湘潭大学化工学院刘平乐

huyouren

导师姓名： 刘平乐
导师职称： 教授
导师电话： 0731-58298005
电子邮箱： liupingle@xtu.edu.cn
办 公 室 ： 化学工程系
个人主页： http://cpt.xtu.edu.cn/
个人简介
刘平乐，二级教授，博士，博士生导师，化工学院院长，教育部新世纪优秀人才，湖南省普通高校学科带头人，湖南省新世纪121人才，湖南省首届石油化工优秀工程师。曾在荷兰屯特大学（Twente University )、美国北卡罗莱纳州立大学（NCSU）访学， 先后主持和参与国家自科基金重点、国家自科基金以及省部级项目20余项，完成中石化总公司、中化集团等横向技术开发和转让项目10余项。获国家科技进步二等奖1项，湖南省科技进步一等奖1项，三等奖1项。湖南省第六届青年科技奖，省部级鉴定5项、获国家发明专利17项。在Ind. & Eng. Chem. Res., Chem Eng J, ChemCatChem, J Mol. Catal. A: Chem., Catal. Commun., Catal. Lett., Chin.J. of Chem.Eng.,及《化工学报》等刊物发表论文60多篇。
研究方向
（1）催化材料与催化反应工程
（2）化工新产品与新工艺的研究开发
科研项目
主持项目：
1.国家自科基金项目（2010.01-2012.12）在线反应红外技术研究新型加氢催化剂催化硝基环己烷制备环己酮肟20976148
2.国家自科基金项目（2013.01-2016.12）具有加氢和重排活性双功能催化剂构筑及催化硝基环己烷一步制备己内酰胺研究21276218
3. 国家自科基金项目（2017.01-2019.12）新型改性海泡石负载型镍基多金属催化剂构筑及催化己二腈加氢性能研究U1662127
4. 湖南省战略性新兴产业项目（2015.01-2018.12）基于海泡石催化新材料关键技术及应用2015GK1060
5. 湖南省科技厅重点项目（2011.01-2013.12）环境友好生产1,5-二氨基萘新技术2010WK2008
6. 湖南省高校科技成果产业化培育项目（2009.07-2015.06）气相催化氯化合成四氯对苯二腈技术产业化09CY007
7. 湖南省教育厅重点项目（2010.01-2012.12）在线反应红外技术研究新型加氢催化剂催化硝基环己烷制备环己酮肟09A090
8. 湖南省自科基金项目（2008.01-2010.12）硝基苯加氢合成对氨基酚新型催化剂的研制与性能评价07JJ6017
9. 湖南省教育厅优秀青年项目（2005.01-2007.12）新型纳米碳纤维载体加氢催化剂的研究与开发04B060
10. 湘潭大学博士基金项目（2004.01-2006.12）环己烷氧化反应动力学研究
11. 连云港市东金化工有限公司项目（2009.01-2010.12）乙酰甲胺磷生产工艺优化
12. 湖南比德生化科技有限公司（2012.01-2014.12）1,5- 二硝基萘加氢工艺优化
科研成果
(1)    Yang Lv, Jun Li, Sheng Feng, Pingle Liu*, Fang Hao, Wei Xiong*, He'an Luo, Multi-walled Carbon Nanotubes Supported Nickel Nanoparticles Doped with Magnesia and Copper for Adiponitrile Hydrogenation with High Activity and Chemoselectivity under Mild Conditions, Chemical Engineering Journal, 2018, 10.1016/j.cej.2018.04.031
(2)       Wei Long, Pingle Liu*, Yang Lv, Wei Xiong, Fang Hao, He’an Luo, Silica-supported Cu–Pt bimetallic catalysts for liquid-phase diethyl oxalate hydrogenation, Can. J. Chem. 2018, 96: 394–403
(3)       Yang Lv, Pingle Liu*,  Fang Hao, Wei Xiong*, He￠an Luo, High Catalytic Behavior of Activated Carbon-Supported K-Fe-Ni Based Catalysts for 1,6-Hexanedinitrile Hydrogenation under Mild Conditions, ChemSelect, 2018
(4)   Wei Long, Yang Lv, Pingle Liu*, Fang Hao, Wei Xiong, Xie Li, Haishuai Cui, He’an Luo. Different crystal form titania supported Ruthenium nanoparticles for liquid phase hydrodeo -xygenation of guaiacol, Journal of Nanoscience and Nanotechnology, 2018
(5)    Shengtao Wu, Zuqin Duan, Fang Hao*, Shaofeng Xiong, Wei Xiong, Yang Lv, Pingle Liu*, He’an Luo, Preparation of acid-activated sepiolite/Rhodamine B@SiO2 hybrid fluorescent pigments with high stability, Dyes and Pigments,2017, 137: 395-402.
