邹勃,吉林大学超硬材料国家重点实验室教授,博士生导师,长江学者特聘教授(2017.3-2022.2),国家杰出青年科学基金获得者(2018.1-2022.12),长白山学者特聘教授(2015.1-2017.12)。 主要从事高压物理和高压化学研究,利用自主设计搭建的高压原位吸收、发射、拉曼和红外光谱等多种高压原位光谱实验测量系统,建立了高压化学实验室。 利用高压这个独特的热力学参量,通过调控化学反应动力学势垒和热力学相变势垒,发现了系列高压相截获的方法,并成功应用在高能密度材料上;成功实现了压致变色材料光学特性的大范围精确调控,提出了压力诱导发光(PIE)的概念;发现了新型超大负压缩率材料、提出分子层滑移和“酒架状”非共价键结构等负压缩新机制,为制备具有特定功能的化学材料提供了新思路和新方法。 共发表包括Nature Commun, J Am Chem Soc和Angew Chem Int Ed等在内的SCI论文270余篇,被SCI论文引用5200余次,H因子为36。
代表性论文:
高压下卤素钙钛矿材料研究 1. Z. Ma, Z. Liu, S. Lu, L. Wang, X. Feng, D. Yang, K. Wang, G. Xiao,* L. Zhang,* S. A. T. Redfern, and B. Zou,* Pressure-Induced Emission of Halide Perovskite Cs4PbBr6 Nanocrystals. Nature Commun. 9 (2018), 4506 (压力诱导发光PIE) 2. G. Xiao, Y. Cao, G. Qi, L. Wang, C. Liu, Z. Ma, X. Yang, Y. Sui, W. Zheng, and B. Zou,* Pressure Effects on Structure and Optical Properties in Cesium Lead Bromide Perovskite Nanocrystals. J. Am. Chem. Soc. 139 (2017), 10087 3. Q. Li, Y. Wang, W. Pan, B. Zou,* W. Yang, J. Tang, and Z. Quan,* High Pressure Band Gap Engineering in Lead-Free Cs2AgBiBr6 Double Perovskite. Angew. Chem. Int. Ed. 56 (2017), 15969 (高压下带隙截获) 4. L. Zhang, C. Liu, L. Wang, C. Liu, K. Wang,* and B. Zou,* Pressure-Induced Emission Enhancement, Band-Gap Narrowing, and Metallization of Halide Perovskite Cs3Bi2I9. Angew. Chem. Int. Ed. 57 (2018), 11213 (压力诱导发光PIE) 5. Q. Li, S. Li, K. Wang, Z. Quan, Y. Meng, and B. Zou,* High Pressure Study of perovskite-like Organometal Halide: Band Gap Narrowing and Structural Evolution of [NH3-(CH2)4-NH3]CuCl4. J. Phys. Chem. Lett. 8 (2017), 500 6. L. Wang, K. Wang, and B. Zou,* Pressure-Induced Structural and Optical Properties of Organometal Halide Perovskite Based Formamidinium Lead Bromide. J. Phys. Chem. Lett. 7 (2016), 2556 7. L. Wang, K. Wang, G. Xiao, Q. Zeng, and B. Zou,* Pressure Induced Band Gap Shifts and Structural Evolution of Organometal Halide Perovskite-Based Methylammonium Lead Chloride. J. Phys. Chem. Lett. 7 (2016), 5273
高压下负压缩材料研究 1. Q. Zeng, K. Wang,* and B. Zou,* Large Negative Linear Compressibility in InH(BDC)2 from Framework Hinging. J. Am. Chem. Soc. 139 (2017), 15648 2. Q. Zeng, K. Wang, Y. Qiao, X. Li, and B. Zou,* Negative Linear Compressibility due to Layer Sliding in a Layered MOF, J. Phys. Chem. Lett. 8 (2017), 1436 3. Y. Qiao, K. Wang, H. Yuan, K. Yang, and B. Zou,* Negative Linear Compressibility in Organic Mineral Ammonium Oxalate Monohydrate with Hydrogen Bonding Wine-rack Motifs. J. Phys. Chem. Lett. 6 (2015), 2755
高压下压致变色材料研究
