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[专家学者] 中国人民大学化学系牟天成

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发表于 2017-3-18 19:29:08 | 只看该作者 |只看大图 回帖奖励 |倒序浏览 |阅读模式
牟天成
中国人民大学化学系,副教授,博士生导师


教育经历
2001/09 – 2004/06,中国科学院化学研究所,博士
1995/09 – 1998/06,曲阜师范大学,化学系,硕士
1990/09 – 1994/06,烟台师范学院,化学系,学士


工作经历
2004/07 –       中国人民大学化学系
2005/06 – 2006/12,德国奥登堡大学工业化学系
1998/07 – 2001/08,烟台师范学院化学系


学术兼职:
英国皇家化学会期刊RSC Advances的Associate Editor
中国化学会绿色化学专业委员会委员
中国化工学会离子液体专业委员会委员
英国皇家化学会会员Member of Royal Society of Chemistry (MRSC)


奖励:
2016中国分析测试协会科学技术奖(CAIS)一等奖,排名第一
邮件:tcmu(at)ruc.edu.cn


专著
1.T Mu*, B Han*, Structures and Thermodynamic Properties of Ionic Liquids, in Structures and Interactions of Ionic Liquids, Structure and Bonding, Vol 151, Springer-Verlag, Berlin and Heidelberg, 2014, VII, 107-139.
2.牟天成,超临界流体科学与技术(第十章), 中国石化出版社, 北京 (2005)
授权专利
1.一种原油破乳剂及其制备方法,授权号:ZL201310523190.0
2.一种调节相对湿度的方法,授权号:ZL201310331355.4
3.利用离子液体捕集二氧化碳和提取壳聚糖的方法,授权号:ZL201310368718.1
4.利用离子液体-二氧化碳体系分级分离不同聚合度的纤维素的方法,授权号:ZL201310581983.8
论文发表
2017年
1.B Wang, L Qin, T Mu*, Z Xue, G Gao*, Are Ionic Liquids Chemically Stable? Chem Rev, 2017, DOI: 10.1021/acs.chemrev.6b00594.
2.Z Xue*, J Jiang, M-G Ma, M-F Li, T Mu*, Gadolinium-Based Metal-Organic Framework as an Efficient and Heterogeneous Catalyst to Activate Epoxides for Cycloaddition of CO2 and Alcoholysis, ACS Sustainable Chem. Eng., 2017, 5 (3), 2623–2631.
2016年
3.J Wang, Z Xue, C Yan, Z Li, T Mu*, Fine Regulation of the Cellulose Dissolution and Regeneration by Low Pressure CO2 in DMSO/Organic Base: the Dissolution Behavior and Mechanism, Phys Chem Chem Phys, 2016, 18(48), 32772 – 32779.
4.Z Xue*, X Zhao, J Wang, T Mu*, Transfer hydrodehalogenation of aryl halides accelerated by saturated sodium acetate aqueous solution, RSC Adv, 2016, 6, 102193-102197
5.Z Xue*, M Ma, Z Li, T Mu*, Advances in conversion of glucose and cellulose to 5-hydroxymethylfurfural over heterogeneous catalysts, RSC Adv, 2016, 6, 98874 – 98892.
6.G Li, Z Xue, B Cao, C Yan, T Mu*, Preparation and properties of C=X, (X is O, N, S) based distillable ionic liquids and their application for rare earth separation, ACS Sustainable Chem Eng, 2016, 4(12), 6258−6262.
7.J Jiang, W Zhao, Z Xue, Q Li, C Yan, T Mu*, PEGylated quasi-ionic liquid electrolytes: fundamental physiochemical properties and electrodeposition of aluminium, ACS Sustainable Chem Eng, 2016, 4(10), 5814-5819.
8.C Yan, Z Xue, W Zhao, J Wang, T Mu*, Surprising Hofmeister ion effects on the bending vibration of water, ChemPhysChem, 2016, 17(20), 3309-3314.
9.Z Xue*, B Cao, W Zhao, J Wang, T Yu, T Mu*, Heterogeneous Nb-containing catalyst/N,N-dimethylacetamide-salts mixtures: Novel and efficient catalytic systems for dehydration of fructose, RSC Adv, 2016, 6, 64338 - 64343.
10.Z Xue*, W Chang, Y Cheng, J Liu, J Li, W Zhao, T Mu*, CO2-in-PEG emulsion-templating synthesis of poly(acrylamide) with controllable porosity and their use as efficient catalyst supports, RSC Adv, 2016, 6, 58182 - 58187.
