曹利平,博士,西北大学。2006年6月获华中师范大学学士学位,2011年5月获华中师范大学理学博士学位,2011年5月至2014年5月在美国马里兰大学做博士后研究,2014年5月到西北大学化学与材料科学学院工作。主要集中于探索人工合成功能化超分子主体分子在分子组装、分子机器、超分子聚合物材料、以及超分子药物体系的生物传递等方面的应用,并且取得了一系列具有较高学术价值的研究成果。至今,已发表论文50余篇,其中在国际具有重要学术影响的期刊上发表论文20余篇,其中4篇发表在J.Am.Chem.Soc.(2)和Angew.Chem.,Int.Ed.(2);相关工作被Spotlights on Recent JACS Publications重点评述,以及作为VIP paper和Poster of the frontispiece(首页封文章)发表。
姓名:曹利平 性别:男 民族:汉族
部门:无机化学与材料化学学部
职称:教授
邮箱:chcaoliping@nwu.edu.cn 电话:13572011784(H) 13572011784(O)
研究方向: Supramolecular Chemistry, Host-Guest Chemistry, Molecular Machine, Self-assembly System, Stimuli-responsive System, Drug Delivery
简 介
本组致力于有机-无机超分子化学、主客体化学、功能材料等相关领域的研究,欢迎对本课题组感兴趣的同学报考!同时欢迎本科学生加入科研团队,为读研做前期准备。地址:西安市长安区学府大道1号,西北大学,化学与材料科学学院,710127。办公室:化材院大楼618,实验室620-622。
教育与职业经历:
2016年-今:陕西省百人计划特聘教授
2015年-今:西北大学优秀青年学术骨干
2014-今:教授,博导,西北大学,化学与材料科学学院。
2011-2014:博士后,美国马里兰大学,化学与生物化学系;
2006-2011:理学博士,华中师范大学,农药与化学生物学教育部重点实验室;
2002-2006:学士,华中师范大学,化学学院。
研究兴趣:
基于分子识别的刺激响应超分子体系的建立;新颖大环分子的合成及其功能化应用研究;抗癌药物的靶向传递体系的建立;分子组装体的合成。主持国家自然科学基金面上项目、陕西省教育厅自然科学基金重点项目和陕西省自然科学基金面上项目。
代表性科研成果:
36. Y. Yu, Y. Li, X. Wang, H. Nian, L. Wang, Y. Zhao, J. Li, X. Yang, S. Liu, and L. Cao*, Cucurbit[10]uril-based [2]Rotaxane: Preparation and Supramolecular Assembly-Induced Fluorescence Enhancement. J. Org. Chem. 2017, 10.1021/acs.joc.7b00400. (SCI,IF=4.785,二区top)
35. P. Wang, Y. Wu, Y. Zhao, Y. Yu, M. Zhang, and L. Cao*, Crystalline Nanotubular Framework constructed by cucurbit[8]uril for selective CO2 adsorption, Chem. Commun. 2017, DOI: 10.1039/C7CCC02074K. (SCI,IF=6.567,一区)
34. D. Sigwalt, M. Sekutor, L. Cao, P. Y. Zavalij, J. Hostas, H. Ajani, P. Hobza, K. Mlimaric-Majerski, R. Glaser, L. Isaacs, Unraveling the Structure-Affinity Relationship between Cucurbit[n]urils (n = 7, 8) and Cationic Diamondoids. J.Am.Chem.Soc.,2017,139, 3249-3258.(SCI,IF=13,一区top)
33. J. Li,‡ Y. Zhao,‡ Y. Dong, Y. Yu, L. Cao* and B. Wu,CrystEngComm, 2016, DOI: 10.1039/C6CE01320A (前封面文章,SCI = 3.80,二区)
32. Dong, Y.; Cao, L.* Functionalization of Cucurbit[n]uril. Progress in Chemistry, 2016, 28, 1039-1053.(SCI = 0.89,四区)
31. Li, J.; Yu, Y.; Luo, L.; Li, Y.; Wang, P.; Cao, L.*; Wu, B. Square [5]Molecular Necklace Formed From Cucurbit[8]uril and Carbazole Derivative. Tetrahedron Lett. 2016, 57, 2306-2310.(SCI, IF=2.6,三区)
30. Škalamera,Đ.; Cao,L.; Isaacs, L.*; Glaser, R.*,Mlinarić-Majerskia, K.* Steric hindrance to the syntheses and stabilities of 1,5- and 2,6-naphthalene N-permethylated diammonium salts. Tetrahedron,2016, 72,1541-1546.(SCI, IF=2.6,三区)
29. Yu.Y.;Li,J.;Zhang,M.;Cao,L.*;Isaacs,L.*,Hydrophobic monofunctionalized cucurbit[7]uril undergoes self-inclusion complexation and forms vesicle-type assemblies.Chem.Commun.2015,51,3762-3765.(SCI,IF=6.7,一区)
28. Cao,L.;Šekutor,M.;Zavalij,P.Y.;Mlinarić-Majerski,K.*;Glaser R.*;Isaacs,L.*,Cucurbit[7]uril.Guest Pair with an Attomolar Dissociation Constant.Angew.Chem.,Int.Ed.,2014,53,988-993.(SCI,IF=13.4,封面文章,一区 top)(VIP paper and Poster of the frontispiece in Angew.Chem.,Int.Ed.)