(6)    Yang Lv, Fang Hao*, Pingle Liu*, Shaofeng Xiong, He’an Luo, Improved catalytic performance of acid-activated sepiolite supportednickel and potassium bimetallic catalysts for liquid phase hydrogenation of 1,6-hexanedinitrile, Journal of Molecular Catalysis A: Chemical, 2017, 426: 15–23.
(7)    Wei Long, Fang Hao, Wei Xiong, Pingle Liu*, He’an Luo. Modified sepiolite supported nickel and tungsten oxide catalysts for glycerol hydrogenolysis to 1,2-propanediol with high selectivity under mild conditions. Reaction Kinetics, Mechanisms and Catalysis, 2017,122(1): 85-100.
(8)    Yihui Hou, Pingle Liu, Qinglin Hou, Haiting Duan, Yujia Xie. Study on Removal Fluid Inclusions in Quartz Sand by Microwave Explosion, Nanoscience and Nanotechnology Letters. 2017, 9(2), 151-154.
(9)    Yang Lv, Fang Hao*, Shaofeng Xiong, Pingle Liu*, He'an Luo, Catalytic properties of Nickel/Sepiolite promoted with potassium and lanthanum in adiponitrile hydrogenation under mild conditions, RSC Advances, 2016, 6: 60933-60939.
(10)Yang Lv, Fang Hao*, Pingle Liu*,Shaofeng Xiong, He’an Luo, Liquid phase hydrogenation of adiponitrile over acidactivated sepiolite supported K–La–Ni trimetallic catalysts, Reaction Kinetics Mechanisms and Catalysis, 2016, 119: 555–568.
(11)Wei Xiong, Kai-Jun Wang, Xi-Wang Liu, Fang Hao*, Han-Yan Xiao, Ping-Le Liu*, He-An Luo, 1,5-dinitronaphthalene hydrogenation to 1,5-diaminonaphthalene over carbon nanotube supported non-noble metal catalysts under mild conditions, Applied Catalysis A: General, 2016, 514: 126-134.
(12)Yujia Xie, Fengyong Zhang, Pingle Liu*, Fang Hao, He’an Luo, Zinc Oxide Supported trans-CoD(p?Cl)PPCl-Type Metalloporphyrins Catalyst for Cyclohexane Oxidation to Cyclohexanol and Cyclohexanone with High Yield, Industrial & Engineering Chemistry Research, 2015, 54: 2425?2430.
(13)Ze Feng, Yujia Xie, Fang Hao*, Pingle Liu*, He’an Luo, Catalytic oxidation of cyclohexane to KA oil by zinc oxide supported manganese 5,10,15,20-tetrakis(4-nitrophenyl)porphyrin, Journal of Molecular Catalysis A: Chemical, 2015, 410: 221–225.
(14)Ze Feng, Yujia Xie, Fang Hao*, Pingle Liu*, He'an Luo, Catalytic oxidation of cyclohexane by substituted metalloporphyrins: experimental and molecular simulation, RSC Advances, 2015, 5: 101593–101598.
(15)Sihua Liu, Fang Hao, Pingle Liu*, He’an Luo, The influence of different preparation methods on the structure and catalytic performance of single-wall carbon nanotubes supported palladium catalysts, RSC Advances, 2015, 5: 22863-22868.
(16)Sihua Liu, Fang Hao, Pingle Liu*, He’an Luo, Hongguang Liao, Liquid phase hydrogenation of adiponitrile over amophrous nickel catalyst, Research on Chemical Intermediates, 2015, 41: 5879-5881.
(17)Pingle Liu*, Wei Xiong, Kun Huang, Fang Hao, Liangjie Wang, He’an Luo, Regioselective Nitration of Naphthalene over HZSM-5 Supported Phosphotungstic Acid, Research on Chemical Intermediates, 2014, 41: 4533-4543.