1. J. Wu, Y. Cheng, J. Lan,* D. Wu, S. Qian, L. Yan, Z. He, X. Li, K. Wang, B. Zou,* and J. You,* Molecular Engineering of Mechanochromic Materials by Programmed C–H Arylation: Making a Counterpoint in Chromism Trend. J. Am. Chem. Soc. 138 (2016), 12803 2. Y. Wang, X. Tan, Y. Zhang, S. Zhu, I. Zhang, B. Yu, K. Wang, B. Yang, M. Li,* B. Zou,* and S. X. Zhang,* Dynamic Behavior of Molecular Switches in Crystal under Pressure and Its Reflection on Tactile Sensing. J. Am. Chem. Soc. 139 (2017), 931 3. Y. Liu, Q. Zeng, B. Zou,* Y. Liu, B. Xu*, and W. Tian, Piezochromic Luminescence of Donor—Acceptor Co-crystal: Distinct Responses to Anisotropic Grinding and Isotropic Compression. Angew. Chem. Int. Ed. 57(2018), DOI:10.1002/anie.201810149 4. Y. Dong, B. Xu, J. Zhang, X. Tan, L. Wang, J. Chen, H. Lv, S. Wen, B. Li, L. Ye, B. Zou,* and W. Tian,* Piezochromic Luminescence Based on the Molecular Aggregation of 9,10-Bis((E)-2-(pyrid-2-yl)vinyl)anthracene. Angew. Chem. Int. Ed. 51 (2012), 10782 5. L. Wang, K. Wang, B. Zou,* K. Ye, H. Zhang,* and Y. Wang, Luminescent Chromism of Boron Diketonate Crystals: Distinct Responses to Different Stresses. Adv. Mater. 27 (2015), 2918 6. S. Zhang, Y. Dai, Y. Gao, S. Luo, K. Wang, B. Zou,* B. Yang,* and Y. Ma, Rehybridization of Nitrogen Atom Induced Photoluminescence Enhancement Under Pressure Stimulation. Adv. Funct. Mater. 27 (2017), 1602276 (压力诱导发光PIE) 7. Y. Gu, K. Wang,* Y. Dai, G. Xiao, Y. Ma, Y. Qiao, and B. Zou,* Pressure-Induced Emission Enhancement of Carbazole: the Restriction of Intramolecular Vibration. J. Phys. Chem. Lett. 8 (2017), 4191 (压力诱导发光PIE) 8. H. Yuan, K. Wang, K. Yang, B. Liu, and B. Zou,* Luminescence properties of compressed tetraphenylethene: the role of intermolecular interactions. J. Phys. Chem. Lett. 5 (2014), 2968 (压力诱导发光PIE)
纳米材料制备及其在高压下的研究 1. G. Xiao, Y. Wang, D. Han, K. Li, X. Feng, K. Wang, L. Liu, S. A. T. Redfern, and B. Zou,* Pressure-induced Large Emission Enhancements of Cadmium Selenide Nanocrystals. J. Am. Chem. Soc. 140 (2018), 13970 (压力诱导发光PIE) 2. G. Xiao, X. Yang, X. Zhang, K. Wang, X. Huang, Z. Ding, Y. Ma, G. Zou, and B. Zou,* A Protocol to Fabricate Nanostructured New Phase: B31-Type MnS Synthesized under High Pressure. J. Am. Chem. Soc. 137 (2015), 10297 (高压相截获) 3. C. Liu, G. Xiao,* M. Yang, B. Zou,* Z. Zhang,* and D. Pang, Mechanofluorochromic Carbon Nanodots: Controllable Pressure-Triggered Blue and Red Shifted Photoluminescence. Angew. Chem. Int. Ed. 57 (2018), 1893 4. S. Lu, G. Xiao, L. Sui, T. Feng, X. Yong, S. Zhu, B. Li, Z. Liu, B. Zou,* M. Jin,* J. S. Tse, H. Yan,* and B. Yang,* Unique Piezochromic Carbon Dots with Two-photon Fluorescence. Angew. Chem. Int. Ed. 56 (2017), 6187 (高压相截获) 5. G. Xiao, C. Zhu, Y. Ma,* B. Liu, G. Zou, and B. Zou,* Unexpected Room-Temperature Ferromagnetism in Nanostructured Bi2Te3. Angew. Chem. Int. Ed. 53 (2014), 729 6. B. Zou, B. Ceyhan, U. Simon, and C. M. Niemeyer,* Self-Assembly of Cross-Linked DNA-Gold Nanoparticle Layers Visualized by In Situ Scanning Force Microscopy. Adv. Mater. 17 (2005), 1643 7. Q. Dai, Y. Wang, X. Li, Y. Zhang, D. J. Pellegrino, M. Zhao, B. Zou,* J. Seo, Y. Wang, and W. W. Yu,* Size-Dependent Composition and Molar Extinction Coefficient of PbSe Semiconductor Nanocrystals. ACS Nano 3 (2009), 1518
