering: C, 2009, 29(1): 328-334.
15. Lei Zhang, Yanjun Jiang, Zhongyi Jiang, Xiaohui Sun, Jiafu Shi, Wei Cheng, Qianyun Sun. Immobilized transglucosidase in biomimetic polymer-inorganic hybrid capsules for efficient conversion of maltose to isomaltooligosaccharides, Biochemical Engineering Journal, 2009, 46(2): 186-192.
14. Lei Zhang, Yanjun Jiang, Zhongyi Jiang, Xiaohui Sun, Jiafu Shi, Lin Li, Jian Li. Biomimetic fabrication of hydroxyapatite-polysaccharide-formate dehydrogenase composite capsules for efficient CO2 conversion, Journal Biomaterial Science, Polymer Edition, 2009, 20(12): 1661-1674.
13. Qianyun Sun, Yanjun Jiang, Zhongyi Jiang, Lei Zhang, Jian Li, Xiaohui Sun. Green and efficient conversion of CO2 to methanol by biomimetic coimmobilization of three dehydrogenases in protamine-templatedtitania, Industrial Engineering Chemistry Research, 2009, 48(9): 4210-4215.
12. Yufei Zhang, Hong Wu, Lin Li, Jian Li, Zhongyi Jiang, Yanjun Jiang, Ying Chen. Enzymatic conversion of Baicalin into Baicalein by β-glucuronidase encapsulated in biomimetic core-shell structured hybrid capsules, Journal of Molecular Catalysis B: Enzymatic, 2009, 57(1): 130-135.
11. Jian Li, Zhongyi Jiang, Hong Wu, Lianhua Long, Yanjun Jiang, Lei Zhang. Improving the recycling and storage stability of enzyme by encapsulation in mesoporous CaCO3-alginate composite gel, Composites Science and Technology, 2009, 69(3): 539-544.
2008
10. Lei Zhang, Yanjun Jiang, Jiafu Shi, Xiaohui Sun, Jian Li, Zhongyi Jiang. Biomimetic polymer-inorganic hybrid microcapsules for yeast alcohol dehydrogenase encapsulation, Reactive and Functional Polymers, 2008, 68(11): 1507-1515.
9. Yanjun Jiang, Lei Zhang, Qianyun Sun, Yufei Zhang, Jian Li, Lin Li, Zhongyi Jiang. Biomimetic coimmobilization of three dehydrogenases in protamine-templatedtitania for conversion of CO2 to methanol, Preprint Papers-American Chemical Society, Divsion of Fuel Chemistry, 2008, 53(1): 431-432.
8. Yanjun Jiang, Lei Zhang, Lin Li, Yufei Zhang, Jian Li, Zhongyi Jiang. Efficient conversion of CO2 to formic acid by formate dehydrogenase encapsulated in biomimetic hydroxyapatite-polysaccharide microcapsules, Preprint Papers-American Chemical Society, Divsion of Fuel Chemistry, 2008, 53(1): 440-441.
7. Yanjun Jiang, Dong Yang, Lei Zhang, Lin Li, Qianyun Sun, Yufei Zhang, Jian Li, Zhongyi Jiang. Biomimetic synthesis of titania nanoparticles induced by protamine, Dalton Transactions, 2008, (31): 4165-4171.
6. Yanjun Jiang, Dong Yang, Lei Zhang, Yan Jiang, Yufei Zhang, Jian Li, Zhongyi Jiang. Facile synthesis and novel application of zirconia catalyzed and templated by lysozyme, Industrial & Engineering Chemistry Research, 2008, 47(6): 1876-1882.
5. Yanjun Jiang, Lei Zhang, Dong Yang, Lin Li, Yufei Zhang, Jian Li, Zhongyi Jiang. Fabrication of polysaccharide-inorganic hybrid biocapsules with improved catalytic activity and stability, Industrial & Engineering Chemistry Research, 2008, 47(8): 2495-2501.
4. Yufei Zhang, Hong Wu, Jian Li, Lin Li, Yanjun Jiang, Yan Jiang, Zhongyi Jiang. Protamine-templated biomimetic hybrid capsules: efficient and stable carrier for enzyme encapsulation, Chemistry of Materials, 2008, 20(3): 1041-1048.
2007
3. Yan Jiang, Yanjun Jiang, Yufei Zhang, Jian Li, Lei Zhang, Zhongyi Jiang. Biosilica-coated κ-carrageenan microspheres for yeast alcohol dehydrogenase encapsulation, Journal of Biomaterials Science, Polymer Edition, 2007, 18(12): 1517-1526.
2. Jing Gao, Yanjun Jiang, Zhihong Huang, Liya Zhou. Evaluation of the kinetic parameters for enzymatic interesterification synthesis of L-ascorbyl lactate by response surface methodology, Applied Biochemistry and Biotechnology, 2007, 136(2): 153-164.
1. Qing Shi, Dong Yang, Yanlei Su, Jian Li, Zhongyi Jiang, Yanjun Jiang, Weikang Yuan. Covalent functionalization of multi-walled carbon nanotubes by lipase, Journal of Nanoparticle Research, 2007, 9(6): 1205-1210.

huatai

共价有机框架（COFs）是一种由有机单体通过强共价键连接制备的晶体形态有序的多孔材料，具有比表面积高、密度低、结构可调、易功能化、稳定性高的特点，在气体分离储存、催化和环境修复等领域受到了广泛关注。COFs的形貌结构对其应用有着显著影响，中空球形COFs因其高比表面积、较短的传质路径以及高负载能力在催化领域有着良好的应用前景。然而制备中空球形COFs通常采用硬模板或软模板法，存在制备条件不温和、流程复杂、分散性差、产量低等缺点。因而，温和条件下中空球形COFs 的可控制备仍是一个巨大挑战。

         河北工业大学刘冠华副教授、姜艳军教授等提出了一种简单的温和条件下可控合成单分散中空球形COFs（H-COF-OMe）的方法。通过时间依赖性实验证实了COFs通过由内向外的Oswald ripening实现初始实心结构向空心转化。所制备的空心球形COFs粒径均匀，具有高比表面积、高结晶度和高化学/机械/热稳定性。此外，用类似方法合成了不同单体组成的中空球形COFs，证明了该合成策略的普适性。中空球形COFs固定化酶相较于热溶剂法制备的堆叠结构COFs固定化脂肪酶（BCL@H-COF-OMe）具有更高的活性。用于1-苯乙醇的动力学拆分，产率接近理值，ee>99%。此外，所获得的固定化酶展现了高的热稳定性、极性有机溶剂耐受性和可重复使用性。