(18)Yanhua Yan, Sihua Liu, Fang Hao, Pingle Liu*, He’an Luo, Nitrocyclohexane hydrogenation to cyclohexanone oxime over mesoporous carbon supported Pd catalyst, Catalysis Communication, 2014, 50: 9-12.
(19)Fengyong Zhang, Yujia Xie, Pingle Liu*, Fang Hao, Zhengjie Yao, He’an Luo, Cycloaddition Reaction of Propylene Oxide and Carbon Dioxide Over NaX Zeolite Supported Metalloporphyrin Catalysts, Catalysis Letters, 2014, 144: 1894–1899.
(20)Hongguang Liao, Donghong Ouyang, Jin Zhang, Yanjuan Xiao, Pingle Liu*, Fang Hao, Kuiyi You, He’an Luo, Benzene Hydrogenation over Oxide-modified MCM-41 Supported Ruthenium-Lanthanum Catalyst: The Influence of Zirconia Crystal Form and Surface Hydrophilicity, Chemical Engineering Journal, 2014, 243: 207-216.
(21)Hongguang Liao, Donghong Ouyang, Jin Zhang, Yanjuan Xiao, Pingle Liu*, Fang Hao, Kuiyi You, He’an Luo, Influence of preparation conditions on the structure of MCM-41 and catalytic performance of Ru/MCM-41 in benzene hydrogenation, Journal of Chemical Research, 2014, 38(2): 90-95.
(22)Yujia Xie, Fengyong Zhang, Pingle Liu*, Fang Hao, He’an Luo, Catalytic oxidation of cyclohexane with dioxygen over boehmite supported trans-A2B2 type metalloporphyrins catalyst, Journal of Molecular Catalysis A: Chemical, 2014, 386: 95-100.
(23)Yujia Xie, Fengyong Zhang, Pingle Liu*, Fang Hao, He’an Luo, Synthesis and catalytic properties of trans-A2B2-type metalloporphyrins in cyclohexane oxidation, Canadian Journal of Chemistry, 2014, 92(1): 49-53.
(24)Zhi-Bin Hu, He-An Luo, Xiao-Guang Wang, Ming-Zhi Huang, Lu Huang, Huai-Lin Pang, Chun-Hui Mao, Hui Pei, Chao-Qun Huang, Jiong Sun, Ping-Le Liu*, Ai-Ping Liu*, Synthesis and Evaluation O-Benzyl Oxime-ether Derivatives Containing β-Methoxyacrylate Moiety for Insecticidal and Fungicidal Activities, Bulletin of the Korean Chemical Society, 2014, 35: 1073-1076.
(25)Fang Hao, Pingle Liu*, Kuiyi You, He’an Luo*, Cyclohexane Nitrosation to ε-Caprolactam with High Selectivity over HY Supported Transition Metals and Phosphotungstic Acid Catalysts, Materials Research Innovation, 2014, 18: 321-326.
(26)Pingle Liu*, Hai-Ke Zhang, Si-Hua Liu, Zheng-Jie Yao, Fang Hao*, Hong-Guang Liao, Kui-Yi You, He-An Luo, Influence of the Support on the Catalytic Performance of Supported Palladium Catalysts in Nitrocyclohexane Hydrogenation to Cyclohexanone Oxime with High Selectivity, ChemCatChem, 2013, 5: 2932-2938.
(27)Hongguang Liao, Sihua Liu, Fang Hao, Pingle Liu*, Kuiyi You, Dandan Liu, He’an Luo, Liquid phase hydrogenation of adiponitrile to 6-aminocapronitrile and hexamethylenediamine over potassium doped Ni/ɑ-Al2O3 catalyst, Reaction Kinetics Mechanisms and Catalysis, 2013, 109: 475-488.
(28)Hongguang Liao, Jing Zhang, Pingle Liu*, Fang Hao, Kuiyi You, He’an Luo, Hydrophilicity Modification of MCM-41 With Zirconia and Supported Ruthenium-Lanthanum for Benzene Hydrogenation to Cyclohexene, Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2013, 43: 1–6.
(29)Pingle Liu*, Haike Zhang, Sihua Liu,Zhengjie Yao, Fang Hao, Kuiyi You, He’an Luo, Nitrocyclohexane hydrogenation to e-caprolactam over Pd/C and 2,4,6-trichloro-[1,3,5]-triazine in N,N-dimethylformamide, Reaction Kinetics Mechanisms and Catalysis, 2012, 107: 383–391.