高压下超分子材料研究,高压相的截获及其在高能密度材料和富氢材料中的应用 1. Q. Li, X. Sha, S. Li, K. Wang, Z. Quan, Y. Meng, and B. Zou,* High-Pressure Effects on Hofmann-Type Clathrates: Promoted Release and Restricted Insertion of Guest Molecules. J. Phys. Chem. Lett. 8 (2017), 2745 2. K. Wang, D. Duan, R. Wang, D. Liu, L. Tang, T. Cui, B. Liu, Q. Cui, J. Liu, B. Zou,* and G. Zou, Pressure-Induced Phase Transition in Hydrogen-Bonded Supramolecular Adduct Formed by Cyanuric Acid and Melamine. J. Phys. Chem. B 113 (2009), 14719 (高压相截获) 3. S. Li, Q. Li, J. Zhou, R. Wang, Z. Jiang, K. Wang, D. Xu, J. Liu, B. Liu, G. Zou, and B. Zou,* Effect of High Pressure on the Typical Supramolecular Structure of Guanidinium Methanesulfonate. J. Phys. Chem. B 116 (2012), 3092 (高压相截获) 4. S. Li, Q. Li, R. Li, J. Liu, K. Yang, B. Liu, and B. Zou,* New Assembly of Acetamidinium Nitrate Modulated by High Pressure. J. Phys. Chem. C 118 (2014), 23443 (高压相截获,高能密度材料) 5. S. Li, Q. Li, K. Wang, M. Zhou, X. Huang, J. Liu, K. Yang, B. Liu, T. Cui, G. Zou, and B. Zou,* Pressure-Induced Irreversible Phase Transition in the Energetic Material Urea Nitrate: A Combined Raman Scattering and X-ray Diffraction Study. J. Phys. Chem. C 117 (2013), 152 (高压相截获,高能密度材料)
6. R. Wang, S. Li, K. Wang, D. Duan, L. Tang, T. Cui, B. Liu, Q. Cui, J. Liu, B. Zou,* and G. Zou, Pressure-induced Phase Transition in Hydrogen-Bonded Supramolecular Structure: Guanidinium Nitrate. J. Phys. Chem. B 114 (2010), 6765 (高能密度材料) 7. T. Yan, K. Wang, X. Tan, J. Liu, B. Liu, and B. Zou,* Exploration of the Hydrogen-Bonded Energetic Material Carbohydrazide at High Pressures. J. Phys. Chem. C 118 (2014), 22960 (高能密度材料) 8. S. Li, Q. Li, K. Wang, X. Tan, M. Zhou, B. Li, B. Liu, G. Zou, and B. Zou,* Pressure-Induced Phase Transition in Guanidinium Perchlorate: A Supramolecular Structure Directed by Hydrogen Bonding and Electrostatic Interactions. J. Phys. Chem. B 115 (2011), 11816-11822 (高能密度材料)
9. G. Qi, K. Wang,* G. Xiao, and B. Zou,* High Pressure, a Protocol to Identify the Weak Dihydrogen Bonds: Experimental Evidence of C—H···H—B Interaction. Sci. China Chem. 61 (2018), 276 (富氢材料)
10. G. Qi, K. Wang, X. Li, and B. Zou,* High Pressure Behavior of Hydrogen Storage Material Guanidinium Borohydride, J. Phys. Chem. C 120 (2016), 13414 (富氢材料) 11. G. Qi, K. Wang,* K. Yang, and B. Zou,* Pressure Induced Phase Transition of Hydrogen Storage Material Hydrazine Bisborane: Evolution of Dihydrogen Bonds. J. Phys. Chem. C 120 (2016), 21293 (富氢材料)
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