深圳大学田雷

hezuo

田雷，深圳大学特聘副研究员，助理教授，硕士生导师，深圳市海外高层次人才，香港大学博士后研究员。现任《高分子通报》编委。2018年博士毕业于西北工业大学，主要从事胶体结构控制制备与性能研究，开创新型种子溶胀聚合技术。随后获得香港大学第39届postdoctoral fellowship (PDF)，加入香港大学化学系担任博士后研究员，开展高分子刷可控合成及其诱导形成空腔结构的机理研究。2020年5月任教于深圳大学化学与环境工程学院，长期致力于高性能高分子材料的设计合成与性能研究。近期在瞬态可回收高分子、高性能离子/电子导通高分子及纤维、热致液晶高分子及纤维、碳纤维用高分子前驱体、智能高分子材料等取得系列进展。迄今为止，在Macromolecules，ACS Applied Materials & Interfaces，Polymer chemistry，ACS Sustainable Chemistry & Engineering，Langmuir等国际知名期刊上发表学术论文40多篇。近3年，作为负责人主持科研项目4项，包括国家自然基金1项，深圳市基础研究面上项目1项，深圳市孔雀计划启动项目1项。主持教研项目2项，包括广东省高等教育教学研究和改革项目1项等。
       
田雷
职称：助理教授/特聘副研究员
EMAIL：leitian@szu.edu.cn



工作与教育经历
2020.11-至今，深圳大学，化学与环境工程学院，特聘副研究员
2020.05-至今，深圳大学，化学与环境工程学院，助理教授
2018.09-2020.03，香港大学，化学系，博士后研究员
2013.09-2018.06，西北工业大学，应用化学系，理学博士
2009.09-2013.07，西北工业大学，应用化学系，工学学士



研究方向
v 高分子能源材料及宽温域高电导固态聚合物电解质
v 高安全高能量密度固态聚合物电池研究
v 高强高韧软电子材料的设计制备与应用
v 高性能碳材料成碳机理及复合材料研究