11.Z Xue*, X Zhao, R Sun, T Mu*, Biomass-Derived γ-Valerolactone-Based Solvent Systems for Highly Efficient Dissolution of Various Lignins: Dissolution Behaviour and Mechanism Study, ACS Sustainable Chem Eng, 2016, 3864–3870.
12.Y Zhang, Z Xue, J Wang, X Zhao, Y Deng*, W Zhao, T Mu*, Controlled Deposition of Pt Nanoparticles on Fe3O4@Carbon Microspheres for Efficient Oxidation of 5-Hydroxymethylfurfural, RSC Adv, 2016, 6, 51229 – 51237.
13.Z Xue*, J Jiang, G Li, W Zhao, J Wang, T Mu*, Zirconium-cyanuric acid coordination polymer: Highly efficient catalyst for conversion of levulinic acid to γ-valerolactone, Cat Sci Technol, 2016, 6, 5374 – 5379.
14.Q Li#, J Jiang#, G Li, W Zhao, X Zhao, T Mu*, The electrochemical stability of ionic liquids and deep eutectic solvents, Sci China, Chem, 2016, 59(5), 571-577.
15.G Li, C Yan, B Cao, J Jiang, W Zhao, J Wang, T Mu*, Highly Efficient I2 Capture by Simple and Low-cost Deep Eutectic Solvents, Green Chem, 2016, 18, 2522 – 2527.
16.Z Xue*, Y Zhang, G Li, J Wang, W Zhao, T Mu*, Niobium phytic prepared from phytic acid and NbCl5: Highly efficient and heterogeneous acid catalyst, Cat Sci Technol, 2016, 6, 1070 – 1076.
2015年
17.W Zhao, Z Xue, J Wang, J Jiang, X Zhao, T Mu*, Large-Scale, Highly Efficient, and Green Liquid-Exfoliation of Black Phosphorus in Ionic Liquids, ACS Appl. Mater. Interfaces, 2015, 7 (50), 27608–27612.
18.Z Xue*, X Sun, Z Li, T Mu*, CO2 as a regulator for controllable preparation of highly dispersed chitosan-supported Pd catalysts in ionic liquid, Chem Commun, 2015, 51, 10811-10814.
19.王晓静,牟天成*,离子液体的吸水性研究进展,科学通报,2015,60(26), 2516-2524.
20.Q Tian, R Li, H Sun*, Z Xue*, T Mu*, Theoretical and experimental study on the interaction between 1-butyl-3-methylimidazolium acetate and CO2, J Mol Liq, 2015, 208, 259-268.
21.X Sun, C Huang, Z Xue, C Yan, T Mu*, Efficient and sustainable strategy for the hierarchical separation of lignin-based compounds using ionic liquid/ compressed CO2, Energy & Fuels, 2015, 29 (4), 2564–2570.
22.X Sun, Z Liu, Z Xue, Y Zhang, T Mu*, Extraction of 5-HMF from the conversion of glucose in ionic liquid [Bmim]Cl by compressed carbon dioxide, Green Chem, 2015, 17(5), 2719-2722.
23.Q Tian, S Liu, X Sun, H Sun*, Z Xue, T Mu*, Theoretical Studies on the Dissolution of Chitosan in Acetate-based Ionic Liquids, Carbohyd Res, 2015, 408, 107-113.
24.X Sun, C Huang, Z Xue*, T Mu*, An environmentally benign cycle to regenerate chitosan and capture carbon dioxide by ionic liquids, Energy Fuels, 2015, 29 (3), 1923–1930.
25.S Liu, Y Chen, Y Shi, H Sun*, Z Zhou, T Mu*, Investigations on the thermal stability and decomposition mechanism of an amine–functionalized ionic liquid by TGA, NMR, TG-MS experiments and DFT calculations, J Mol Liq, 2015, 95-102.
26.Y Chen, C Yan, X Ma, Y Cao, T Mu*, Evolutional mechanism of 1-ethyl-3-methyl-imdazolium acetate uptaking water from air detected with a new coupled method: two-dimensional correlation difference spectroscopy, J Mol Liq, 2015, 203, 169-180.
27.C Yan, T Mu*, Molecular understanding of ion specificity at the peptide bond, Phys Chem Chem Phys, 2015, 17, 3241-3249.