27. Cao,L.;Hettiarachchi,G.;Briken,V.*;Isaacs,L.*,Cucurbit[7]uril Containers for Targeted Delivery of Oxaliplatin to Cancer Cells.Angew.Chem.,Int.Ed.,2013,52,12033-12037.(SCI,IF=13.4,一区top)
26. Vinciguerra,B.‡;Cao,L.‡(共同第一作者);Cannon,J.R.;Zavalij,P.Y.;Fenselau,C.;Isaacs,L.*,Synthesis and Self-Assembly Processes of Monofunctionalized Cucurbit[7]uril.J.Am.Chem.Soc.,2012,134,13133-12140.(SCI,IF=11.4,一区top)(Spotlights on Recent JACS Publications,J.Am.Chem.Soc.,2012,134,14265-14266)
25. Mingming Zhang‡;Cao,L.‡(共同第一作者);Isaacs,L.*,Cucurbit[6]uril-cucurbit[7]uril heterodimer promotes controlled self-assembly of supramolecular networks and supramolecular micelles by self-sorting of amphiphilic guests.Chem.Commun.2014,50,14756-14759.(SCI,IF=6.7,一区)
24. Cao,L.;Isaacs,L.*,Daisy Chain Assembly Formed from aCucurbit[6]uril Derivative.Org.Lett.2012,14,3072-3075.(SCI,IF=6.3,一区)
23. Cao,L.;Wang,J.G.;Ding,J.Y.;Wu,A.X.*;Isaacs,L.*,Reassembly self-sorting triggered by heterodimerization.Chem.Commun.2011,47,8548–8550.(SCI,IF=6.7,一区)
22. Cao,L.;Meng,X.G.;Ding,J.Y.;Chen,Y.F.;Gao,M.;Wu,Y.D.;Li,Y.T.;Wu,A.X.*;Isaacs,L.*,Nanotubular non-covalent macrocycle within non-covalent macrocycle assembly:(MeOH)(12)encapsulated in amolecular clip cyclododecamer.Chem.Commun.2010,46,4508–4510.(SCI,IF=6.7)
21. Cao,L.;Ding,J.Y.;Gao,M.;Wang,Z.H.;Li,J.;Wu,A.X.*,Novel and Direct Transformation of Methyl Ketones or Carbinols to Primary Amides by Employing Aqueous Ammonia.Org.Lett.2009,11,3810–3813.(SCI,IF=6.3)(highlighted by Organic Chemistry Portal:http://www.organic-chemistry.org ... 649.shtm;ChemInform,2010,41,DOI:10.1002/chin.201004082)
20. Cao,L.;Skalamera,D.;Zavalij,P.Y.;Hobza,P.*;Mlinarić-Majerski,K.*;Glaser R.*;Isaacs,L.*,Influence of Hydrophobic Residues on the Binding of CB[7]toward Diammonium Ions of Common Ammonium•••ammonium Distance.Org.Biomol.Chem.2015,DOI:10.1039/c5ob00784d(SCI,IF=3.5)
19. Cao,L.;Ding,J.Y.;Wang,J.G.;Chen,Y.;Gao,M.;Xue,W.J.;Wu,A.X.*,Colorimetric Fluoride Sensor Based on aBisthiourea Functionalized Molecular Clip.Synlett 2010,2553–2556.(SCI,IF=2.8)
18. Cao,L.;Ding,J.Y.;Yin,G.D.;Gao,M.;Li,Y.T.;Wu,A.X.*,Thioglycoluril as aNovel Organocatalyst:Rapid and Efficient alpha-Monobromination of 1,3-Dicarbonyl Compounds.Synlett 2009,1445–1448.(SCI,IF=2.8)
17. Cao,L.;Isaacs,L.*,Absolute and relative binding affinity of cucurbit 7uril towards aseries of cationic guests.Supramol.Chem.2014,26,251-258.(SCI,IF=2.1)
16. 曹利平;高蒙;李义涛;丁娇阳;吴彦东;祝艳平;佘能芳;吴安心*,二元组装体集群时的高选择性杂化重组行为.中国科学B辑:化学2009,39,343–349.(国家核心期刊)
15. Lucas,D.;Minami,T.;Iannuzzi,G.;Cao,L.;Wittenberg,J.B.;Anzenbacher,Jr.P.*;Isaacs,L.*,Templated Synthesis of Glycoluril Hexamer and Monofunctionalized Cucurbit[6]uril Derivatives.J.Am.Chem.Soc.,2012,134,13133-12140.(SCI,IF=11.4)
14. Šekutor,M.;Molčanov,K.;Cao,L.;Isaacs,L.*;Glaser R.*;Mlinarić-Majerski,K.*Design,Synthesis,and X-ray Structural Analyses of Diamantane Diammonium Salts:Guests for Cucurbit[n]uril(CB[n])Hosts.Eur.J.Org.Chem.2014,12,2533-2542.(SCI,IF=3.2)