2023年
29. Dai Wang, Hui Xie, Qiang Liu, Kexin Mu, Zhennuo Song, Weijian Xu, Lei Tian*, Caizhen Zhu, and Jian Xu. Low-Cost, High-Strength Cellulose-based Quasi-Solid Polymer Electrolyte for Solid-State Lithium-Metal Batteries. Angew. Chem. Int. Ed. 2023, e202302767.
2022年
28. Lei Tian, Jiji Tan, Dai Wang, Weiliang Dong, Haiyu Huang, Xintong Li, Caizhen Zhu, Jian Xu. Transient materials from hypersensitive ionic polymer fibers. Chemical Engineering Journal, 2023, 454, 140549.
27. 王岱，田雷，朱才镇，徐坚。固态聚合物电解质研究进展。高分子通报 。稿号：GFZTB-2022-0251.R1.
26. Lei Tian* #, Jiji Tan#, Weiliang Dong, Bo Yang, Cuihua Li, Dai Wang, Haiyu Huang, Xintong Li, Caizhen Zhu*, Jian Xu. Wireless Autonomous Soft Crawlers for Adjustable Climbing Actuation. [J/OL].Chinese Journal of Polymer Science 401-9(2022), DOI: 10.1007/s10118-022-2858-2.
25. Lei Tian*, Liu Y, Wang D, et al. Particle-Click-Particle: Colloidal Clusters from Click Seeded Emulsion Polymerization. Polymer Chemistry, 2022, 13, 1084-1089
2021年
24. Jia, Man; Liu, Huichao; Yang, Guang; Zhang, Shuo; Yang, Jinglong; Tian, Lei*; Zhu, Caizhen*; Xu, Jian*. ACS Applied Materials & Interfaces. 2021, 13(14): 16887-16894
23. Zheng Tang, Chaofan Chang, Feng Bao , Lei Tian, Huichao Liu, Mingliang Wang, Caizhen Zhu * and Jian Xu. Feasibility of Predicting Static Dielectric Constants of Polymer Materials: A Density Functional Theory Method[J]. Polymers, 2021, 13(2): 284.
22. Lei Tian*, Li B, Li X, et al. Janus dimers from tunable phase separation and reactivity ratios. Polymer Chemistry, 2020, 11(28): 4639-4646.
21. Lei Tian*, Li B, Zhang Q, et al. Polymer Brush-Induced Hollow Colloids via Diffusion-Controlled Silication[J]. Langmuir, 2020, 36(42): 12678-12683.
2020年以前
20. Lei Tian, Xiangjie Li, Panpan Zhao, et al. Generalized Approach for Fabricating Monodisperse Anisotropic Microparticles via Single-Hole Swelling PGMA Seed Particles. Macromolecules 2015, 48, 7592−7603.
19. Lei Tian, Xue Li, Panpan Zhao, et al. Fabrication of Liquid Protrusions on NonCross-Linked Colloidal Particles for Shape-Controlled Patchy Microparticles. Macromolecules 2016, 49, 9626-9636.
18. Xue Li, Lei Tian, Zafar Ali, et al. Design of flexible dendrimer-grafted flower-like magnetic microcarriers for penicillin G acylase immobilization. Journal of Materials Science, 2018, 53.2: 937-947.
17. Dewei Wan, Lei Tian, Xue Li, et al. A versatile strategy for enzyme immobilization: Fabricating lipase/inorganic hybrid nanostructures on macroporous resins with enhanced catalytic properties. Biochemical Engineering Journal, 2018, 139: 101-108.
16. Lei Tian, Li X, Wan D, et al. Large-Scale Fabrication of Polymer Ellipsoids with Controllable Patches via Viscosity-Induced Deformation of Spherical Pa
15. Lei Tian, Xue Li, Dewei Wan, et al. Fast Swelling Strategy for Flower-Like Micro-Sized Colloidal Surfactants with Controllable Patches by Regulating the Tg of Seed Particles. Polym. Chem., 2017, 8, 5327-5335.
14. Lei Tian, Xue Li, Dewei Wan, et al. Self-Stripping of Free-Standing Microparticle Gel Membranes Driven by Asymmetric Swelling. J. Mater. Chem. C 2017, 5, 7830-7836.
13. Lei Tian, Xue Li, Panpan Zhao, et al. Impressed pressure-facilitated seeded emulsion polymerization: design of fast swelling strategies for massive fabrication of patchy microparticles. Polym. Chem., 2016, 7, 7078–7085.
12. Zafar Ali, Lei Tian, B Zhang, et al. Synthesis of Fibrous and non-fibrous mesoporous silica Magnetic yolk–shell microspheres as a recyclable support for immobilization of Candida rugosa Lipase. Enzyme and Microbial Technology, 2017, 103: 42-52.
11. Lei Tian, Panpan Zhao, Xue Li, et al. Large-Scale Fabrication of Polymer Microcavities with Adjustable Openings and Surface Roughness Regulated by the Polarity of both Seed Surface and Monomers. Macromol. Rapid Commun. 2016, 37, 47−52. (cover)
10. Lei Tian, Panpan Zhao, Xue Li, et al. Design of Raspberry-Shaped Microcarriers with Adjustable Protrusions and Functional Groups for Improvement of Lipase Immobilization and Biocatalysis: Environment Friendly Esterification of Oleic Acid for Biodiesel. ChemCatChem 2016, 8, 2576. (cover)
9. Panpan Zhao, Lei Tian, Xue Li, et al. Effect of the Structure and Length of Flexible Chains on Dendrimers Grafted Fe3O4@SiO2/PAMAM Magnetic Nanocarriers for Lipase Immobilization. ACS Sustainable Chem. Eng., 2016, 4, 6382–6390.
8. Zafar Ali, Lei Tian, Panpan Zhao, et al. Immobilization of lipase on mesoporous silica nanoparticles with hierarchical fibrous pore. Journal of Molecular Catalysis B, 2016, 134, 129–135.
7. Xiangjie Li, Jingjing Zhou, Lei Tian, et al. Effect of crosslinking degree and thickness of thermosensitive imprinted layers on recognition and elution efficiency of protein imprinted magnetic microspheres. Sensors and Actuators B: Chemical, 2016, 225, 436-445.
6. Zafar Ali, Lei Tian, Panpan Zhao, et al. Micron-sized flower-like Fe3O4@GMA magnetic porous microspheres for lipase immobilization. RSC Adv., 2015, 5, 92449-92455.
5. Xiangjie Li, Baoliang Zhang, Lei Tian, et al. Improvement of recognition specificity of surface protein-imprinted magnetic microspheres by reducing nonspecific adsorption of competitors using 2-methacryloyloxyethyl phosphorylcholine. Sensors and Actuators B: Chemical, 2015, 208, 559-568.
4. Baoliang Zhang, Hepeng Zhang, Lei Tian, et al. Magnetic microcapsules with inner asymmetric structure: Controlled preparation, mechanism, and application to drug release. Chemical Engineering Journal, 2015, 275, 235-244.
3. Xiangjie Li, Jingjing Zhou, Lei Tian, et al. Bovine serum albumin surface imprinted polymer fabricated by surface grafting copolymerization on zinc oxide rods and its application for protein recognition. Journal of separation science, 2015, 38(19), 3477-3486.² 2. Lei Tian, Baoliang Zhang, Xiangjie Li, et al. Facile fabrication of Fe3O4@PS/PGMA magnetic Janus particles via organic–inorganic dual phase separation. RSC Adv. 2014, 4, 27152.
1. Xiangjie Li, Baoliang Zhang, Lei Tian, et al. Effect of carboxyl density at the core–shell interface of surface-imprinted magnetic trilayer microspheres on recognition properties of proteins [J]. Sensors and Actuators B: Chemical, 2014, 196, 265-271.