(30)Fang Hao, Jun Zhong, Ping-Le Liu*, Kui-Yi You, He-An Luo, Amorphous SiO2-Al2O3 supported Co3O4 and its catalytic properties in cyclohexane nitration to caprolactam, Journal of Molecular Catalysis A: Chemical, 2012, 363-364: 41-48.
(31)Fang Hao, Jun Zhong, Ping-Le Liu*, Kui-Yi You, Chao Wei, He’an Luo, One-Step Cyclohexane Nitrosation to -Caprolactam over Metal Substituted AlPO-5, Chinese Journal of Catalysis, 2012, 33: 670-676.
(32)Hong-Guang Liao, Yan-Juan Xiao , Hai-Ke Zhang, Ping-Le Liu*, Kui-Yi You, Chao Wei, He'an Luo, Hydrogenation of nitrocyclohexane to cyclohexanone oxime over Pd/CNT catalyst under mild conditions, Catalysis Communication, 2012, 19: 80-84.
(33)Fang Hao, Jun Zhong, Pingle Liu*, Kuiyi You, He’an Luo, Preparation of mesoporous SiO2-Al2O3 supported Co or Mn catalysts and their catalytic properties in cyclohexane nitrosation to caprolactam, Journal of Molecular Catalysis A: Chemical, 2011, 351: 210-216.
(34)Pingle Liu*, Yaohua Hu, Min Ni, Kuiyi You, He’an Luo, Liquid phase hydrogenation of nitrobenzene to para-aminophenol over Pt/ZrO2 catalyst and SO42-/ZrO2-Al2O3 solid acid, Catalysis Letters, 2010, 140: 65-68.
(35)Pingle Liu*, Huan Xie, Kuiyi You, Fang Hao, Xiaofeng Li, He’an Luo*, Preparation of SiO2-Al2O3 and Its Supported Co3O4 Catalysts for Nitrosation of Cyclohexane, Catalysis Letters, 2010, 136: 150-154.
(36)Huajie Liu, Kuiyi You, Pingle Liu*, He’an Luo, Hyperplane intercept vector calibration method in grey analytical systems, Analytical Sciences, 2010, 26: 613-617.
(37)Huajie Liu, Pingle Liu*, Kuiyi You and He’an Luo, Studies of Liquid-phase Cyclohexanone Ammoximation over a Titanium Silicate Sieves using online ATR-FTIR Spectroscopy, Catalysis Communication, 2010, 11, 887-891.
(38)Pingle Liu*, Huan Xie, Shirong Tan, Kuiyi You, Nailiang Wang, He’an Luo*, Carbon nanofibers supported nickel catalyst for liquid phase hydrogenation of benzene with high activity and selectivity, Reaction Kinetics and Catalysis letters, 2009, 97(1): 101-108.
(39)Xiao Luo, Pingle Liu*, He’an Luo, Improvement of Prandtl mixing length theory and application in modeling of turbulent flow in circular tubes, Journal of Central South University of Technology, 2008, 15:774-778.
(40)Pingle Liu*, Liangjie Wang, He’an Luo, Bubble effectiveness in cyclohexane non-catalytic oxidation Process, Iranian Journal of Chemistry and Chemical Engineering, 2007, 26(1): 85-92.
(41)Pingle Liu*, L. Lefferts, Preparation of carbon nano-riber washcoat on porous silica foam as structured catalyst support, Chinese Journal of Chemical Engineering, 2006, 14 (3): 294-300.
(42)Pingle Liu*, L. Lefferts, Preparation of thin porous silica foam on alumina disk substrate, Catalysis letters, 2006, 106(1-2): 49-53.
(43)Pingle Liu*, Lishan Zou, He’an Luo, Liangjie Wang, Jinhua Zheng, Estimation of kinetic parameters for autocatalytic oxidation of cyclohexane based on a modified adaptive genetic algorithm, Chinese Journal of Chemical Engineering, 2004, 12(1): 49-54.