28.Y Chen, T Mu*, A new way to interpret PCMW two-dimensional correlation spectroscopy: probing the dynamic interaction for ionic liquid [EMIM][Ac] to absorb atmospheric water, Applied Spectroscopy, 2015, 69(1), 130-142.
29.Z Liu, X Sun, M Hao, C Huang, Z Xue, T Mu*, Preparation and Characterization of Regenerated Cellulose from Ionic Liquid Using Different Methods, Carbohydrate Polymers, 2015, 117, 99-105.
30.Yu Chen, S Li*, Z Xue, M Hao, T Mu*, Quantifying the hydrogen-bonding interaction between cation and anion of pure [EMIM][Ac] and evidencing the ion pairs existence in its extremely diluted water solution: via 13C, 1H, 15N and 2D NMR, J Mol Stru, 2015, 1079(5), 120-129.
2014年
31.Y Chen, C Yan, W Zhao, Z Liu, T Mu*, The dynamic process of radioactive iodine removal by ionic liquid 1-butyl-3-mehtyl-imidazolium acetate: discriminating and quantifying halogen bonds versus induced force, RSC Adv, 2014, 4 (98), 55417 – 55429.
32.Y Chen, X Sun, C Yan, Y Cao, T Mu*, The Dynamic Process of Atmospheric Water Sorption in [EMIM][Ac] and Mixtures of [EMIM][Ac] with Biopolymers and CO2 Capture in These Systems, J Phys Chem B, 2014, 118 (39), 11523–11536.
33.Y Chen, Y Cao, C Yan, Y Zhang, T Mu*, The Dynamic Process of Atmospheric Water Sorption in [BMIM][Ac]: Quantifying Bulk vs Surface Sorption and Utilizing Atmospheric Water as a Structure Probe, J Phys Chem B, 2014, 118, 6897-6907.
34.Y Cao, Y Chen, X Sun, T Mu*, Quantifying the Concentration of Ionic Liquids in Water and Qualifying the Conjugated and Inductive Effects of Ionic Liquids by Ultraviolet-Visible Spectroscopy, Clean-Soil, Air, Water, 2014, 42(8), 1162-1169.
35.X Sun, S Liu, A Khan, C Zhao, C Yan, T Mu*, Ionicity in acetate-based protic ionic liquids: evidences for both liquid and gaseous phases, New J Chem, 2014, 38 (8), 3449 – 3456.
36.X Sun, Q Tian, Z Xue, Y Zhang, T Mu*, The dissolution behaviour of chitosan in acetate-based ionic liquids and their interactions: from experimental evidence to density functional theory analysis, RSC Adv, 2014, 4, 30282-30291.
37.C Yan, J Han, C Huang, T Mu*, Demulsification of Water-in- Oil Emulsions by Alternating Copolymers, Energy Technol, 2014, 2(7), 618-624.
38.Y Cao, T Mu*, A comprehensive investigation on the thermal stability of 66 ionic liquids by thermogravimetric analysis, Ind Eng Chem Res, 2014, 53 (20), 8651–8664, Feature Article.
39.X Wang, Y Chi, T Mu*, A review of the transport properties of ionic liquids, J Mol Liq, 2014, 193, 262-266.
40.X Sun, Y Chi, T Mu*, Studies on staged precipitation of cellulose from ionic liquid by compressed carbon dioxide, Green Chem, 2014, 16(5), 2736-2744.
41.C Yan, T Mu*, Investigation of ionic liquids for efficient removal and reliable storage of radioactive iodine: a halogen-bonding case, Phys Chem Chem Phys, 2014, 16(11), 5071-5075.
42.X Sun, Z Xue, T Mu*, Precipitation of chitosan from ionic liquid solutions by compressed CO2 anti-solvent method, Green Chem, 2014, 16, 2102-2106.
43.Y Chen, Y Cao, T Mu*, A new application of acetate- based ionic liquids: potential usage as drying materials, Chem Eng Technol, 2014, 37(3), 527-534.