tianliang

近日，深圳大学化学与环境工程学院田雷/朱才镇/徐坚团队，在《Advanced Materials》（影响因子29.4，中科院JCR 1区，Top期刊）上发表了题为《Hybrid Crosslinked Solid Polymer Electrolyte via In-Situ Solidification Enables High-Performance Solid-State Lithium Metal Batteries 》的研究论文。硕士生母可心为本文的第一作者，田雷助理教授和朱才镇教授为本文通讯作者，通讯单位为深圳大学化学与环境工程学院。
       固体聚合物电解质（SPE）因其优异的加工性能和界面相容性，已成为固态电池产业化的重要发展方向和理论研究热点，但仍存在诸多缺陷，严重阻碍了其进一步的实际应用，如室温下离子电导率低（约10-7 S cm-1）、与电极材料界面接触不良（界面阻抗增大）、稳定性差（热稳定性和界面稳定性）、机械强度低（难以抑制锂枝晶造成短路）等。鉴于上述限制固态聚合物电解质大规模应用的问题，固态电池“原位固化“制备策略应运而生。即在热学、光学或电学条件下，在电池内部对液态前驱体进行原位固化，实现超共形界面兼容，极大地解决了固/固界面接触问题。通过分子设计构建的有机/无机杂化交联PDOL，将聚合物材料的良好加工性、界面接触性和电极兼容性等优点与无机材料的优异离子传输性、热稳定性、阻燃性等优点相结合，可有效解决上述问题。

         本工作提出了一种有机/无机杂化交联聚合物电解质(HCPE)的策略，该策略以1，3-二氧戊环（DOL）为单体、缩水甘油醚氧丙基笼状聚倍半硅氧烷(PS)作为交联剂和杂化中心在电池内部原位固化，形成的杂化交联网络有利于电化学稳定性和Li+传输动力学，由此制备的HCPE在30℃时具有优异的离子电导率2.22×10-3 S cm−1，较高的Li+转移数(tLi+)为0.88，电化学稳定窗口宽为5.2 V。这些突出性能使得组装的锂对称电池能够在1mA cm-2电流密度下实现高度稳定的锂沉积/剥离超过1000小时。此外，组装的LFP| HCPE |Li电池在2C下具有123.3 mAh g-1的高可逆放电比容量，并且在600次循环后具有92.1%的优异容量保持率。由此提出的HCPE克服了聚醚电解质易分解和安全性差的挑战，使“原位固化”进一步走向实际应用。
        该研究成果得到国家自然科学基金、广东省重点领域研发计划、广东省自然科学基金、广东省创新创业团队引进计划、广东省基础与应用基础研究基金项目、深圳市科技计划和中石油创新基金等项目资金资助。
        文献详情：Kexin Mu, Dai Wang, Weiliang Dong, Qiang Liu, Zhennuo Song, Weijian Xu, Pingping Yao, Yin’an Chen, Bo Yang, Cuihua Li, Lei Tian,* Caizhen Zhu,* Jian Xu, Hybrid Crosslinked Solid Polymer Electrolyte via In-Situ Solidification Enables High-Performance Solid-State Lithium Metal Batteries Adv. Mater. 2023, 202304686.
      https://doi.org/10.1002/adma.202304686