13. Cao,L.*;Meng,X.G.;Ding,J.Y.;Xi,H.L;Wu,A.X.,J.Chem.Crystallogr.2011,41,425–429.(SCI,IF=1.2)
12. Cao,L.*;Meng,X.G.;Gao,M.;She,N.F.;Wu,A.X.,Acta Crystallogr.,Sect.C:Cryst.Struct.Commun.2008,64,o69–o72.(SCI,IF=1.3)
11. Zhu,Y.;Yuan,J.J.;Li,Y.T.;Gao,M.;Cao,L.;Ding,J.Y.;Wu,A.X.*,Synlett 2011,52–56.(SCI,IF=2.8)
10. Li,L.;She,N.F.;Fei,Z.;So,P.k.;Wang,Y.Z.;Cao,L.;Wu,A.X.*;Yao,Z.P.*,J.Fluorescence 2011,21,1103-1110.
9. Ding,J.Y.;Chen,Y.;Wang,J.G.;Wu,A.X.;Cao,L.*,J.Chem.Res.2010,246–249.(SCI)
8. Gao,M.;Yang,Y.;Wu,Y.-D.;Deng,C.;Cao,L.;Meng,X.-G;Wu,A.X.*,Org.Lett.2010,12,1856–1859.
7. Gao,M.;Yang,Y.;Wu,Y.-D.;Deng,C.;Shu,W.M.;Zhang,D.X.;Cao,L.;She,N.F.;Wu,A.X.*,Org.Lett.2010,12,4026–4029.
6. Gao,M.;Cao,L.;Wang,Z.H.;Sun,J.J.;She,N.F.;Wu,A.X.*,Synlett 2009,315–319.(SCI,IF=2.7)
5. She,N.F.;Gao,M.;Cao,L.;Wu,A.X.*;Isaacs,L.*,Org.Lett.2009,11,2603–2606.(SCI,IF=6.3)
4. Wang,Z.;Yin,G.;Qin,J.;Gao,M.;Cao,L.;Wu,A.,Synthesis 2008,3675-3681.
3. Li,Y.T.;Meng,X.G.;Cao,L.;Wang,Y.Z.;Yin,G.D.;Gao,M.;Wen,L.L.;Wu,A.X.*,Crystal Growth&Design 2008,8,1645–1653.(SCI,IF=4.2)
2. Zhou,B.H.;Cao,L.;Yin,G.D.;Gao,M.;Wu,A.X.*,Can.J.Chem.2007,85,586–591.(SCI,IF=1.4)
1. She,N.F.;Gao,M.;Cao,L.;Yin,G.D.;Wu,A.X.*,Synlett 2007,2533–2536.(SCI,IF=2.7)
会议论文
8.Cao,L.* 葫芦脲官能团功能化及其应用.the 15th National Conference on Macrocyclic Chemistry&the 7th National Conference on Supramolecualr Chemistry, 2016.(邀请报告)
7.Yu, Y.; Dong, Y.; Cao,L.*,Monofunctionalized Cucurbit[7]uril.the 10th International Symposium on Macrocyclic and Supramolecualr Chemistry,2015,A-20.
6.Cao,L.*,基于葫芦脲大环的金属有机框架.中西部地区无机化学化工学术研讨会,三峡大学,宜昌,2016,p42.
5.Yu,Y.;Li,J.;Cao,L.*,Amphiphilic supramolecular assemblies based on monofunctionalized cucurbit[7]uril.The 4th international conference on cucurbituril,2015,Naikai University,Tianjin,P.R.China.
4. Cao,L.*,Synthesis of Monofunctionalized Cucurbit[n]uril.the 17th National Conference on Macrocyclic Chemistry&the 9th National Conference on Supramolecualr Chemistry,2014,26.(分会报告)
3. Cao,L.;Isaacs,L..*,Monofunctionalized Cucurbit[7]uril.the 9th International Symposium on Macrocyclic and Supramolecualr Chemistry,2014,A-20.
2. Cao,L.;Isaacs,L..*,Synthesis and Daisy-Chain Assembly of Monofunctionalized Cucurbit[6]uril Derivatives.the 8th International Symposium on Macrocyclic and Supramolecualr Chemistry,2013,A-31.
1. Cao,L.;Ding,J.Y.;Sun,J.J.;Wang,J.G.;Xue,W.J.;Gao,M.;Wu.A.X.*,The bimolecular devices based on asymmetric molecular clips.the 15th National Conference on Macrocyclic Chemistry&the 7th National Conference on Supramolecualr Chemistry,2010,256–257.(英国皇家化学会优秀墙报奖)
参与编写专著
1. Cao,L.;Zhao,J.;Yang,D.;Yang,X.-J.;Wu,B.*,Hydrogen Bonding-Driven Anion Recognition in Hydrogen Bonded Supramolecular Structures.Springer-Verlag Berlin Herdelberg,2015,DOI:10.1007/978-3-662-45756-6_5.
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