44.Y Cao, X Sun, Y Chen, T Mu*, Water sorption in amino-acid ionic liquids: kinetic, mechanism, and correlations between hygroscopicity and solvatochromic parameters, ACS Sustainable Chem Eng, 2014, 2(2), 138-148.
45.Z Xue, Y Zhang, X Zhou, Y Cao, T Mu*, Thermal stabilities and decomposition mechanism of amino- and hydroxyl-functionalized Ionic Liquids, Thermochimica Acta, 2014, 578, 59-67.
46.Y Cao, Y Chen, X Wang*, T Mu*, Predicting the hygroscopicity of imidazolium-based ILs varying in anion by hydrogen-bonding basicity and acidity, RSC Adv, 2014, 4, 5169-5176.
47.Y Chen, Y Cao, Y Zhang, T Mu*, Hydrogen bonding between acetate-based ionic liquids and water: three types of IR absorption peaks and NMR chemical shifts change upon dilution, J Mol Stru, 2014, 1058, 244-251.
48.Y Chen, Y Cao, X Sun, T Mu*, Hydrogen bonding interaction between acetate-based ionic liquid 1-ethyl-3-methylimidazolium acetate and common solvents, J Mol Liq, 2014, 190, 150-158.
49.H Sun, X Zhou, Z Xue, Z Zhou*, T Mu*, Theoretical Investigations on the Reaction Mechanisms of amine–functionalized ionic liquid [aEMMIM][BF4] and CO2, Int J Greenhouse Gas Con, 2014, 20, 43-48.
2013年
50.Y Cao, Yu Chen, T Mu*, A new way to tune relative humidity: by saturated ionic liquid aqueous solutions, New J Chem, 2013, 37(12), 3890-3898. (内封面, hot article)
51.Y Chen, Y Cao, X Lu, C Zhao, C Yan, T Mu*, Water Sorption in Protic Ionic Liquids: Correlation between Hygroscopicity and Polarity, New J Chem, 2013, 37, 1959-1967.
52.Y Chen, X Zhou, Y Cao, Z Xue, T Mu*, Quantitative investigation on the physical and chemical interactions between CO2 and amine–functionalized ionic liquid [aEMMIM][BF4] by NMR, Chem Phy Lett, 2013, 574, 124-128.
53.Y Chen, Y Cao, X Sun, C Yan, T Mu*, New Criteria Combined of Efficiency, Greenness, and Economy for Screening Ionic Liquids for CO2 Capture, Int J Greenhouse Gas Con, 2013, 16, 13-20.
54.Y Cao, Y Chen, L Lu, Z Xue, T Mu*, “Water Sorption in Functionalized Ionic Liquids: Kinetics and Intermolecular Interactions”, Ind Eng Chem Res, 2013, 52, 2073-2083.
2012年
55.Z Xue, T Mu*, J Gmehling*, Comparison of the a prior COSMO-RS models and Group Contributions Methods: Original UNIFAC, Modified UNIFAC(Do) as well as Modified UNIFAC(Do) Consortium, Ind Eng Chem Res, 2012, 51, 11809-11817.
56.Y Cao, Y Chen, X Sun, Z Zhang, T Mu*, Water sorption in ionic liquids: kinetics, mechanisms and hydrophilicity, Phys Chem Chem Phys. 2012, 14, 12252-12262.
57.Y Chen, Y Cao, Y Shi, Z Xue, T Mu*, “Quantitative Research on the Vaporization and Decomposition of [EMIM][Tf2N] by Thermogravimetric Analysis-Mass Spectrometry”, Ind Eng Chem Res, 2012, 51(21), 7418-7427.
2011年
58.Y Chen, J Han, T Wang, T Mu*, “Determination of Absorption Rate and Capacity of CO2 in Ionic Liquids at Atmospheric Pressure by Thermogravimetric Analysis”, Energy & Fuels, 2011, 25(12), 5810-5815.
59.Z Xue, Z Zhang, J Han, Y Chen, T Mu*, Carbon dioxide capture by a dual amino ionic liquid with amino-functionalized imidazolium cation and taurine anion, Int J Greenhouse Gas Con, 2011, 5(4), 628-633.