每年招收1-2名博士，3-5名硕士，课题组招收8-10名硕士，欢迎报考

daretian

今年上半年，我校化工学院刘平乐教授团队先后在《应用催化B》（Applied Catalysis B: Environmental）、《催化学报》（Journal of Catalysis）、《绿色化学》（Green Chemistry ）、《美国化学会应用材料与界面》（ACS Applied Materials & Interfaces）等顶级期刊发表研究成果。

       今年1月，刘平乐教授团队在催化领域顶级期刊连续发表了2篇论文。“氮掺杂碳纳米管无金属加氢催化剂高效催化硝基苯加氢反应（Nitrogen-doped carbon nanotubes as a highly active metal-free catalyst for nitrobenzene hydrogenation）”发表在《应用催化B》（一区TOP期刊，影响因子为14.229），第一作者是熊伟副教授，通讯作者是刘平乐教授。该成果通过杂原子改性得到碳纳米管非金属催化剂，因不含金属组分但却拥有媲美金属的加氢催化性能，具有极大的研究意义和环保价值。“疏水改性核壳MOFs纳米反应器中肉桂醛转移加氢制备肉桂醇:金属-N键作为活性位点的识别（Transfer hydrogenation of cinnamaldehyde to cinnamyl alcohol in hydrophobically modified core–shell MOFs nanoreactor: Identification of the formed metal–N as the structure of an active site”）在《催化学报》（一区TOP期刊，影响因子为7.723）上发表，第一作者是博士研究生崔海帅，通讯作者是刘平乐教授和熊伟副教授。该研究成果与现有催化剂相比，在大大降低生产成本和避免使用碱性添加剂的条件下，实现了高效的制备肉桂醇，符合绿色催化的原则。
       今年4月，刘平乐教授团队在化学类顶级期刊《绿色化学》（一区TOP期刊，影响因子为9.405 ）上发表题为“萘一步催化胺化高收率制备萘胺（One-step catalytic amination of naphthalene to naphthylamine with exceptional yield）”的最新研究成果，第一作者是郝芳副教授，通讯作者是刘平乐教授。该成果首次采用钒基催化剂，将萘通过一步反应成功合成萘胺。相比传统的硝化还原方法，该一步法在极大简化工艺步骤的同时将催化剂的成本大大降低，具有很高的应用价值和研究意义。
       今年5月，刘平乐教授团队在美国化学会顶级期刊《美国化学会应用材料与界面》（一区TOP期刊，影响因子为8.69）上发表题为“选择性Cl修饰赤铁矿纳米晶面用于高效催化氧化环己烷:新形成的Cl-O活性位点的识别（Selective Cl-decoration on Nanocrystal Facets of Hematite for High-efficiency Catalytic Oxidation of Cyclohexane: Identification of the New Formed Cl-O as Active Sites）”的研究论文，第一作者是博士研究生吴生焘，通讯作者是刘平乐教授和王聪慧博士。该研究通过对纳米晶体表界面上合理的原子调控，从原子尺度上对催化剂的“构效关系”进行深入理解，发现赤铁矿各晶面经卤素原子Cl修饰后能同时提高环己烷转化率和KA油的选择性，并通过DFT计算对催化反应的活性位点进行了识别，具有很高的理论研究价值和应用价值。
       刘平乐教授团队成员由3名副教授（熊绍锋、郝芳、熊伟）、2名博士（王聪慧、吕扬）、36名在读博士和硕士研究生组成，主要研究方向为催化材料与催化反应工程、化工新产品与新工艺的研究开发、化工过程模拟与优化等，其成员入选了教育部新世纪优秀人才支持计划、“芙蓉学者”特聘教授、湖南省普通高校学科带头人、湖南省121人才工程二层次人选等。近年来，团队与挪威理工大学、美国北卡罗来纳州立大学、美国韦恩州立大学、荷兰屯特大学、中科院大连化学物理研究所、华南理工大学、中南大学等国内外大学与科研机构开展了广泛的交流与合作，现已完成国家自科基金项目、湖南省自科基金项目等20余项，在研国家自科基金项目2项、湖南省战略性新兴产业科技攻关类项目1项、湖南省自然科学基金项目3项。完成企业横向技术开发和转让项目10余项，荣获国家科技进步二等奖、湖南省科技进步一等奖、省教学成果一等奖、省自然科学奖三等奖、湖南省青年科技奖等荣誉。
（刘宇谦）
（来源：湘潭大学）
（链接：http://news.xtu.edu.cn/html/jiaoxueky/show_12420.html）