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沙发
发表于 2018-3-22 11:39:36 | 只看该作者
《关于热重分析仪和热稳定性-以离子液体为例》

中国人民大学教授牟天成讲到,低共熔溶液是由一定化学计量比的氢键受体(如季铵盐)和氢键给体(如酰胺、羧酸和多元醇等化合物)组合而成的两组分或三组分低共熔混合物,其凝固点显著低于各个组分纯物质的熔点。Abbott等人2003年首次报道。物理化学性质与离子液体非常相似,因此也被称为“准离子液体”或“离子液体类似物”。

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板凳
发表于 2019-2-25 08:56:31 | 只看该作者
低共熔溶剂(DESs)溶剂化处理V2VI3硫属化合物用于高效可见光驱动产氢



金属硫属化物在肼/硫的混合溶剂中的溶解可以产生高质量、大面积的半导体薄膜。但是肼具有高毒性、爆炸性和致癌性,使其工业化变得困难。Brutchey等人用二胺/二硫醇的混合物溶解V2VI3硫属化合物并获得高质量的化合物薄膜,但二硫醇具有恶臭气味,所有操作只能在手套箱中进行,带来了严重的可扩展性挑战。因此,人们迫切需要一种新型的绿色溶剂溶解本体金属硫属化合物半导体。

低共熔溶剂(DESs)具有制备简单、廉价和无毒的优点,已用于催化、有机合成、溶解和分离、电化学和材料化学等多个领域。然而,用于溶解金属硫属化合物半导体的DESs很少报道。


近日,中国人民大学牟天成团队提出了一种用于溶解九种V2VI3硫属元素化物的新型DES。其中氢键供体采用甲基硫脲(MTU),而氢键受体则采用1,5-二氮杂双环[5.4.0] -5-十一碳烯(DBU)。上图描述了九种硫属元素化物的溶解和用于可见光驱动氢析出的溶液处理策略。

他们使用三乙醇胺(TEOA)作为牺牲电子供体,在可见光(420-760 nm)的照射下对再生的Sb2S3进行光催化H2产率的测试,下图显示了溶液加工处理之前和之后光催化析氢效率的比较。氢气量随时间稳定增加,再生的Sb2S3(436 μmol•L-1•h-1)与原始的Sb2S3产氢效率(51 μmol•L-1•h-1)相比,效率提高8.5倍,表明溶剂化处理工艺可以作为提高H2产生效率的有效策略。平均量子产率和太阳能-氢能转换效率分别达到15.57%和9.02%,在现有Sb2S3基光催化剂中最高。
这项工作提供了一种环境友好的DES(DBU/MTU),用于溶解和再沉积九种V2VI3硫属元素化物。其中,锑和铋的化合物在退火后可得到纯相材料。沉积的膜具有均匀且致密的小尺寸纳米颗粒。这种绿色溶剂可以扩展到溶解/再沉积其它硫属化物材料,并且再生的材料在光催化的其它领域具有应用潜力,例如光催化CO2还原和N2固定。

这一成果近期发表在Green Chemistry 上,文章的共同第一作者是中国人民大学的博士研究生王晋芳牟红宇


该论文作者为:Jinfang Wang, Hongyu Mou, Rong Li, Yan Li, Debao Wang, Zhimin Xue and Tiancheng Mu
Solution Processing V2VI3 Chalcogenides with Deep Eutectic Solvent for Enhanced Visible-Light-Driven Hydrogen Production
Green Chem., 2018, DOI: 10.1039/C8GC03085E


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